A metal sulfide-coated single-walled carbon nanotube nanocable and a synthesis method thereof, relating to a cable and a synthesis method thereof, which are prepared in situ by a chemical vapor deposition (CVD) thermal reaction method; graphite, catalyst, and Sulfur growth promoter, silicon powder, metal powder or metal compound powder are compressed; an inert atmosphere is used as a protective atmosphere and carrier gas, and graphite, catalyst, sulfur-containing growth promoter, and silicon powder are reacted to form single-walled carbon nanotubes; sulfur-containing growth promotion The agent reacts with metal powder or metal compound powder to form metal sulfide, and the single-walled carbon nanotubes and metal sulfide clusters leave the surface of the raw material and flow to the low temperature area; during this process, the metal sulfide clusters are coated on the single-walled carbon nanotubes. tube surface. The cable has excellent photoelectrochemical properties, and the core of the cable is only composed of one or several single-walled carbon nanotubes, which is conducive to the exertion of the nanoscale electrical effect of the single-walled carbon nanotubes, and reflects more excellent novel characteristics.