The invention discloses an electro-Fenton-auto-oxidation device for treating microelectronic
wastewater, the device comprises a water inlet
system and a method thereof, a reactor shell, a combined
cathode, an
anode, a power supply, an
aeration system, a water outlet
system and a Fe<2+> adding system, and the combined
cathode comprises a membrane frame and a
stainless steel wire mesh. When the device disclosed by the invention is used for treating microelectronic
wastewater, the working state of the
aeration system and the feeding amount of Fe<2+> can be adjusted according to the concentration change of H2O2 in inlet water, so that high-efficiency
decomposition of H2O2 is realized, and residual
refractory organic matters in the
wastewater are oxidized and removed by effectively utilizing strong oxidizing substances generated in the
decomposition process; when the
decomposition rate of H2O2 in a
reaction system is too high and supply is insufficient, dissolved
oxygen generates H2O2 on the surface of a
cathode material through intermittent
aeration, and H2O2 self-compensation is realized; according to the device and the treatment method, the decomposition of H2O2 in the microelectronic wastewater and the synchronous removal of
refractory organic matters can be efficiently realized with low consumption.