The present invention discloses a chromium-free passivation liquid for treating a tin-plated steel plate, wherein the pH value of the chromium-free passivation liquid is 3-4. The chromium-free passivation liquid comprises an inorganic compound containing at least one selected from silicon, titanium and zirconium, a metal compound containing at least one selected from aluminum, vanadium, manganese, cobalt, nickel and molybdenum, a soluble resin, an acid for adjusting the pH value of the passivation liquid to 3-4, and the balance of water and other unavoidable impurities, wherein the contents of silicon, titanium and zirconium are 0.1-20 g/L, the contents of aluminum, vanadium, manganese, cobalt, nickel and molybdenum are 0.1-20 g/L, and the soluble resin content is 0.1-20 g/L. The tin-plated steel plate treated by the chromium-free passivation liquid obtained with the technical scheme has characteristics of excellent corrosion resistance, excellent sulfurization resistance, excellent coating material adhesion and excellent processability.