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38 results about "Zinc cadmium sulfide" patented technology

Zinc cadmium sulfide is a mixture of zinc sulfide (ZnS) and cadmium sulfide (CdS). It is used for its fluorescent properties. Bioaccumulation of this chemical may occur along the food chain, for example in plants and in seafood. Long-term or repeated exposures are expected to have harmful effects on the kidneys, bones, and respiratory tract , resulting in kidney impairment, osteoporosis (bone weakness), and chronic inflammation of the respiratory tract.

Semiconductor device with higher oxygen (02) concentration within window layers and method for making

A method for making a heterojunction photovoltaic device (200) is provided for converting solar radiation to photocurrent and photovoltage with improved efficiency. The method and apparatus include an improved window layer (230) having an increased oxygen (140) concentration with higher optical bandgap and photo to dark conductivity ratio. The improved photovoltaic device (200) is made using a deposition method which incorporates the use of a gas mixture of an inert gas (115) and a predetermined amount of oxygen (140), deposited at or near room temperature. Window layers contemplated by the present invention include, but are not limited to, cadmium sulfide (CdS) and various alloys of zinc cadmium sulfide (ZnxCd1-xS). To further increase the efficiency of the resultant photovoltaic device (200), deposition parameters are controlled and monitored to improve the deposited window layer (230).
Owner:ALLIANCE FOR SUSTAINABLE ENERGY

Zinc-cadmium sulfide photocatalyst with visible light response and preparation method thereof

The invention relates to a zinc-cadmium sulfide photocatalyst nanometer material with visible light response and a preparation method thereof, and belongs to the field of inorganic material preparation. The catalyst consists of zinc-cadmium sulfide, and has good visible light absorption performance and excellent activity of degrading organic pollutant by visible light. The photocatalyst and the method have the characteristics of low cost, simple preparation process and easy industrialized production.
Owner:TIANJIN POLYTECHNIC UNIV

Solid solution catalyst for photocatalytic decomposition of water to produce hydrogen, and preparation method thereof

The invention relates to a solid solution catalyst with simple substances nickel and cobalt loaded surface and for photocatalytic decomposition of water to produce hydrogen, and a preparation method thereof, and belongs to the technical field of photocatalysts. The preparation method of the catalyst for high-efficiency photocatalytic decomposition of water to produce hydrogen comprises the following steps: dissolving copper acetate and zinc acetate in deionized water, adding sodium sulfide to form a solid solution precursor, adding the obtained precursor to a reaction kettle, reacting at a certain temperature for a period of time, washing the obtained product, and drying to obtain a product zinc cadmium sulfide; and loading metals nickel and cobalt on the surface of the zinc cadmium sulfide. The catalyst improves the reaction rate of hydrogen production through photocatalytic decomposition of water to 211417[mu]mol h<-1>g<-1> from 78130[mu]mol h<-1>g<-1> of pure zinc cadmium sulfide, and improves the performances above 2 times. The catalyst has industrial application in energy crisis solution, and is a new technical means for producing environmentally-friendly novel energy.
Owner:JILIN UNIV

Method and device for preparing zinc cadmium sulfide selenide nanowires with fluorescence changing from ultraviolet to red

The invention discloses a method and device for preparing zinc cadmium sulfide selenide nanowires with fluorescence changing from ultraviolet to red. The method is characterized by adopting high temperature to volatilize zinc sulfide in a zinc sulfide volatilization region and cadmium selenide in a cadmium selenide volatilization region, adopting a sedimentation method to grow zinc cadmium sulfide selenide nanowires on a growth carrier in a growth region in the environments of certain vacuum and airflow and ensuring the ratio of such components of the nanowires as the zinc sulfide and the cadmium selenide to continuously change from 1:0 to 0:1 through movement of the growth carrier in the growth region. The device comprises a high temperature furnace, a box body, a vacuum pump, a gas cylinder and a moving device, wherein a connecting lever suspending in the box body is arranged inside the box body; two containers are arranged on the connecting lever; a carrier platform installed on the box body is arranged at the same side of the two containers; and the moving device can be utilized to move the box body and the carrier platform at certain speed. The fluorescence spectra of the zinc cadmium sulfide selenide nanowires prepared by the method and device can continuously change from ultraviolet to red in a monotone manner.
Owner:ZHEJIANG UNIV

Preparation of a triptycene polymer NTP/ zinc cadmium sulfide Cd0.5Zn0.5S composite photocatalyst

The invention relates to a preparation of a triptycene polymer NTP / zinc cadmium sulfide Cd0.5Zn0.5S composite photocatalyst. The method comprises the following steps: preparing a triptycene polymer NTP, preparing zinc cadmium sulfide Cd0.5Zn0.5S and preparing the triptycene polymer NTP doped zinc sulfide cadmium (NTP@Cd0.5Zn0.5S) composite photocatalyst. The preparation method provided by the invention has the beneficial effects that the preparation method is simple, the preparation conditions are easy to control, and the prepared triptycene polymer NTP doped zinc sulfide cadmium Cd0.5Zn0.5Scomposite catalyst has the advantages of no secondary pollution and high photocatalytic efficiency and the like, and has a certain application value.
Owner:CHANGZHOU UNIV

Porous two-dimensional zinc cadmium sulfide nanosheet as well as preparation method and application thereof

The invention provides a porous two-dimensional zinc cadmium sulfide nanosheet as well as a preparation method and an application thereof, and belongs to the technical field of nano photocatalysts. The preparation method of the porous two-dimensional zinc cadmium sulfide nanosheet comprises the following steps: mixing a zinc salt, an ethylenediamine aqueous solution and a sulfur source, and carrying out a first solvothermal reaction to obtain a zinc sulfide-ethylenediamine precursor; mixing the zinc sulfide-ethylenediamine precursor, a cadmium salt and an organic solvent, and carrying out a second solvothermal reaction to obtain a zinc cadmium sulfide-ethylenediamine precursor; and mixing the zinc cadmium sulfide-ethylenediamine precursor with water, and carrying out a hydrothermal reaction to obtain the porous two-dimensional zinc cadmium sulfide nanosheet. The porous two-dimensional zinc cadmium sulfide nanosheet prepared by the method is uniform in surface pore passage distribution,multiple in reaction active sites, stable in performance and excellent in catalytic effect on hydrogen production by photocatalytic decomposition of water.
Owner:NORTHWEST UNIV(CN)

Preparation method of porous nano spherical zinc-cadmium sulfide solid solution

The invention discloses a preparation method of a porous nano spherical zinc-cadmium sulfide solid solution and belongs to the technical field of photocatalytic materials. The preparation method comprises the following steps: 1, dissolving Zn(Ac)2.2H2O and Cd(Ac)2.2H2O in a mixed solution of ethylene glycol and sodium hydroxide, and executing stirring vigorously; 2, adding thiourea into the solution prepared in the step 1, continuously stirring them, executing heating for reaction, executing cooling to room temperature after the reaction is finished to obtain a crude product, repeatedly washing the crude product with deionized water and absolute ethyl alcohol respectively, centrifugally recovering the product, and carrying out vacuum drying to obtain the porous nano spherical zinc-cadmiumsulfide solid solution. The preparation method is simple, a preparation period is short, the technological process is easy to control, and the porous nano spherical Zn0.5Cd0.5S solid solution materialprepared by the method has high-efficiency photocatalytic hydrogen production performance.
Owner:DONGGUAN UNIV OF TECH

Method for preparing gilvous occlusion pigment from cadmium-containing waste acid solution generated in acid pickling process

The invention discloses a method for preparing a gilvous occlusion pigment from cadmium-containing waste acid solution generated in an acid pickling process. Cadmium-containing wastewater generated in the acid pickling process is directly utilized to produce a zirconium silicate microcrystal occluded cadmium sulfide pigment, and zinc ions are doped by virtue of introduction of zinc sulfate to form a cadmium sulfide and zinc sulfide solid solution color former which is used for producing the zirconium silicate microcrystal occluded zinc cadmium sulfide pigment. According to the invention, zirconium oxychloride, zinc sulfate and waste acid solution containing cadmium and selenium generated in the acid pickling process as well as sodium hydroxide and sodium sulphide are subjected to chemical coprecipitation reaction in a reaction kettle, filter-pressed and washed, and dried; and then the above reaction product is evenly mixed with a mineralizer and white carbon black according to a certain ratio and calcined at a high temperature, and the calcined product is acidized, ball-milled, filter-pressed, washed and dried to obtain the zirconium silicate occluded cadmium sulfide yellow pigment or zirconium silicate occluded zinc cadmium sulfide gilvous occlusion pigment product. The gilvous occlusion pigment can replace praseodymium yellow pigment for use.
Owner:LILING KEXING IND CO LTD

Metal or metalloid modified zinc cadmium sulfide-ethylenediamine photocatalyst and preparation method

The invention discloses a metal or metalloid modified zinc cadmium sulfide-ethylenediamine photocatalyst and a preparation method. The preparation method of the metal modified zinc cadmium sulfide-ethylenediamine photocatalyst comprises the following steps that (1) ZnxCd1-xS-ethylenediamine hybrid nanosheets are prepared; (2) metal ion modified ZnxCd1-xS-ethylenediamine hybrid nanosheets are prepared; and (3) the metal modified zinc cadmium sulfide-ethylenediamine photocatalyst is prepared. The method is simple in process, easy and convenient to operate and low in preparation cost, and the prepared metal or metalloid compound modified ZnxCd1-xS-ethylenediamine photocatalyst is highly dispersed in water and has high visible light catalysis water-splitting hydrogen production performance and good chemical stability.
Owner:TIANJIN UNIV

Fluorescent material

The invention discloses a fluorescent material. The fluorescent material comprises, by weight, 25 to 35 parts of N-R substituent-p-nitroaniline, 10 to 15 parts of zinc metasilicate, 5 to 10 parts of zinc-cadmium sulfide, 3 to 9 parts of fluorescein, 2 to 5 parts of morin, 10 to 15 parts of a cyclic phenol compound, 3 to 9 parts of zirconia, 2 to 7 parts of alumina and 4 to 10 parts of garnet. The fluorescent material and other fluorescent materials can be combined and be manufactured into a white light luminescence device, or the fluorescent material can be individually used as security pattern fluorescent paint.
Owner:QINGDAO SHENGHAN CHROMATOGRAPH TECH CO LTD

Preparation method of zinc cadmium sulfide/bismuth oxybromide composite visible light catalyst

The invention relates to a preparation method of a zinc cadmium sulfide / bismuth oxybromide composite visible light catalyst. The method includes preparing zinc cadmium sulfide and a bismuth oxybromidephotocatalyst; and preparing the zinc cadmium sulfide / bismuth oxybromide composite photocatalyst. Beneficial effects of the method are that the method is simple, low in cost, and easy to operate; preparation conditions are easy to implement and control; and the prepared composite visible light catalyst is a green, pollution-free and high-performance catalyst, has high photocatalytic activity, short degradation time and good effects, and has a potential application prospect.
Owner:CHANGZHOU UNIV

Preparation method of nanogold copper quenching zinc-cadmium sulfide electrofluorescence insulin sensor

The invention relates to a preparation method of a nanogold copper quenching zinc-cadmium sulfide electrofluorescence insulin sensor, and belongs to the field of an electrofluorescence sensor. The electroluminescence spectrum of zinc-cadmium sulfide is well overlapped with the ultraviolet absorption atlas of nanogold copper; the nanogold copper can be used as a receptor to generate energy resonance transfer with the zinc-cadmium sulfide, so that the electrofluorescence response of the zinc-cadmium sulfide is quenched. Gold coats the zinc-cadmium sulfide / amino nitrogen doping mesoporous carbon Au@ZnxCd1-xS / NMC to be used as an insulin capture antibody substrate material. The nanogold copper AuCu is used as an insulin detection antibody immobilization material. Through zinc doping, the CdS electrofluorescence response can be improved; ZnxCd1-xS is used as an electrofluorescence signal source; the quenching effect of AuCu on Au@ZnxCd1-xS is used; the detection on insulin is realized according to different electrochemical luminous signal intensities of the insulin with different concentrations.
Owner:UNIV OF JINAN

Nano flower-shaped zinc cadmium sulfide solid solution photocatalyst and preparation method thereof

The invention provides a nano flower-shaped zinc cadmium sulfide solid solution photocatalyst and a preparation method thereof, and belongs to the technical field of photocatalytic materials. The preparation method comprises the steps of: dissolving zinc acetate, cadmium acetate and sodium hydrosulfide in an aqueous solution of 1, 2-diaminopropane to obtain a precursor solution, the molar ratio of the zinc acetate to the cadmium acetate being 3: 2; and carrying out hydrothermal reaction on the precursor solution at 120-160 DEG C, separating a product in the obtained reaction solution, and sequentially washing and drying the product to obtain the nano flower-shaped zinc cadmium sulfide solid solution photocatalyst. The nano flower-shaped Zn0.6Cd0.4S sulfide with a multilevel structure is synthesized by adopting a one-pot hydrothermal method, the cost is low, the material purity is high, the crystallinity is strong, and a reference is provided for later preparation of multi-component solid solution photocatalyst powder.
Owner:SHAANXI UNIV OF SCI & TECH

Composite material for preparing hydrogen energy source by decomposition water under visible light and its preparation method

The invention provides a preparation method of a composite material for preparing hydrogen energy source by decomposition water under visible light. Through an one-step hydrothermal method, graphene is compounded with zinc indium sulfide mixed with rare-earth and zinc cadmium sulfide mixed with rare-earth; on the one hand, graphene structures a heterogeneous structure on the surface of a catalystsurface so as to improve the photocatalytic activity of a photocatalytic material; on the other hand, the graphene can be used as a transition body of electronic migration in the composite catalyst material under the irradiation of the visible light, thus separation between an electron and a hole is effectively reached, and the compounding of a photon-generated carrier is stopped; thus hydrogen production can be stabilized under the effect of the visible light; moreover, the composite material of the zinc indium sulfide mixed with rare-earth and graphene and the composite material of the zinccadmium sulfide mixed with rare-earth and the graphene are further compounded; the photocatalysis hydrogen production activity of the material is further promoted, and the requirement of the photocatalytic water splitting hydrogen production material responded to the visible light in the photocatalysis field can be satisfied.
Owner:王丽燕

Zinc cadmium sulfide nanorod and nickel nanorod heterojunction photocatalyst, preparation method thereof, hydrogen production system and hydrogen production method

The invention belongs to the technical field of photocatalytic hydrogen production, and particularly relates to a zinc cadmium sulfide nanorod and nickel nanorod heterojunction hydrogen production photocatalyst, a preparation method thereof, a hydrogen production system and a hydrogen production method. The method comprises the following steps: 1) mixing a zinc salt, a cadmium salt, ethanolamine, cysteine and a urea aqueous solution at room temperature, then carrying out a hydrothermal reaction, and separating the obtained solid product to obtain a zinc cadmium sulfide nanorod; and 2) dispersing the zinc cadmium sulfide nanorod obtained in the step 1) in an aqueous solution of polyethylene glycol and nickel sulfate, then adding urea and hydrazine hydrate, and then carrying out hydrothermal reaction to obtain the zinc cadmium sulfide nanorod and metal nickel nanorod heterojunction hydrogen production photocatalyst. According to the scheme, the semiconductor photocatalyst and the hydrogen production promoter are organically combined into a heterojunction material, and the efficient hydrogen production photocatalyst is formed.
Owner:WUHAN INSTITUTE OF TECHNOLOGY

B-ZCSv/Cd with B doping, S vacancy and Schottky junction, preparation method and application of B-ZCSv/Cd in production of hydrogen from dye wastewater

The invention discloses a photocatalyst for directly producing hydrogen from dye wastewater, namely B-ZCSv / Cd with B doping, S vacancy and Schottky junction and a preparation method of the B-ZCSv / Cd. The photocatalyst is obtained by treating zinc cadmium sulfide with NaBH4 in an inert atmosphere. The method for preparing the catalyst is simple and easy to implement and environment-friendly. When being used as a water photolysis catalyst, the photocatalyst has relatively high activity; when hydrogen is produced in dye wastewater, the activity is further improved, and meanwhile, dye degradation is realized.
Owner:QINGDAO UNIV OF SCI & TECH

New material for preparing clean hydrogen energy and preparation method of new material

The invention provides a new material for preparing clean hydrogen energy and a preparation method of the new material. The new material is prepared from Zn(Ac)2.2H2O, In(NO3)3, Cd(Ac)2.2H2O, rare earth compounds, a graphene oxide solution and thioacetamide, wherein the new material is formed by stacking irregular particles, the size of the particles is 10-30 nm, and the specific surface area is 400-600 m<2> / g. According to the preparation method, by adopting a one-step hydrothermal method to compound graphene, zinc-indium sulfide doped with rare earth elements and zinc-cadmium sulfide doped with rare earth elements, on the one hand, the photocatalytic activity of a photocatalytic material can be improved by utilizing graphene to construct a heterojunction structure on the surface of the catalytic material, on the other hand, under the radiation of visible light, graphene can be used as a transitional body of electron transfer in the composite catalytic material, so that the separationof electron and cavities can be achieved effectively, combination of photon-generated carriers can be prevented; therefore, the effect of stable hydrogen generation can be achieved under the action of visible light, and the new material has a pretty good application prospect of industrialization.
Owner:王丽燕

Method for preparing magnetic zinc cadmium sulfide composite photocatalyst

The invention discloses a preparation method of a magnetic zinc cadmium sulfide composite photocatalyst, and belongs to the field of inorganic catalysts. The preparation method comprises the followingsteps of: preparing soft magnetic materials, namely manganese zinc ferrites MnxZn1-xFe2O4 and MnxZn1-xFe2O4 / C, by using a hydrothermal method, and then preparing a magnetic cadmium sulfide compositephotocatalyst (MnxZn1-xFe2O4 / C / Zn0. 8Cd0.2S) by using an impregnation precipitation method. The method is simple in preparation process, little in used equipment and low in energy consumption. The prepared MnxZn1-xFe2O4 / C / Zn0. 8Cd0.2S is stable in magnetic performance and high in photocatalytic activity; under the irradiation of a simulated sunlight xenon lamp, 100mL of a rhodamine B solution witha concentration of 10mg / L is degraded through 0.1g of the prepared composite magnetic photocatalyst, the degradation rate of rhodamine B reaches 92.6% within 90min, the photocatalyst is magneticallyrecycled under an external magnetic field, and the degradation rate of rhodamine B is 86.9% after the photocatalyst is repeatedly used five times. The product prepared by the method can be widely applied to the field of photocatalytic degradation of organic pollutants.
Owner:CHONGQING VOCATIONAL INST OF ENG +1

Fluorescent material

The invention relates to a fluorescent material. The fluorescent material comprises the following components in parts by weight: 40-55 parts of N-R substituent-p-nitroaniline, 4-8 parts of zinc silicate, 5-10 parts of zinc cadmium sulfide, 8-15 parts of fluorescent yellow, 2-5 parts of morin, 10-15 parts of a cyclic phenolic compound, 3-9 parts of zirconium oxide, 2-7 parts of aluminum oxide, 4-10parts of garnet and 5-10 parts of mesoporous acrylamide polymer nanoparticles. Compared with the prior art, the fluorescent material has the beneficial effects: through the improvement on a formula of a fluorescent material disclosed by CN103074063A, the proportions of the N-R substituent-p-nitroaniline and the fluorescence yellow are appropriately increased, the proportions of other components are adjusted, and then a fluorescent polymer with fluorescence intensity, namely the mesoporous acrylamide polymer nanoparticles, is added, so that the fluorescence intensity of the finally obtained fluorescent material is greatly enhanced.
Owner:GUILIN AONISITE ENERGY SAVING & ENVIRONMENT PROTECTION TECH

Porous two-dimensional zinc cadmium sulfide nanosheet, preparation method and application thereof

The invention provides a porous two-dimensional zinc sulfide nanosheet and its preparation method and application, belonging to the technical field of nanophotocatalysts. The preparation method of porous two-dimensional zinc cadmium sulfide nanosheets provided by the invention includes the following steps: mixing zinc salt, ethylenediamine aqueous solution and sulfur source, performing a first solvothermal reaction to obtain a zinc sulfide-ethylenediamine precursor; Mix the zinc sulfide-ethylenediamine precursor, cadmium salt and organic solvent to perform a second solvothermal reaction to obtain the zinc sulfide cadmium-ethylenediamine precursor; combine the zinc sulfide cadmium-ethylenediamine precursor and Mix water and perform hydrothermal reaction to obtain porous two-dimensional zinc sulfide nanosheets. The porous two-dimensional zinc sulfide nanosheets prepared by the invention have uniform surface pore distribution, many reaction active sites, stable performance, and excellent catalytic effect on photocatalytic water splitting to produce hydrogen.
Owner:NORTHWEST UNIV

Tungsten carbide/cadmium zinc sulfide composite photocatalyst as well as preparation method and application thereof

The invention relates to a tungsten carbide / cadmium zinc sulfide composite photocatalyst as well as a preparation method and application thereof. The method comprises the following steps: S1, dispersing tungsten carbide in water to obtain turbid liquid; S2, adding soluble cadmium salt and soluble zinc salt into the turbid liquid according to a molar mass ratio of cadmium to zinc of 1: 10-10: 1, then adjusting the pH value to 4-10, and uniformly performing stirring; S3, adding the sodium sulfide solution or the potassium sulfide solution into the turbid liquid according to a ratio of the totalmolar mass of cadmium in the soluble cadmium salt and zinc in the soluble zinc salt to the molar mass of sulfur in the sodium sulfide solution and / or the potassium sulfide solution being 1: 1 to 1-2;continuously performing stirring to obtain a tungsten carbide / cadmium zinc sulfide composite photocatalyst. The tungsten carbide / cadmium zinc sulfide composite photocatalyst has excellent photocatalytic hydrogen production performance. The invention also comprises application of the composite photocatalyst in preparation of hydrogen by decomposing water.
Owner:CHANGSHA UNIVERSITY

Photocatalyst for efficiently photocatalytically decomposing water to produce hydrogen and preparation method thereof

PendingCN112023948AImproving the hydrogen production performance of photolysis waterChemically stableCatalyst activation/preparationHydrogen productionThio-Ethylic acid
The invention discloses a photocatalyst for efficiently photocatalytically decomposing water to produce hydrogen and a preparation method of the photocatalyst. Cadmium zinc sulfide in the photocatalyst is of a granular structure, the diameter of the cadmium zinc sulfide is about 20 nm to 100 nm, MoS2 is of a flower-shaped structure formed by stacking two-dimensional sheets, and cadmium zinc sulfide solid solution particles are evenly distributed on the surface of MoS2. The preparation method comprises the following steps: respectively adding cadmium acetate and anhydrous zinc acetate into absolute ethyl alcohol, uniformly stirring a mixed solution, then adding thioacetamide and MoS2, uniformly stirring again to obtain a raw material solution, transferring the raw material solution into a reaction kettle, reacting at high temperature, cooling the solution to room temperature after the reaction is finished, centrifuging the obtained product through a centrifugal machine, collecting precipitates; and cross-washing the precipitates with deionized water and absolute ethyl alcohol, and drying the washed precipitates in a drying oven to obtain a product, namely the MoS2 / Zn0. 5Cd0. 5S photocatalyst. The flower-like metal sulfide (MoS2) and cadmium zinc sulfide are compounded to construct the heterojunction, thereby enhancing the water photolysis hydrogen production performance.
Owner:XI'AN POLYTECHNIC UNIVERSITY

Visible light-assisted Fenton promoter as well as preparation method and application thereof

The invention discloses a visible light-assisted Fenton promoter as well as a preparation method and an application thereof. The Fenton promoter is composed of a cadmium-zinc sulfide solid solution. Based on a solid solution cocatalyst containing three elements of cadmium, zinc and sulfur, the catalyst is prepared from zinc acetate, cadmium chloride and thioacetamide through a simple solvothermal method. The experiments prove that the co-catalyst has multiple excellent characteristics of good morphology, excellent photo-Fenton co-catalysis performance, recyclability and the like, is expected to play an important role in sewage treatment, and has a wide application prospect.
Owner:安徽理工大学环境友好材料与职业健康研究院(芜湖) +1

A phosphorus-doped zinc cadmium sulfide solid solution catalyst, photocatalytic system and method for splitting water to produce hydrogen

The invention discloses a phosphorus-doped zinc-cadmium sulfide solid solution catalyst. The chemical formula of the phosphorus-doped zinc-cadmium sulfide solid solution catalyst is P-Zn x cd 1‑x S, where 0≤x≤1. The invention also discloses a preparation method of the phosphorus-doped zinc-cadmium sulfide solid solution catalyst, which includes the following steps: mixing the zinc-cadmium sulfide solid solution with a phosphorus source and then performing a phosphating reaction to prepare a phosphorus-doped zinc-cadmium sulfide solid solution catalyst. The preparation method of the present invention has fewer types of raw materials, is cheap and easy to obtain, has mild reaction conditions and is simple to operate. The invention also discloses a photocatalytic system including the phosphorus-doped zinc cadmium sulfide solid solution catalyst. The photocatalytic system does not need to add any cocatalyst and electron sacrificial agent. The reaction system is simple and it catalyzes water decomposition under pure water conditions. More conducive to practical applications.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI +1

Preparation method and application of cadmium zinc sulfide/mesoscopic niobium pentoxide S-type heterojunction fiber photocatalyst

The invention relates to a cadmium zinc sulfide / mesoscopic niobium pentoxide S-type heterojunction fiber photocatalyst. A cadmium zinc sulfide / mesoscopic niobium pentoxide S-type heterojunction is composed of a (001) diffraction crystal face of mesoscopic niobium pentoxide and a (002) diffraction crystal face of cadmium zinc sulfide. The preparation method comprises the following steps: adding mesoscopic niobium pentoxide in the hydrothermal growth process of cadmium zinc sulfide, and carrying out secondary hydrothermal treatment to obtain the cadmium zinc sulfide / mesoscopic niobium pentoxide S-type heterojunction fiber photocatalyst. The zinc cadmium sulfide / mesoscopic niobium pentoxide S-type heterojunction fiber photocatalyst is applied to catalytic oxidation degradation and reduction of antibiotics under visible light. The zinc cadmium sulfide / mesoscopic niobium pentoxide S-type heterojunction fiber photocatalyst is applied to hydrogen production through catalytic oxidation, degradation and reduction of antibiotics under visible light. The cadmium zinc sulfide / mesoscopic niobium pentoxide S-type heterojunction fiber photocatalyst has the beneficial effects that the photocatalytic performance is excellent, and due to the formation of an S-type heterojunction, the cadmium zinc sulfide / mesoscopic niobium pentoxide S-type heterojunction fiber photocatalyst has stronger light absorption capacity and higher carrier separation efficiency.
Owner:HUBEI NORMAL UNIV

Luminous hub cover

The invention discloses a luminous -hub cover, which comprises a cover body, a mounting hole is arranged in the middle of the cover body, ventilation holes are arranged on the cover body, the ventilation holes are close to the edge of the cover body, the outer surface of the cover body is provided with a protrusion, the protrusion surface is provided with a light-storing material, and the light-storing material is composed of the following components in parts by weight: 25-35 parts of N-R substituent-P-nitroaniline, 10-15 parts of zinc silicate part, 5-10 parts of zinc cadmium sulfide, 3-9 parts of fluorescent yellow, 2-5 parts of morin, 10-15 parts of cyclic phenol compound, 3-9 parts of zirconia, 2-7 parts of alumina, 4-10 parts of garnet. The invention has the advantages of reasonablestructure design, low cost and good heat dissipation effect, and the ventilation hole can guide the external air flow to the inside and flow along the blades to form a vortex and improve the heat dissipation effect.
Owner:周银峰

Compound alkali metal hydrate dissolvent synthesis method for metallic sulfide nano crystal material

The invention discloses a preparation method for a metal sulfide and a composite metal sulfide nano crystal material, which is suitable for the preparation of the nano crystal materials of cadmium sulfide, cuprous sulfide, zinc sulfide, lead sulfide, bismuth sulfide, and zinc-cadmium sulfide. The method is characterized in that water or organic solvent used in the existing hydrothermal or solvent thermal synthetic methods is replaced with melt composite alkali metal hydroxide which is synthesized through a chemical reaction under the normal atmosphere and a temperature between 100 and 300 DEG C. The raw materials used are soluble inorganic metal salts and sulfide or sulfide compounds, thereby having less controllable parameters and simple art, and being able to amplify manufacturing during the process of synthesis. Metal sulfide crystal produced has the advantages of good crystal, clean surface and even size, and is suitable for the research on the intrinsic properties and the maximum play of the functions of the nano crystal materials. The metal sulfide and the composite metal nano crystal materials have properties of a semiconductor, LED and optoelectronic, thereby being suitable for biomarker and preparation of a nano electronic apparatus, an LED apparatus and an optoelectronic apparatus.
Owner:CHONGQING UNIV

Preparation method of cadmium zinc sulfide-titanic acid nanotube composite photocatalyst

The invention relates to a preparation method of a cadmium zinc sulfide-titanic acid nanotube composite photocatalyst. The prepared cadmium zinc sulfide-titanic acid nanotube composite photocatalyst has relatively high adsorption and photocatalysis performance on wastewater, and the preparation method of the photocatalyst also has the characteristics of low preparation process cost, simple process, easiness in control and the like.
Owner:XI'AN POLYTECHNIC UNIVERSITY

Method and device for preparing zinc cadmium sulfide selenide nanowires with fluorescence changing from ultraviolet to red

The invention discloses a method and device for preparing zinc cadmium sulfide selenide nanowires with fluorescence changing from ultraviolet to red. The method is characterized by adopting high temperature to volatilize zinc sulfide in a zinc sulfide volatilization region and cadmium selenide in a cadmium selenide volatilization region, adopting a sedimentation method to grow zinc cadmium sulfide selenide nanowires on a growth carrier in a growth region in the environments of certain vacuum and airflow and ensuring the ratio of such components of the nanowires as the zinc sulfide and the cadmium selenide to continuously change from 1:0 to 0:1 through movement of the growth carrier in the growth region. The device comprises a high temperature furnace, a box body, a vacuum pump, a gas cylinder and a moving device, wherein a connecting lever suspending in the box body is arranged inside the box body; two containers are arranged on the connecting lever; a carrier platform installed on the box body is arranged at the same side of the two containers; and the moving device can be utilized to move the box body and the carrier platform at certain speed. The fluorescence spectra of the zinc cadmium sulfide selenide nanowires prepared by the method and device can continuously change from ultraviolet to red in a monotone manner.
Owner:ZHEJIANG UNIV

A kind of photocatalytic decomposition water hydrogen production solid solution catalyst and preparation method thereof

The invention relates to a solid solution catalyst with simple substances nickel and cobalt loaded surface and for photocatalytic decomposition of water to produce hydrogen, and a preparation method thereof, and belongs to the technical field of photocatalysts. The preparation method of the catalyst for high-efficiency photocatalytic decomposition of water to produce hydrogen comprises the following steps: dissolving copper acetate and zinc acetate in deionized water, adding sodium sulfide to form a solid solution precursor, adding the obtained precursor to a reaction kettle, reacting at a certain temperature for a period of time, washing the obtained product, and drying to obtain a product zinc cadmium sulfide; and loading metals nickel and cobalt on the surface of the zinc cadmium sulfide. The catalyst improves the reaction rate of hydrogen production through photocatalytic decomposition of water to 211417[mu]mol h<-1>g<-1> from 78130[mu]mol h<-1>g<-1> of pure zinc cadmium sulfide, and improves the performances above 2 times. The catalyst has industrial application in energy crisis solution, and is a new technical means for producing environmentally-friendly novel energy.
Owner:JILIN UNIV
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