The invention discloses a degradable low-temperature co-fired ceramic, which is a ceramic material mainly composed of borosilicate inorganic polymer molecular structure, and its composition chemical formula is xB 2 o 3 ·ySiO 2 · zAl 2 o 3 ·wMO, where MO is MgO, CaO, SrO, BaO, Na 2 O, Al 2 o 3 、K 2 At least one of O, ZnO or rare earth element oxides, x, y, z, w are mass percentages, 20wt%≤x≤65%, 15%≤y≤65%, 0%≤z≤30%, 0 %≤w≤30%. The preparation method of the ceramic is based on SiO 2 , SiO 2 ·nH 2 O, H 3 BO 3 , B 2 o 3 , NaOH, KOH, Ba(OH) 2 ·8H 2 O, Al(OH) 3 , MgO, CaO, SrO, ZnO and rare earth oxides as raw materials, through ball milling, drying, grinding, calcination, granulation, molding and sintering process steps. The degradable ceramic can not only be co-fired with electrode materials such as silver, copper and gold, but also can be co-fired with low-melting-point metal electrodes such as aluminum. Based on its unique borosilicate-rich inorganic polymeric structure as the hydrolysis trigger phase, through the control of the chemical composition of the ceramic and the design of the dispersion distribution of the hydrolysis trigger phase in the structure, the ceramic can degrade itself in humid conditions, water and salt solutions.