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60results about "Calcium/strontium/barium halides" patented technology

Method for preparing high-purity magnesium oxide with high boron salt lake brine

Provided is a method for preparing high-purity magnesium oxide with high boron salt lake brine. Salt lake brine is evaporated through a salt pan, concentrated to crystallize potassium sulfate, sodium chloride and potassium chloride and is drawn with lithium in adsorption mode so as to obtain master sauce brine containing magnesium and boron. Concentrated sulfuric acid is added into master sauce brine for reacting, and coarse boracic acid and acidized brine are obtained after cooling and filtering. Potential of hydrogen (pH) value of acidized brine is adjusted to be 5.5-6.5, and acidized brine passes through ion exchange resin adsorbing boron. When boron concentration in effluent liquid is higher than 5 mg / L, brine is not injected, boron-removed brine is obtained, then boron-removed brine and ammonium chloride solution are filled with ammonia for stirring and to produce magnesium sedimentation reaction, reaction temperature ranges from 60 DEG C to 80 DEG C, pH ranges from 7.5 to 8.0, the reaction is stopped when concentration of free ammonia reaches 1.8-2.2 mol / L, and magnesium hydroxide and magnesium sedimentation mother solution are obtained. Magnesium oxide is obtained by calcining magnesium hydroxide, content of magnesium oxide is larger than 99.8%, and magnesium extraction ratio is larger than 90%. Sedimentation mother solution adopts lime to steam ammonia, and generated ammonia circulates to magnesium sedimentation reaction. Mother solution after ammonia steaming is evaporated, concentrated and crystallized to obtain calcium chloride. Ion exchange resin adsorbing boron is washed, analyzed and regeneratively cycled for use. Boron-containing analysis solution is concentrated and cooled to pick up coarse boracic acid, and coarse boracic acid is recrystallized to obtain refined boracic acid with purity larger than 99%. High-purity magnesium oxide prepared by the method is high in purity, good in economic benefit, free of environment pollution, strong in operability and favorable for industrial production.
Owner:CENT SOUTH UNIV

Method for preparing high-purity anhydrous strontium iodide

The invention relate to a method for preparing high-purity anhydrous strontium iodide. The method comprises the following steps: dropwise adding hydroiodic acid into a reaction vessel containing an aqueous solution containing a strontium compound under stirring until the pH of the solution is 5-6 to obtain an iodide-strontium aqueous solution; regulating the pH value of the iodide-strontium aqueous solution to 7-9 for filtering; after concentrating filtrate to near saturation, quickly lowering the temperature to 0-4 DEG C and precipitating crystal substances; filtering to obtain the crystal substances dissolving in water, and obtaining a purified iodide-strontium aqueous solution; heating the purified strontium iodide aqueous solution to 150-200 DEG C under the flowing inert shielding gas, and preserving heat for 1-30 hours to dehydrate to obtain a SrI2.xH2O white flurry material, wherein x is less than or equal to 1; grinding the white flurry material into powder in an anhydrous and oxygen-free inert atmosphere, and putting in a glass vessel; under vacuum, heating the glass vessel to 350-450 DEG C and preserving heat for 1-20 hours to remove crystal water in the powder, and naturally lowering the temperature to room temperature in the condition of keeping vacuum; heat-sealing the glass vessel in the condition of keeping vacuum.
Owner:SHANGHAI INST OF CERAMIC CHEM & TECH CHINESE ACAD OF SCI
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