The invention belongs to the technical field of enamel material, and specifically relates to a vanadium-titanium enamel glaze material, and a preparation method thereof. The preparation method is used for solving technical problems that cost of a conventional vanadium-titanium enamel glaze material is high, glossiness of enamel glaze obtained via sintering is not high enough, fishscaling is observed, and acid and alkali resistance is not high enough. The vanadium-titanium enamel glaze material is prepared from, by mass, 22 to 28 parts of pretreated vanadium-titanium magnetite titanium separation tailing or vanadium-titanium boundary ore, 20 to 22 parts of feldspar powder, 5 to 8 parts of quartz sand, 24 to 26 parts of borax, 1.5 to 2 parts of sodium nitrate, 3.5 to 5.5 parts of lithium carbonate, 5 to 7 parts of fluorite powder, 0.1 to 0.3 part of sodium fluosilicate, 3 to 5 parts of cryolite, 2 to 4 parts of limestone, 3 to 4 parts of cobalt nitrate, 1 to 2 parts of nickel nitrate, 2 to 3 parts of sodium vanadate, and 1 to 2 parts of antimony oxide. Firm combination of the vanadium-titanium enamel glaze material with carbon steel billet can be realized; acid and alkali resistance is higher than that stipulated by national standard; and the vanadium-titanium enamel glaze material can be used for a plurality of matrixes such as hot-rolled carbon steel and cast iron.