The invention provides a high-temperature-resisting structural
adhesive film capable of being stored for a long time at the
room temperature and a preparation method thereof and relates to a structural
adhesive film and a method for preparing the
adhesive film. The structural adhesive film and the method for preparing the adhesive film aim to solve the problems that an existing structural adhesive film is short in
room temperature storage life, and combusted
smoke is high in
toxin. The adhesive film is composed of polybenzoxazine resin, a
toughening agent, modifier, a heat conduction material, a
coupling agent,
inorganic filler and a carrier. The preparation method includes the steps that firstly, process modifier and
toughening modifier are subjected to prepolymerization in a reaction kettle, then the polybenzoxazine resin is added and stirred to be uniform, and modified polybenzoxazine resin is obtained; then, the modified polybenzoxazine resin is subjected to vacuum kneading with the
silane coupling agent, the heat conduction material and the
inorganic filler through a kneading
machine, and an adhesive material is obtained; finally, the adhesive material is subjected to
hot pressing with the carrier on an adhesive film calender to be made into the film, and the high-temperature-resisting structural adhesive film can be obtained. The high-temperature-resisting structural adhesive film has the advantages of being
flame retardant, low in
smoke, low in
toxin, capable of achieving complete curing at the temperature of 185 DEG C, high in
adhesion strength and good in high
temperature resistance; the adhesive film is stored for 180 days at the
room temperature, and process performance and adhesion performance maintain unchanged.