2results about How to "Avoid carbon formation" patented technology

This invention discloses a two-step hydrothermal method for preparing nickel-iron bimetallic MOF derivatives and its application. By controlling the precursor structure through a two-step hydrothermal strategy, the nickel-iron bimetallic MOF derivative catalyst forms a foam-like hierarchical porous carbon framework. The metal nanoparticles are uniformly dispersed, small in size, and encapsulated by carbon layers, significantly improving the specific surface area and accessibility of active sites. It exhibits excellent hydrogen yield and anti-carbon deposition performance in plastic pyrolysis tar reforming. The synergistic effect of nickel and iron electrons effectively inhibits metal sintering and carbon deposition, and has good catalytic stability. This invention solves the problem in existing nickel-iron bimetallic MOF derivatives where phase separation easily occurs in one-step synthesis due to the difference in nucleation and growth rates between nickel and iron ions and organic ligands, leading to uneven metal distribution, increased particle size, underdeveloped pore structure, and low accessibility of active sites, thus affecting catalytic reforming activity and anti-carbon deposition ability.

This invention focuses on the application of a PtZn / Al2O3 bimetallic catalyst in the propane dehydrogenation reaction. A uniquely structured mixed oxide support was synthesized through a co-precipitation strategy incorporating an appropriate amount of silicon (Si), and metallic Pt was loaded using an equal-volume impregnation method. Benefiting from the uniform dispersion of Zn, Pt is atomically dispersed on the surface of Zn nanoclusters, improving metal utilization and catalytic efficiency. The introduction of Si significantly optimizes the metal-support interaction, greatly enhancing the catalyst's activity and stability. With catalyst particles of 20-40 mesh, it exhibits excellent catalytic performance, along with good high-temperature stability and resistance to carbon deposition. This preparation process is simple, reproducible, and achieves efficient and highly selective propylene production with low amounts of precious metals, demonstrating promising industrial application prospects.