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A polar modified high-purity polyethylene, its preparation method and application

PendingCN122080288AImprove electronic statusgood conditionBulk chemical productionPolymer sciencePtru catalyst
This invention relates to the field of polyethylene technology, specifically to a polar-modified high-purity polyethylene, its preparation method, and its applications. The method includes the following steps: In the presence of a nickel phosphonate catalyst, ethylene is polymerized with a polar monomer to obtain polar-modified polyethylene. The nickel phosphonate catalyst has the structure shown in Formula C. This invention, by employing a novel nickel phosphonate catalyst, improves the catalyst's tolerance to polar comonomers, increases the insertion rate of polar groups, and prepares polar-modified high / ultra-high molecular weight polyethylene, thereby improving the properties of polyethylene.
Owner:PUENE CRYSTAL NEW MATERIALS (SHANGHAI) CO LTD +1

Phosphine sulfonic acid type ligands, nickel phosphine sulfonic acid catalysts, and methods of making and using the same

PendingCN122325508AImprove electronic statusDecreased oxygen affinitySulfonatePolymer science
This invention relates to the field of polyolefin technology, specifically to a phosphonic sulfonic acid ligand for olefin polymerization, a nickel phosphonic sulfonate catalyst, its preparation method, and its application. The phosphonic sulfonic acid ligand structure is shown in Formula L, and the nickel phosphonic sulfonate catalyst is formed by a phosphonic sulfonic acid ligand and an organonitrile complex. The catalyst provided by this invention is a Drent-type catalyst composed of benzenesulfonic acid and 1,3,2-diazaphosphonic acid, which is resistant to polar comonomers and facilitates the preparation of high molecular weight polyolefins with biased polarity.
Owner:PUENE CRYSTAL NEW MATERIALS (SHANGHAI) CO LTD +1

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