The invention discloses a thermal-insulated hybrid coating containing waste polystyrene foam plastic. The coating is prepared from raw materials as follows: perfluoroalkyl alcohol, methyl isobutyl ketone, HDI tripolymer, methyl methacrylate, styrene, hydroxyethyl methacrylate, tridecafluorooctyl methacrylate, benzoyl peroxide, methanol silica sol, propylene glycol methyl ether acetate, waste polystyrene, maleic anhydride, hexadecyl trimethyl ammonium chloride, an emulsifier OP-10, rosin, ferrite powder, a proper amount of 5% ammonia water, a proper amount of mercaptoalkylalkoxysilane, a proper amount of dimethyl silicone, a proper amount of 10% dibutyl tin dilaurate, a dispersant, a flatting agent, a defoaming agent, a proper amount of butyl acetate, a proper amount of 20% alkali liquor, ethyl acetate, a proper amount of dichloromethane, a proper amount of acetone and a proper amount of deionized water. The prepared coating has good hydrophobic and oleophobic effects, good thermal-insulated effects and high adhesion, is simple in preparation process and has better practical application prospects.