A control valve of a deep-water blowout preventer belongs to the field of deep-water oil-drilling equipment. The control valve consists of a guide control valve and an electromagnetic control valve, wherein the electromagnetic control valve is arranged in the guide control valve. The electromagnetic control valve consists of a cable plug (1), an upper valve seat (2), a bolt (3), a gland (4), an electromagnetic valve body (5), a guide valve body (6), a sealing ring (7), an electromagnetic valve body (8), an isolating ring (9), a compression spring (10), a magnetic conductive ring (11), an electromagnetic coil (12), an iron core (13), an electromagnetic coil slot (14), a lower valve seat (15), a filter grate (16), a fastening nut (17), a screw plug (18) and a head contact pin (19). The control valve has the advantages of compact structure, reliable working, long life and reliable sealing. The electromagnetic control valve bodies are not under the action of the deep-water pressure directly. The iron core and a valve core of the electromagnetic control valve are integrated, and the response speed of a control circuit can be greatly improved.