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33 results about "4-Heptanone" patented technology

4-Heptanone or heptan-4-one is an organic ketone with the chemical formula C₇H₁₄O.

Blended frother for producing low ash content clean coal through flotation

An improved frothing agent adaptable to froth flotation process to enhance coal selectivity for separation and efficiency of the forth flotation process comprises:-A blended mixture ofKetone (2,6 Dimethl-4-Heptanone)85-89%(Wr %)Ester molecule(Tetrahydrofurfuryl acetate)10-12%(Wt %)Epoxide conditioner (1,2-Epoxydodecane)0.25-0.30%(Wt %)Water4.75-5.25%(Wt %)
Owner:TATA STEEL

Adhesive composition primarily intended for use in medical applications

The present invention provides an adhesive composition for use in bonding a polymeric fitting to an olefin-containing component of an article used in medical applications. The adhesive composition according to the invention includes an adhesive polymer system dissolved in a solvent system. The solvent system includes an organic solvent having a solubility parameter within the range of from about 7.5 to about 10 (cal / cm<3>)<1 / 2>. Subsequent to forming a bond between the polymeric fitting and the olefin-containing component, the adhesive composition can meet the requirements for USP Class VI materials. In a preferred embodiment of the invention, the adhesive composition includes a low shear mixture of an adhesive polymer system including an atactic polypropylene and a low density polyethylene that is dissolved in a solvent system including a blend of d-limonene and a ketone selected from the group consisting of 4-heptanone and cyclohexanone. The adhesive composition can be used, for example, to bond polymeric fittings made of materials such as, but not limited to, acrylic, polycarbonate, polyvinyl chloride, polyolefin, acrylonitrile butadiene-styrene, and polyester, to olefin-containing components of articles used in medical applications such as, but not limited to, tubing.
Owner:LYONDELLBASELL ADVANCED POLYMERS INC

Plated film paint system, plastic part with metal effect coating, and preparation method of plated film paint system

The invention discloses a plated film paint system. The plated film paint system comprises a transparent UV priming paint, a transparent UV intermediate coat used for coating a clad layer, a colored paint, and a transparent UV finishing coat; the transparent UV intermediate coat comprises, by weight, 20 to 50% of polyurethane acrylate, 5 to 10% of hydroxy acrylic resin, 10 to 20% of acetic ester,10 to 20% of butyl acetate, 10 to 20% of 2,6-Dimethyl-4-heptanone, and 0.5 to 3% of an auxiliary agent, wherein the molecular weight of the hydroxy acrylic resin is larger than 50000. The plated filmpaint system is adopted in preparation of the plastic part with metal effect coating, laser carving is carried out after coating of all the coats, the transparent UV finishing coat and the colored paint layer are removed via calcinations, clad layer metal effect is achieved. Compared with the prior art, the technology possesses following advantages: technology process is simple, production efficiency is increased, paint layer clunging force is high, and color change is not caused after laser carving.
Owner:长沙松润新材料有限公司

Adhesive composition primarily intended for use in medical applications

The present invention provides an adhesive composition for use in bonding a polymeric fitting to an olefin-containing component of an article used in medical applications. The adhesive composition according to the invention includes an adhesive polymer system dissolved in a solvent system. The solvent system includes an organic solvent having a solubility parameter within the range of from about 7.5 to about 10 (cal / cm3)½. Subsequent to forming a bond between the polymeric fitting and the olefin-containing component, the adhesive composition can meet the requirements for USP Class VI materials. In a preferred embodiment of the invention, the adhesive composition includes a low shear mixture of an adhesive polymer system including an atactic polypropylene and a low density polyethylene that is dissolved in a solvent system including a blend of d-limonene and a ketone selected from the group consisting of 4-heptanone and cyclohexanone. The adhesive composition can be used, for example, to bond polymeric fittings made of materials such as, but not limited to, acrylic, polycarbonate, polyvinyl chloride, polyolefin, acrylonitrile butadiene-styrene, and polyester, to olefin-containing components of articles used in medical applications such as, but not limited to, tubing.
Owner:LYONDELLBASELL ADVANCED POLYMERS INC

Preparation method of pyrrolizidine-9-acetic acid hydrochloride

The invention discloses a preparation method of pyrrolizidine-9-acetic acid hydrochloride, comprising the following chemical reactions: 1) preparing 1,7-bi-p-nitryl benzenesulfonate -4-heptanone as a raw material according to the prior art for reacting with ammonium chloride and ammonia to generate pyrrolizidine-chlorate; 2) reacting the pyrrolizidine-chlorate with sodium cyanoacetate to generate pyrrolizidine-9-acetonitrile; and 3) allowing the pyrrolizidine-9-acetonitrile with concentrated hydrochloric acid to generate the pyrrolizidine-9-acetic acid hydrochloride. By adopting a chemical synthesis method, the preparation method of the invention greatly simplifies preparation flow, shortens reaction time and effectively lowers production cost; and the pyrrolizidine-9-acetic acid hydrochloride prepared by the preparation method has high yield and good quality, thus meeting the need of industrialized production.
Owner:苏州永拓医药科技有限公司

Heat treatment PAG water base quenching medium stabilizer and uses thereof

The present invention discloses a heat treatment PAG water base quenching medium stabilizer, which comprises the following components, by weight, 1-10 parts of a foam breaking polysiloxane solution, 1-12 parts of 2,6-dimethyl-4-heptanone, 1-15 parts of alkenyl succinic acid-zinc naphthenate, 1-5 parts of barium sulfonate, and 1-8 parts of polyethylene glycol. The heat treatment PAG water base quenching medium stabilizer is mainly used for a water base quenching medium adopting polyaleneglycol (PAG) as a main component, wherein an addition amount is 0.1-2% of a weight of a PAG aqueous solution. The invention further discloses uses of the heat treatment PAG water base quenching medium stabilizer.
Owner:SHANGHAI SPACE PRECISION MACHINERY RES INST

Method for preparing ketone compounds by transferring ABE fermentation solution

The invention relates to a method for preparing ketone compounds. According to the method, an ABE fermentation solution (acetone-butanol-ethanol water solution) is adopted as a reactant, and the ketone compounds are prepared through a reaction under catalysis of a cerium-based composite oxide. The reaction conditions are as follows: the reaction is carried out at normal pressure in a fixed bed reactor, a reaction temperature is 350-500 DEG C, and a feeding mass space velocity of the ABE is 0.1-2.0 h<-1>. The method is characterized in that the cerium-based composite oxide is used as the catalyst, the catalyst is simple to prepare and has good stability, the ketone compounds are generated through efficiently catalyzing the ABE, the conversion rate is up to 95% (based on the total carbon number), and the total selectivity of the ketone compounds can reach 99%, wherein the selectivity of 4-heptanone is 92%, and the selectivity of 2-pentanone is 8%.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Conversion of ethanol to c5+ ketones in single catalyst bed

ActiveUS20180215692A1Simple and efficient productionSimplified to fuel conversionCarbonyl compound preparation by condensationMetal/metal-oxides/metal-hydroxide catalystsAlcohol2-Heptanone
Methods, systems and catalysts for converting an alcohol containing feedstock to an upgraded material in a single catalyst bed wherein a feedstock is fed to a catalyst under preselected conditions to obtain an intermediate; and condensing the intermediate through an aldol condensation reaction to yield a product containing an upgraded material. In one instance the feedstock includes ethanol, the catalyst is a mixed metal oxide catalyst and the upgraded material is typically a C5+ ketone(s) or alcohol(s), such as 2-pentanone, 2-heptanone, 4-heptanone and 2-nonanone.
Owner:BATTELLE MEMORIAL INST

Acrylamide ultrahigh molecular weight polymerization reaction initiator

ActiveCN102532364ASlow reaction speedReduce free radical concentrationMethyl isobutyl ketoneReaction temperature
The invention an acrylamide ultrahigh molecular weight polymerization reaction initiator, which consists of 20-50 parts of methyl isobutyl ketone, 10-40 parts of 4-heptanone, 3-10 parts of dimethylfomamide, 10-30 parts of azobisvaleronitrile, 3-5 parts of azobisisobutyronitrile and 10-30 parts of dimethyl azobisisobutyrate. The invention relates to a composite initiator special for synthesizing ultrahigh molecular weight polyacrylamide, which is suitable for bulk kettle polymerization for industrially generating polyacrylamide. A plurality of initiators are compounded, a polymerization reaction is completed in a segmental initiating way, free radicals are released segmentally by different types of initiators with different activating energy at different reaction temperatures, certain concentration of the free radicals is kept, a polymerization reaction speed is controlled, and the molecular weight of a polymerized product can be increased effectively. Reaction activating energy differs, and segmental initiation is performed; the initiator is water-soluble, and a reaction is uniform; and the reaction is insensitive to acid and alkaline environments, and high adaptability is achieved.
Owner:大庆市华兴化工有限责任公司

High-fillibility high-rubbing property primer and preparation method thereof

The invention relates to a high-fillibility high-rubbing property primer and a preparation method thereof. The method comprises the following steps: according to parts by weight, adding 20-40 parts of modified acrylic resin A, 10-20 parts of modified acrylic resin B, 2-4 parts of wetting dispersant, 10-15 parts of nano talcum powder, 5-10 parts of superfine barium sulfate, 0.2-0.5 parts of carbon black, 0.5-1 part of anti-settling agent, 5-15 parts of xylene, 5-10 parts of n-butyl acetate and 5-10 parts of dimethyl-4-heptanone respectively in a vat in sequence, and stirring for 30min at 600-800r / min, then putting into a grinder to grind to a fineness below 10 micrometers and discharging, and finally adding 0.2-0.5 parts of fluorocarbon-modified polyacrylic acid flatting agent and stirring for 30min at 600-800r / min. Compared with the prior art, the primer has the advantages of excellent adhesive force on various PP+GF (propene polymer and glass fiber), great easiness in polishing, excellent recoatability, suitability for various finishing coats and the like.
Owner:DONGLAI COATING TECH SHANGHAI

Preparation method of 7A-pyrrolizidine-acetonitrile

The invention relates to a preparation method of a 7A-pyrrolizidine-acetonitrile. Gamma-butyrolactone as raw material is subjected to nucleophilic substitution reaction, acid hydrolysis cyclization reaction and nucleophilic addition decarboxylation reaction for preparing the 7A-pyrrolizidine acetonitrile. The method is characterized in that a transition intermediate CMP-1 is subjected to separation and purification to substitute a carbon chain constructed by a parent nuclear provided by 1,7-dichloro-4-heptanone. The method has easy purification and high yield, and the intermediate is stable and easy to save and transfer. An inorganic ammonium salt ammonium acetate is used as a source of ammonia to substitute the ammonia widely used in a traditional process, so as to prepared product with high purity under mild conditions (GC>99%). The method avoids the disadvantages of high energy consumption (frozen reaction), long time consumption and low quality product (need to distillation, and the product purity between 98-99%) in a traditional process. The production process uses low-priced and easily available raw materials in each step, does not use toxic organic solvents, has easy post-treatment, produces few "three wastes" and is green and environment-friendly.
Owner:SUZHOU CANIMBLE BIOTECH

Blended frother for producing low ash content clean coal through flotation

InactiveCN101861211AFlotationAcetic acidKetone
An improved frothing agent adaptable to froth flotation process to enhance coal selectivity for separation and efficiency of the forth flotation process comprises :- A blended mixture of Ketone (2,6 Dimethl-4-Heptanone) - 85-89% (Wr%) Ester molecule (Tetrahydrofurfuryl acetate) - 10-12% (Wt%) Epoxide conditioner (1,2-Epoxydodecane) - 0.25-0.30%(Wt%) Water - 4.75-5.25%(Wt%).
Owner:TATA STEEL LTD

High-carbon ketone preparation method

The invention relates to a high-carbon ketone preparation method, wherein the raw material is an ABE fermentation broth, the catalyst is cerium oxide, the product is high-carbon ketone, and the reaction temperature is 350-500 DEG C. According to the present invention, the catalyst of the method has advantages of simple preparation and good stability, and can efficiently catalyze to selectively generate the high-carbon ketone, wherein the conversion rate is up to 72% (based on the total carbon number), the highest selectivity of the product high-carbon ketone can reach 98%, the 4-heptanone selectivity is 80%, the 2-pentanone selectivity is 15%, and the 2-heptanone selectivity is 3%.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Heterogeneous azeotropic distillation method for separating 2-pentanone, 4-heptanone, water and carbon dioxide mixture

The invention provides a heterogeneous azeotropic distillation method for separating a 2-pentanone, 4-heptanone, water and carbon dioxide mixture. The method comprises the following steps: feeding a 2-pentanone, 4-heptanone, water and carbon dioxide raw material into a left half side of a partitioned water tower from an inlet of a raw material to be separated, carrying out gas-liquid separation, discharging a gas phase from a gas phase outlet, feeding into a condenser, and separating a condensed liquid by using a gas-liquid-liquid separator so as to obtain a carbon dioxide enriched gas phase,a ketone enriched phase and a water enriched phase, backflowing the ketone enriched phase into the left half side of the partitioned wall tower, backflowing the water enriched phase into a right halfside of the partitioned wall tower, extracting so as to obtain a carbon dioxide enriched gas, carrying out release, feeding the ketone enriched phase into the tower kettle of a distillation tower so as to obtain a 4-heptanone product, condensing a gas phase discharged from the top of the distillation tower by using a distillation tower condenser, backflowing a part of the gas phase into the distillation tower, and collecting the other part as a 2-pentanone product. The method has the advantages of being good in separation effect, and the investment expense and the mounting space can be greatlyreduced and saved.
Owner:SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI

Preparation method of 5-methyl-2-heptylene-4-one

The invention discloses a preparation method of 5-methyl-2-heptylene-4-one. The preparation method comprises the following steps of using gamma-butyrolactone as raw material, and reacting with sec-butylmagnesium bromide, so as to obtain a 2-sec-butyl-2-hydroxytetrahydrofuran intermediate; dewatering, so as to obtain a 5-sec-butyl-2,3-dihydrofuran intermediate; catalyzing, and opening loop, so as to obtain 1-hydroxyl-5-methyl-4-heptanone; dewatering, and shifting double bonds, so as to obtain a product of 5-methyl-2-heptylene-4-one. The preparation method has the advantages that the used gamma-butyrolactone and sec-butyl bromide are commodity products, so that the obtaining of reaction raw materials is easy, and the cost of raw materials is low; in addition, the chemical metering for oxidization reaction is avoided, the pollution is little, the operation is simple, the purity of the product is high, and the preparation method is suitable for industrial production.
Owner:GUANGXI UNIV

Method for preparing 4-heptanone from butanol

The present invention relates to a method for preparing 4-heptanone from butanol, wherein specifically butanol is used as a raw material and is subjected to a reaction under a normal pressure with a catalyst cerium oxide or doped cerium oxide to obtain the product 4-heptanone, and the reaction device is a fixed-bed reactor. According to the present invention, cerium oxide or doped cerium oxide isused as the catalyst, and the catalyst is easily prepared, and can catalyze the high-selectivity generation of 4-heptanone, wherein the selectivity can reach more than 90%, and rge stability is good.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Method for preparing ketone compounds from acetic acid and ethanol by using two-stage method

The invention relates to a method for preparing ketone compounds. A reaction is carried out at normal pressure in a two-stage fixed bed reactor, a first-stage catalyst is CeO2, a reaction temperatureis 300-450 DEG C, a raw material is acetic acid, and a feeding mass space velocity of the raw material is 0.1-1.0 h<-1>. Acetone is generated after the acetic acid is subjected to a ketonization reaction in the first stage, and then a second-stage reaction is carried out. A second-stage catalyst is CeO2-SnO2, a reaction temperature is 350-450 DEG C, a raw material is ethanol, and a feeding mass space velocity of the raw material is 0.1-1.0 h<-1>. 2-pentanone and 4-heptanone are prepared through dehydrogenation and an Aldol condensation reaction in the second stage. The method is characterizedin that CeO2 and a cerium-based composite oxide are used as catalysts, and the catalyst is simple to prepare and has good stability. The ketone compounds are generated by efficiently catalyzing aceticacid and ethanol through a two-stage method, the conversion rate is up to 35% (based on the total carbon number), and the total selectivity of the ketone compounds can reach 99%, wherein the selectivity of 2-pentanone is 85%, and the selectivity of 4-heptanone is 15%. In the process, acetic acid and ethanol are taken as raw materials, the raw material source is wide, and a potential industrial application prospect is achieved.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Titanium dioxide added waterborne acrylic paint and preparation method thereof

The objective of the invention is to provide a titanium dioxide added waterborne acrylic paint with high weather resistance and capabilities of insulating and preserving heat and a preparation method thereof. The waterborne acrylic paint comprises acrylic resin, a dispersant, a wetting agent, a film forming agent, an antifoaming agent, a filling material and a solvent, wherein the film forming agent comprises amino resin; the antifoaming agent comprises 4-heptanone fluoride; and the filling material comprises rutile type titanium dioxide. The preparation method comprises the following steps: S1, predispersing the acrylic resin, the dispersant, the wetting agent, the filling material and the solvent so as to obtain a predispersed system; and S2, subjecting a predispersed system obtained in the step S1 to grinding treatment, then adding the film forming agent, the antifoaming agent and the solvent into the predispersed system in sequence, and carrying out uniform mixing under stirring so as to obtain the titanium dioxide added waterborne acrylic paint. According to the invention, after coating of the waterborne acrylic paint provided by the invention, infrared ray can be effectively reflected, so the temperature of the waterborne acrylic paint is lower than the temperature of a material; and cooling devices like an air conditioner are not needed for cooling even in solar terms with a high temperature, so the purpose of saving energy is achieved.
Owner:TAIZHOU HUANGYAN MINGZHI DECORATION MATERIALS CO LTD

Preparation method, product and application of compound with hazel characteristic aroma

The invention relates to the technical field of compound synthesis, and particularly relates to a preparation method of a compound with hazel characteristic aroma. The preparation method comprises the steps of: reacting 2-butanone and phosphorus tribromide under proper conditions to obtain an intermediate product A, then adding magnesium powder and iodine, reacting under proper conditions to obtain an intermediate product B, and then reacting in the presence of Dess-Martin oxidant to obtain the compound with hazel characteristic aroma, wherein analysis proves that the compound is higher purity 5-methyl-4-heptanone. The compound with hazel characteristic aroma obtained by the preparation method provided by the invention is pure and natural in aroma.
Owner:HUABAO FLAVOURS & FRAGRANCES CO LTD

A kind of preparation method of 7a-double condensed pyrrolidine-acetonitrile

The present invention relates to a preparation method of 7A-double-condensed pyrrolidin-acetonitrile, which uses gamma-butyrolactone raw material to prepare 7A-double-condensed pyrrole through affinity substitution reaction, acidolysis ring-closure reaction and affinity addition decarboxylation reaction Pyridine-acetonitrile, which is characterized in that the transition intermediate CMP-1 is separated and purified to replace 1,7-dichloro-4-heptanone to provide the carbon chain constructed by the mother nucleus. The purification is simple, the yield is high, and the intermediate is stable and easy to store and transfer . The inorganic ammonium salt ammonium acetate is used as the ammonia source to replace the large-scale ammonia gas used in the traditional process, and a high-purity (GC>99%) product is produced under relatively mild conditions. It avoids the shortcomings of the traditional process such as high energy consumption (low temperature freezing reaction), long time consumption, and low product quality (rectification is required, and the product purity is between 98‑99%). The raw materials of each step in the production process are cheap and easy to obtain, no toxic organic solvents are used, the post-treatment is simple, the "three wastes" are less in the production process, and it is green and environmentally friendly.
Owner:SUZHOU CANIMBLE BIOTECH

Organic synthesis raw material valeric acid synthesis method

The invention relates to an organic synthesis raw material valeric acid synthesis method, which mainly comprises: adding 3 mol methyl propyl ketone and 4-6 mol tributyl citrate solution to a reactioncontainer, controlling the stirring speed at 190-220 rpm, reducing the solution temperature to 6-9 DEG C, maintaining for 60-80 min, increasing the temperature of the solution to 10-15 DEG C, adding 3-4 mol chromium acetate in 3-6 times every 30-40 min, continuously carrying out the reaction for 2-3 h, standing for 60-80 min, adding 300 ml of a potassium nitrate solution, layering the solution, extracting 3-5 times with a 4-heptanone solution, extracting 4-6 times with a 3-methyl-2-pentanone solution, combining the oil layer and the extraction liquid, re-crystallizing in an isobutyl butyrate solution, and dehydrating with a dehydrating agent to obtain the finished product valeric acid.
Owner:CHENGDU DONG DIAN AI ER TECH

2-mercapto-5-methyl-4-heptanone and its use in flavor and fragrance compositions

The present invention is directed to a novel compound, 2-mercapto-5-methyl-4-heptanone, a process of augmenting, enhancing or imparting taste to a material selected from the group consisting of a foodstuff, a chewing gum, a medicinal product, and toothpaste comprising the step of incorporating an olfactory acceptable amount of 2-mercapto-5-methyl-4-heptanone, and a process of improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of 2-mercapto-5-methyl-4-heptanone.
Owner:INTERNATIONAL FLAVORS & FRAGRANCES

2-mercapto-5-methyl-4-heptanone and its use in flavor and fragrance compositions

The present invention is directed to a novel compound, 2-mercapto-5-methyl-4-heptanone, a process of augmenting, enhancing or imparting taste to a material selected from the group consisting of a foodstuff, a chewing gum, a medicinal product, and toothpaste comprising the step of incorporating an olfactory acceptable amount of 2-mercapto-5-methyl-4-heptanone, and a process of improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of 2-mercapto-5-methyl-4-heptanone.
Owner:INTERNATIONAL FLAVORS & FRAGRANCES

Acrylamide ultrahigh molecular weight polymerization reaction initiator

ActiveCN102532364BSlow reaction speedReduce free radical concentrationMethyl isobutyl ketoneReaction temperature
The invention an acrylamide ultrahigh molecular weight polymerization reaction initiator, which consists of 20-50 parts of methyl isobutyl ketone, 10-40 parts of 4-heptanone, 3-10 parts of dimethylfomamide, 10-30 parts of azobisvaleronitrile, 3-5 parts of azobisisobutyronitrile and 10-30 parts of dimethyl azobisisobutyrate. The invention relates to a composite initiator special for synthesizing ultrahigh molecular weight polyacrylamide, which is suitable for bulk kettle polymerization for industrially generating polyacrylamide. A plurality of initiators are compounded, a polymerization reaction is completed in a segmental initiating way, free radicals are released segmentally by different types of initiators with different activating energy at different reaction temperatures, certain concentration of the free radicals is kept, a polymerization reaction speed is controlled, and the molecular weight of a polymerized product can be increased effectively. Reaction activating energy differs, and segmental initiation is performed; the initiator is water-soluble, and a reaction is uniform; and the reaction is insensitive to acid and alkaline environments, and high adaptability is achieved.
Owner:大庆市华兴化工有限责任公司
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