The invention relates to a corona-resistant groove insulation material and a preparation method thereof. The groove insulation material sequentially comprises a first adhesive layer, a first mica paper layer, a second adhesive layer, a film layer, a third adhesive layer, a second mica paper layer and a fourth adhesive layer from top to bottom, wherein the first adhesive layer, the second adhesive layer, the third adhesive layer and the fourth adhesive layer are respectively formed by nano modified adhesive, the nano modified adhesive is the adhesive which is mixed with nano powder body, the content of the nano powder body in the nano modified adhesive is 15 to 25 percent, and the granularity of the nano powder body is 20nm to 100nm. The corona-resistant service life of the insulation material can be improved by more than 50 times compared with the existing groove insulation material; and meanwhile, the paint quantity in the resin immersing process can be increased, and the mechanical property and the electric insulation performance of a curing system can be improved. In addition, the cost of the groove insulation material is lower, so that the industrialized mass production and popularization of the groove insulation material can be favored.