The invention discloses a method for smelting ZG06Cr13Ni4Mo steel, which comprises the following steps: S1 calculation of ingredients, calculation of total charge according to the amount of molten steel required by the product, selection of charge and alloy with Ni weight percentage of 4% as the target value, charge including return of 25Cr2Ni4MoV raw materials, nickel-containing pig iron, high-quality scrap steel; S2 electric arc furnace roughing, including charge melting, dephosphorization and decarburization, pre-deoxidation, alloying, reduction and tapping steps, wherein, in the dephosphorization and decarburization step, when [C]≤ When 0.02% and [P]≤0.003%, the oxidized slag is removed, and in the pre-deoxidation step, after all the oxidized slag is removed, 5.0-6.0kg / t steel of aluminum and iron is added for pre-deoxidation; S3 ladle refining, the total refining time ≥1h, lift out and pour after refining. The invention utilizes an electric arc furnace and a refining furnace to produce low-carbon stainless steel products with w(C): 0.04-0.06%, the technological process is simple, the smelting cycle is short, the equipment complexity is reduced compared with the VOD and AOD smelting processes, the smelting cost is low, and The average oxygen content in molten steel is 5.9ppm, which improves the purity of molten steel.