The invention discloses a weather-proof flux core wire used for coating-free bridge steel and a preparing method of the weather-proof flux core wire. The weather-proof flux core wire is composed of a steel skin and a powder core. The powder core comprises, by weight percent, 2%-8% of ferro-boron, 0.01%-2% of ferromolybdenum, 1%-6% of fluoride, 1.5%-8% of zircon sand, 2%-7% of magnesium powder, 2%-5% of quartz sand, 2%-8% of silicon iron, 5%-19% of electrolytic manganese, 1%-5% of ferromanganese, 1%-6% of nickel powder, 1%-8% of chromium metal, 1%-8% of copper powder, 2%-9% of ferrotitanium, 0.1%-5% of feldspar, 2%-8% of sodium titanate, 20%-40% of rutile and the balance iron powder. Compared with the prior art, the weather-proof flux core wire is stable in welding arc and little in splashing, slag removing is easy, a welding joint is formed attractively, the weather-proof flux core wire is suitable for all-position welding, the mechanical performance of the welding joint is good, the impact toughness at the temperature of minus 40 DEG C is larger than 80 J, and very high corrosion resistance is achieved.