The invention belongs to the technical field of 
negative temperature coefficient thermistors, and in particular relates to an in-situ-generated layered composite 
negative temperature coefficient thermosensitive 
ceramic material, a preparation method and an application thereof.  The structure of the heat-sensitive 
ceramic material is a base layer, a 
transition layer, and a sensitive layer in sequence, wherein: the base layer is composed of a 
perovskite phase or a doped 
perovskite phase, and the sensitive layer is composed of a sharp  
Crystal phase or doped 
spinel phase, the composition of the 
transition layer is: 
perovskite phase or doped perovskite phase and 
spinel phase or doped 
spinel mixed in equal volumes  mixture.  Introducing the cold spraying technology into the preparation of 
layered structure composite heat-sensitive ceramics, the in-situ generation of layered composite 
negative temperature coefficient heat-sensitive 
ceramic materials was prepared, which overcomes the shortcomings of traditional methods and realizes the sensitivity to the thickness of the sensitive layer and the 
microstructure of the material.  The effective control of NTC is of great significance for the preparation of NTC thermosensitive 
ceramic materials with 
low resistance, high B value and high stability for suppressing surge current.