The invention discloses a carbon-fiber-reinforced polytetrafluoroethylene composite material for valve sealing and a preparation method of the carbon-fiber-reinforced polytetrafluoroethylene composite material for valve sealing. The carbon-fiber-reinforced polytetrafluoroethylene composite material for valve sealing is characterized by being prepared from, by weight, 2-3 parts of carbon fibers, 5-10 parts of carbon nano tubes, 10-15 parts of ethyl alcohol, 25-35 parts of polytetrafluoroethylene emulsion, an appropriate amount of acetic acid, 15-25 parts of hydrofluoric acid, 15-25 parts of nitric acid, 1-2 parts of lanthanum chloride, 4-6 parts of silane coupling agent KH550, 2-3 parts of edetic acid, 1-2 parts of Fe(NO3)3, 1-2 parts of Co(NO3)3, an appropriate amount of ammonium hydroxide, an appropriate amount of nickel foam, 3-5 parts of diamond, 5-7 parts of dodecyltrimethylammonium bromide, an appropriate amount of methane, an appropriate amount of argon, an appropriate amount of nitrogen and100-150 parts of distilled water. The carbon-fiber-reinforced polytetrafluoroethylene composite material for valve sealing has the advantages that the nickel foam in a three-dimensional form serves as polymer filler, so that mechanical performance of the composite material is improved, and the added carbon nano tubes can be distributed more evenly; through treatment of the carbon fibers, surface wettability is improved and the interface adhesion quality of the composite material is improved.