The invention relates to a heterogeneous
polymerization reaction catalyst and application of the heterogeneous
polymerization reaction catalyst to preparing a homopolymer and a
copolymer. The heterogeneous
polymerization reaction catalyst mainly comprises a supported catalyst
promoter A and a catalyst B, the structure of the catalyst B is shown in the formula (I) or the formula (II), R1-R5 are respectively independently chosen from
hydrogen,
alkyl group, substituendum of the
alkyl group,
alkoxy group,
alkyl sulphanyl,
halogen,
nitryl,
aryl group or substituendum of the
aryl group in the formula, the adjacent groups in the R1-R5 form a ring and the number of the formed ring structures is less than 4, R6 is the alkyl group or the
aryl group, and L is alkyl group substituted
phosphine or allyl. The heterogeneous polymerization reaction catalyst can be used to prepare the homopolymer and the
copolymer, the activity is relatively high, the tolerance of the polar functional group is relatively good, the molecular weight of the prepared
polymer is relatively large, the distribution of the molecular weight is relatively narrow, the morphology is controllable, no subsequent
processing is needed, and the phenomenon of adhesion on a kettle is effectively improved.