The invention relates to the technical field of glass, and particularly discloses four-silver glass and a preparation method thereof. The four-silver glass sequentially comprises a substrate SiNx base layer, a first functional layer, a first AZO
metal protective layer, a first composite
dielectric layer, a second functional layer, a second AZO
metal protective layer, a second composite
dielectric layer, a third functional layer, a third AZO
metal protective layer, a third composite
dielectric layer, a fourth functional layer, a fourth AZO metal protective layer and a SiNx protective layer. A non-steel four-silver
glass structure is formed by a SiNx base layer, a first functional layer, a first AZO metal protective layer, a first composite
dielectric layer, a second functional layer, a second AZO metal protective layer, a second composite
dielectric layer, a third functional layer, a third AZO metal protective layer, a third composite
dielectric layer, a fourth functional layer, a fourth AZO metal protective layer and a SiNx protective layer. And when being applied to single hollow glass with the
transmittance of 61%, the glass has a good
shading coefficient, meanwhile, the transmission color is not in a greenish state, and the transmission effect is effectively ensured.