The application discloses a
glassy carbon gradient-coated hard carbon negative
electrode material and a preparation method and application thereof. The preparation method comprises the following steps: S1, uniformly mixing hard carbon
powder and / or hard carbon precursor
powder with
furan resin
powder to obtain a composite precursor powder; and S2, sequentially performing low-temperature melting
quenching treatment and sectional type temperature rising
carbonization treatment on the composite precursor powder to obtain the hard carbon negative
electrode material. The preparation method is simple in operation, can integrally form a glassy gradient
carbon layer with gradient distribution of density, pore size and content of heteroatoms on the surface of the hard carbon, the dense inner layer can precisely block the defects on the surface of the hard carbon, inhibit the
electrolyte side reaction, the porous outer layer can construct a rapid
transmission channel for ions and electrons, and the gradient distribution of the content of the heteroatoms is beneficial to the regulation of the interface
electron structure and the induction of the formation of a stable SEI film. The
sodium ion battery constructed by the hard carbon negative
electrode material exhibits high charging specific capacity, high first-cycle coulombic efficiency and excellent cycle stability.