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33 results about "Ceramic chemistry" patented technology

Ceramic chemistry studies the relationship between the physical properties of fired ceramics and ceramic glazes and their chemistry. Although ceramic technicians have long understood many of these relationships, the advent of computer software to automate the conversion from batch to formula and analysis has brought this science within the reach of many more people. Physical properties of glazes in fired products (like thermal expansion, hardness, index of refraction, color and melting temperature or range) are directly (but not solely) related to the chemistry. Properties of glass melts like viscosity and surface tension are also principally products of chemistry.

Microwave dielectric ceramic and preparation method thereof

The invention discloses a microwave dielectric ceramic and a preparation method thereof. The microwave dielectric ceramic is mainly composed of ZrO2, TiO2 and Nb2O5; the microwave dielectric property of the microwave dielectric ceramic can be improved by selectively adding MgO, CoO, ZnO, NiO and MnO2; the chemical constitution formula of the ceramic is xZrO3-YTiO2-zA(1+W) / 3Nb(2-w) / 2O3; in formula (I), A is one or more elements of Mg, Co, Zn, Ni and Mn; x, y and z are molar ratios, wherein x is between 0.2 and 0.7, y is between 0.2 and 0.6,, z is between 0.1 and 0.2, and, x plus y plus z is equal to 1; numerical range of w is l between 0 and 0.5. According to the microwave dielectric ceramic and the preparation method thereof, the ceramic has the characteristics that the dielectric constant is high, the loss is low, and the temperature coefficient is close to zero, and is liable to sinter; the preparation method has the characteristics that the price of raw materials is low, and a technology during production is simple.
Owner:HEFEI NORMAL UNIV

Pressure proof strontium titanate base energy storage medium ceramic and its preparation method

ActiveCN1785897AOvercome the disadvantage of high firing temperatureHigh dielectric constantStrontium titanateAir atmosphere
The present invention relates to a high pressure-resistant energy-storing medium ceramic and its preparation method. The chemical composition of said ceramic is Sr(Ti0.95 Zr0.05) O3+Xmol% CaTiSiO5, in which X is greater than O and less than or equal to 20. Its preparation method includes the following steps: adopting solid-phase method, using SrCO3 and TiO2 to synthesize SrTiO3; using SrCO3 and ZrO2 to synthesize SrZrO3; using CaCO3 SiO2 and TiO2 to synthesize CaTiSiO5 powder body; mixing materials according to the above-mentioned chemical composition formula; ball-grinding according to the ratio of material; ball: water=1:1:1-1.2, drying; adding polyvinyl alcohol solution as binding agent, granulating, sieving with 40 meshes, press-forming, slowly heating to 600-650deg.C to remove binding agent, sintering at 1260-1420deg.C, heat-insulating for 2-6hr, so as to obtain the invented product.
Owner:WUHAN UNIV OF TECH

Strontium titanate base energy storage medium ceramics and preparing method

ActiveCN1587197AImprove performanceOvercoming low frequency lossIonAir atmosphere
The energy storing strontium titanate base dielectric ceramic has the chemical expression of Sr(ZrxTi1-x)O3, where x is 0.01-0.10, and has doped MnO2 with purity higher than 85 %. The preparation process includes the following steps: compounding material with SrCO3, ZrO2 and TiO2 in 99 % over purity as initial material in the chemical ratio of SrTiO3 and SrZrO3, grinding in deionized water and stoving, maintaining at 1150 deg.c for 4 hr to synthesize SrTiO3 powder, maintaining at 1250 deg.c for 6 hr to synthesize SrZrO3 powder, compounding material based on Sr(ZrxTi1-x)O3, where x is 0.01-0.10, adding MnO2 powder with purity higher than 85 %, grinding in deionized water and mixing, stoving in air atmosphere, adding PVA aqua to pelletize, pressing to form, and sintering in air atmosphere inside high temperature furnace to produce the dielectric ceramic. The dielectric ceramic has high dielectric constant, low loss and high dielectric strength.
Owner:WUHAN UNIV OF TECH

High-energy-storage silver niobate-based lead-free antiferroelectric ceramic and preparation method thereof

The invention discloses high-energy-storage silver niobate-based lead-free antiferroelectric ceramic and a preparation method thereof.The chemical formula of the high-energy-storage silver niobate-based lead-free antiferroelectric ceramicis Ag<1-3x>La<x>Nb<0.9>Ta<0.1>O<3>, wherein x is the molar percentage, and the value of x can meets the electric neutrality requirement. The preparation method ofthe high-energy-storage silver niobate-based lead-free antiferroelectric ceramic comprises the following steps: (1) weighing raw materials according to a stoichiometric ratio in thechemical formula Ag<1-3x>La<x>Nb<0.9>Ta<0.1>O<3>, carrying out ball-milling mixing, drying, sieving and tabletting on the raw materials, and presintering the raw materials for 4-6 hours to obtain a rough blank; (2) grinding the rough blank, carrying out secondary ball milling, drying, sieving, granulating, and uniaxial compression molding, and carrying out isostatic cool compression molding to obtain a biscuit; (3)discharging glue from the biscuit, and sintering to obtain a ceramic chip; and (4) grinding and polishing the ceramic chipinto a ceramic sheet, brushing the ceramic sheet with a silver electrode, calcining, and cooling. The energy storage ceramic with high energy storage density and high energy storage efficiency can be obtained by doping a trace amount of La < 3 + > at ceramicA site, the energystorage density is up to 4.6 J / cm < 3 >, and the energy storage efficiency is up to 59%.
Owner:NANJING UNIV OF POSTS & TELECOMM

High-entropy ceramic with high hardness and high conductivity as well as preparation method and application of high-entropy ceramic

The invention relates to high-entropy ceramic with high hardness and high conductivity as well as a preparation method and application of the high-entropy ceramic. The chemical formula of the high-entropy ceramic is (AaBbCcDdEe)B12. The dodecaboride high-entropy ceramic provided by the invention has high hardness and high conductivity, enriches a boride high-entropy ceramic material system, has the advantages of low cost, simplicity, feasibility, wide application range and the like, and has great application potential in the field of electrical equipment bearing high stress and high conductivity.
Owner:DONGHUA UNIV +2

Method for preparing low-loss wolframite-structure microwave dielectric ceramic by means of reaction sintering technology

InactiveCN105777119ASave burn-inSave secondary ball millingCompression moldingChemical composition
The invention discloses a method for preparing low-loss wolframite-structure microwave dielectric ceramic by means of a reaction sintering technology.The chemical composition expression of the ceramic is AZrNb2O8, wherein A represents Mg, Co, Ni and Mn.When the ceramic is prepared, the raw materials such as ZrO2, MgO, CoO, NiO, MnO and Nb2O5 are blended according to the chemical formula, the technologies of material mixing, drying, sieving, granulating, compression molding and the like are conducted, sintering is conducted at 1,250 DEG C-1,300 DEG C by means of the reaction sintering technology, and the AZrNb2O8 ceramic is obtained.According to the method for preparing the low-loss wolframite-structure microwave dielectric ceramic by means of the reaction sintering technology, the technological processes of presintering and secondary material mixing are omitted, the preparation time is greatly reduced, the preparation cost is reduced, the reaction sintering process technology is simple, the obtained ceramic is excellent in microwave dielectric property, the process is environmentally friendly, and the ceramic has a great application value in industry.
Owner:UNIV OF JINAN

Microwave dielectric ceramic with near-zero frequency temperature coefficient and preparation method thereof

Disclosed is a microwave dielectric ceramic with near-zero frequency temperature coefficient and preparation method, wherein the ceramic has the chemical formula of Ca1-xZnxLa4Ti5O17, wherein x=0.005-0.4, the ceramic is prepared from BaCO3, ZnO, La2O3, TiO2 as raw material through wet grinding and mixing, drying into powder, calcining at 1100-1200 deg. C, wet grinding again, drying and charging polyvinyl alcohol (PVA), press forming, calcining 2-4 hours in high temperature furnace, the prepared microwave dielectric ceramics can be widely applied to the manufacture of various dielectric resonators, electric wave filters and other microwave devices.
Owner:TSINGHUA UNIV

Lithium-magnesium-niobium-aluminum-tungsten microwave dielectric ceramic and preparation method thereof

The invention belongs to the technical field of ceramic materials, and discloses a lithium-magnesium-niobium-aluminum-tungsten microwave dielectric ceramic and a preparation method thereof. The chemical expression of the ceramic is Li3Mg2Nb1-x(Al1 / 3W2 / 3)xO6, and x is larger than or equal to 0.02 and smaller than or equal to 0.08. The preparation method comprises the following steps: by adopting asolid-phase synthesis method, mixing Li2CO3, MgO, Nb2O5, Al2O3 and WO3 according to a stoichiometric ratio, carrying out ball milling, drying and sieving, presintering at 925-1000 DEG C to obtain presintered powder, performing ball milling again, drying, sieving and granulating, pressing into a green body, sintering the green body at 1075-1175 DEG C, keeping the temperature, and cooling to room temperature to obtain the required microwave dielectric ceramic. The microwave dielectric ceramic has the advantages of excellent microwave dielectric properties, low cost, simple preparation technique,no toxicity or pollution, and wide application prospects.
Owner:TIANJIN UNIV

Lanthanum aluminate green ceramic as well as preparation method and application thereof

The invention provides lanthanum aluminate green ceramic as well as a preparation method and application thereof, and relates to the technical field of ceramic. The chemical component of the lanthanum aluminate green ceramic provided by the invention is LaAl < 11-2X-YNi < X > Cr < Y > Ti < X > O < 18 >, X is equal to 1.5-5.0, and Y is equal to 0.0-2.0. The lanthanum aluminate ceramic provided by the invention is green and bright in color, and has relatively high hardness, toughness and color saturation.
Owner:INNER MONGOLIA UNIV OF SCI & TECH

Magnesium-zircon-germanium-niobium microwave dielectric ceramic with low dielectric constant and ultra-low dielectric loss and preparation method and application

The invention discloses magnesium-zircon-germanium-niobium microwave dielectric ceramic with a low dielectric constant and an ultra-low dielectric loss and a preparation method and an application. A chemical expression of the microwave dielectric ceramic is Mg(Zr1-xGex)Nb2O8, wherein x is greater than 0 and less than or equal to 0.4. The preparation method comprises the following steps of: (1) preparing raw materials according to the chemical formula Mg(Zr1-xGex)Nb2O8 (x greater than 0 and less than or equal to 0.4), adding a certain proportion of deionized water and zirconia grinding media for ball milling on a ball mill, (2) drying the raw materials ball-milled in step (1), screening the raw materials with a 40-mesh sieve to form even grained powder, (3) calcining the powder in step (2),(4) performing secondary ball milling, drying and pelletizing on the ceramic powder prefired in step (3), screening the ceramic powder with a 60-mesh sieve, pressing the powder into a green body through a powder compressing machine, and (5) sintering the green body in step (4) at 1260-1320 DEG C for 3-6h to form the magnesium-zircon-germanium-niobium microwave dielectric ceramic. The microwave dielectric ceramic is applied in the field of communication. According to the microwave dielectric ceramic, the very excellent microwave dielectric property can be obtained only by partially replacing zircon ions with micro germanium ions.
Owner:TIANJIN UNIV

Reversible photochromic transparent ceramic as well as preparation method and application thereof

ActiveCN114149262AColor changing high contrastFast coloring/restoration response timeLight protection screensTenebresent compositionsChemical compositionCeramic chemistry
The invention relates to the technical field of ceramic materials, in particular to reversible photochromic transparent ceramic as well as a preparation method and application thereof. The chemical composition of the reversible photochromic transparent ceramic is Ba (AxMgyBz) O3, wherein A is selected from at least one of Zr, Sn, Ti and Hf; b is selected from at least one of Ta and Nb; 4x + 2y + 5z = 4, x is greater than 0 and less than 1, y is greater than 0 and less than 1, and z is greater than 0 and less than 1. The reversible photochromic transparent ceramic disclosed by the invention has the characteristic of reversible conversion from grey white to brown. The Ba (AxMgyBz) O3 photochromic ceramic changes color under the condition of irradiation of about 365 nm and can restore to the original shape under the condition of irradiation of about 450 nm or heating, and the reversible photochromic transparent ceramic is high in color change contrast.
Owner:SONGSHAN LAKE MATERIALS LAB +1

Organic dye-infrared up-conversion luminescent transparent ceramic composite material and preparation method thereof

The invention, on one aspect, provides an organic dye-infrared up-conversion luminescent transparent ceramic composite material, which is composed of an organic dye and an infrared up-conversion luminescent transparent ceramic. The composite material is an organic matter with a strong absorption effect on near-infrared light with a wavelength of 780nm-1100nm. The chemical formula of the infrared up-conversion luminescent transparent ceramic is (HoxYbyY1-x-yZr0.03)2O3, wherein x is greater than or equal to 0.0005 and less than or equal to 0.02, and y is greater than or equal to 0.005 and less than or equal to 0.2. And the composite material is uniformly coated on a surface of the infrared up-conversion luminescent transparent ceramic. According to the material, organic dye molecules with strong absorption and long excited state service life in an infrared region are used as a sensitizing layer to absorb infrared light firstly, and then excited state electrons are transferred to a <2>F5 / 2 excited state energy level of Yb<3+> ions through resonance energy transfer, so that infrared up-conversion luminescence enhancement is realized. The up-conversion luminescent transparent ceramic Ho<3+> / Yb<3+>:Y2O3 and the preparation method thereof have important application in biomedicine and infrared sensing.
Owner:北京科易达知识产权服务有限公司

Low temperature sintered microwave dielectric ceramics and its preparing method

The present invention relates to low temperature sintered microwave dielectric ceramic and its preparation process, and belongs to the field of microwave dielectric ceramic technology. The material has the composition of Li2+xNb3xTi1-4xO3+yB2O3, where 0 C04B 35 / 462 C04B 35 / 622 H01B 3 / 12 1 8 2 2006 / 3 / 9 1821171 2006 / 8 / 23 100378031 2008 / 4 / 2 2008 / 4 / 2 2008 / 4 / 2 Shanghai Inst. of Ceramic Chemistry and Technology, CAS Shanghai 200050 Li Wei Zeng Qun Shi Jianlin Wu Wenjun Guo Jingkun
Owner:SHANGHAI INST OF CERAMIC CHEM & TECH CHINESE ACAD OF SCI

A kind of tin-doped lead lanthanum zirconate titanate thick film ceramics and its preparation and application

The invention provides a tin-doped lead lanthanum zirconate titanate thick film ceramic and its preparation and application, belonging to the technical field of energy storage ceramic materials. The tin-doped lead lanthanum zirconate titanate thick-film ceramic has a chemical composition conforming to the general chemical formula Pb 0.94 La 0.06 (Zr 0.95~x Sn x Ti 0.05 ) 0.985 O 3 , where 0.05≦x≦0.15. The preparation method includes the following steps: (1) weighing each raw material in proportion, mixing, ball milling, drying, sieving and calcining to obtain a sintered product; (2) subjecting the sintered product to high-energy ball milling, drying and sieving to obtain fine particles Powder; (3) Mixing the fine powder with dispersant and solvent, tumbling, adding binder and tumbling, then adding dispersant, binder, solvent and plasticizer, and tumbling to obtain casting slurry ; (4) Casting the casting slurry to obtain a thick film green body, sintering, that is, obtained. The tin-doped lead lanthanum titanate ceramic thick film can withstand an electric field strength of 400 kv / cm, significantly improves the energy storage density and energy storage efficiency of the ceramic thick film, and has wide application prospects.
Owner:GUANGDONG UNIV OF TECH

Stoichiometric mismatched high-energy-storage silver niobate-based ceramic and preparation method thereof

ActiveCN113213927AChange the stoichiometric ratioLow costHybrid carDielectric
The invention discloses stoichiometric mismatched high-energy-storage silver niobate-based ceramic and a preparation method thereof, wherein the chemical formula of the ceramic is Ag[0.985] La[0.005]Nb[1-x]O[3-2.5x], x is molar percentage, and the value of x meets the electric neutrality. Under the condition of not introducing other elements, the high-energy-storage lead-free antiferroelectric ceramic with the maximum energy storage density of 7.05 J / cm<3> (the value is the maximum value in the research field) can be obtained only by reducing the niobium ion content and changing the stoichiometric ratio of the material; and the lead-free energy storage ceramic has the advantages of high energy storage density, high breakdown electric field (318 kV / cm), high polarization intensity (74 [mu]C / cm<2>) and the like, and is expected to be applied to the fields of novel dielectric energy storage devices, pulse power devices, hybrid electric vehicles and the like. Particularly, experiments prove that under the condition that other elements are not introduced, only the innovative idea of changing the stoichiometric ratio of the material is an effective new method in research of the silver niobate-based lead-free energy storage ceramic, and the idea can be applied to the field of other dielectric energy storage research.
Owner:NANJING UNIV OF POSTS & TELECOMM

High-dielectric low-loss doped barium calcium titanate ceramic and preparation method thereof

PendingCN114853468AGood dielectric temperature stabilityLower sintering temperatureFixed capacitor dielectricBarium titanateHigh energy
The invention relates to a high-dielectric low-loss doped barium calcium titanate ceramic and a preparation method thereof, and belongs to the technical field of inorganic non-metallic materials. The lead-free, non-volatile and toxic element-free doped barium calcium titanate ceramic is prepared by adopting a traditional solid-phase reaction method, the chemical formula is Ba0. 70Ca0. 30Ti1-x (Nb0. 5Fe0. 5) xO3, x is the mole number of (Nb0. 5Fe0. 5) 4 < + > and is larger than or equal to 0.04 and smaller than or equal to 0.06, and the material is simple in preparation process, low in cost, low in sintering temperature (1230-1300 DEG C), larger than 4100 in room temperature relative dielectric constant and low in dielectric loss (tan delta lt below 1kHz); 0.037), the dielectric temperature stability is good (the change rate 1t of the relative dielectric constant along with the temperature in the range of room temperature to 200 DEG C; the preparation method is suitable for preparing a high-energy density memory and a high-capacity capacitor, and has a relatively high industrial application value.
Owner:HARBIN UNIV OF SCI & TECH

High-dielectric microwave dielectric ceramic and preparation method thereof

The invention discloses a high-dielectric microwave dielectric ceramic and a preparation method thereof, the chemical composition expression of the ceramic is aLi2O.bCoO.cLn2O3.dNb2O5.eCeO2 (I), and Ln is equal to Y, La or Sm. The microwave dielectric ceramic contains oxides of rare earth elements Y, La or Sm and has good microwave dielectric properties, and the microwave dielectric ceramic obtained by sintering the two oxides of the rare earth elements, Nb2O5 and CeO2 together has good microwave dielectric properties.
Owner:苏州研资工业技术有限公司

Microwave dielectric ceramic and preparation method thereof

The invention discloses a microwave dielectric ceramic and a preparation method thereof, the chemical composition expression of the ceramic is aCaO.bSrO.cLn2O3.dNb2O5.eTiO2 (I), and Ln is equal to Y, Nd or Sm. The microwave dielectric ceramic contains rare earth element oxides of Y, Nd or Sm, and has good microwave dielectric properties, and the microwave dielectric ceramic obtained by sintering the two rare earth element oxides, Nb2O5 and TiO2 and performing combined action has good microwave dielectric properties.
Owner:苏州研资工业技术有限公司

Method for promoting cold sintering of potassium-sodium niobate-based leadless piezoelectric ceramics

The invention discloses a method for promoting cold sintering of potassium-sodium niobate-based leadless piezoelectric ceramics through heat treatment of powder in a reducing atmosphere. The method comprises the following steps: firstly preparing potassium-sodium niobate powder, then carrying out heat treatment in a reducing atmosphere to improve the wettability of the powder and promote cold sintering, then adding deionized water into the potassium-sodium niobate powder, performing grinding, carrying out molding at a set temperature and uniaxial pressure, and then carrying out drying and sintering to obtain the KNN ceramic with excellent performance. The method is simple in process step and easy to operate, the wettability of the powder surface is improved, the problem that a liquid phase is not uniformly distributed on the surfaces of KNN particles in a conventional cold sintering process is solved, the surfaces of the KNN particles are wrapped with a potassium-rich phase more completely, volatilization of K and Na elements is effectively inhibited, deviation of a stoichiometric ratio of the KNN ceramic is reduced, and the performance of the potassium-sodium niobate-based ceramics is improved.
Owner:FUZHOU UNIV

Fe-doped CuAlO2 high-temperature wave-absorbing ceramic and preparation method thereof

The invention discloses Fe-doped CuAlO2 high-temperature wave-absorbing ceramic and a preparation method thereof, and belongs to the technical field of wave-absorbing material preparation. According to the preparation method, Fe is used for doping CuAlO2 to change the conductivity and electromagnetic parameters of CuAlO2 and to generate CuAl<1-x>Fe<x>O2 powder with x smaller than or equal to 0.2,and firing is further performed to form the ceramic. By adopting a Cu source substance, an Al source substance and a Fe source substance as reactants, a ball-milling grinding process and a pre-sintering sintering glue discharging process are matched, and finally the Fe-doped CuAlO2 high-temperature wave-absorbing ceramic is prepared. The preparation method is good in process stability, wide in rawmaterial application range and low in cost, and can be popularized to macro production of the material. The Fe-doped CuAlO2 high-temperature wave-absorbing ceramic prepared by the preparation methodhas a chemical formula of CuAl<1-x>Fe<x>O2, wherein x is smaller than or equal to 0.2, and due to introduction of Fe, the CuAl<1-x>Fe<x>O2 ceramic has relatively large dielectric loss, magnetic property and high-temperature resistance, so that the finally prepared Fe-doped CuAlO2 high-temperature wave-absorbing ceramic has high temperature resistance and excellent wave-absorbing property, and canbe widely applied to high-tech industries such as space flight and aviation.
Owner:SHAANXI UNIV OF SCI & TECH

Polycrystalline YAG ceramic chemical mechanical polishing solution

The invention discloses a polycrystalline YAG (yttrium aluminum garnet) ceramic chemical mechanical polishing solution, and belongs to the technical field of precision / ultra-precision machining. The pH value of the polycrystalline YAG ceramic chemical mechanical polishing solution is 7, and the polycrystalline YAG ceramic chemical mechanical polishing solution comprises a solute and a solvent, wherein the solvent is deionized water. The polishing solution comprises the following components in percentage by mass: 10-30wt% of silica sol, 1-5wt% of aluminum oxide abrasive particles, 0.1-0.5 wt% of an abrasive particle dispersing agent and a proper amount of a pH (Potential of Hydrogen) regulator according to the total mass fraction of 100%, and all the substances are uniformly mixed in deionized water through ultrasonic waves. By adopting the polishing solution, the ultra-smooth polishing of the polycrystalline YAG ceramic can be realized, the grain boundary height difference of the polished polycrystalline YAG crystal surface is obviously reduced, and the ultra-smooth and damage-free polycrystalline YAG crystal surface can be obtained; the grain boundary height difference can be effectively inhibited, and the purpose of super-smooth surface is achieved; and in addition, by adopting the polishing solution provided by the invention, the material removal efficiency is high, and compared with a polishing solution only containing silica sol or aluminum oxide, the removal efficiency is obviously improved.
Owner:DALIAN UNIV OF TECH +1
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