The invention provides a silver plating solution with high sulfur resistance performance, including AgNO 3 25~40g / L, KI 370~420g / L, K 2 CO 3 1~5g / L,K 2 C 2 o 4 1~5g / L and water, and Cu(NO 3 ) 2 ·3H 2 O, C 25 h 22 Au 2 Cl 2 P 2 , Al[CH 3 (CH 2 ) 16 CO 2 ] 3 , (NH 4 ) 2 Mo 2 o 7 、Na 3 o 40 PW 12 ·xH 2 O, ZnI 2 and NiI 2 At least two of the In the silver plating solution provided by the present invention, metal ions such as copper, gold, aluminum, molybdenum, tungsten, zinc or nickel can be compounded into the silver plating layer through compounding of multi-metal ions in the silver plating process to form new composite oxides surface layer, thereby improving the anti-sulfurization performance of the silver plating surface. Experimental result shows, coating provided by the present invention is in 5% Na 2 The change in contact resistance of S after soaking for 5 days was small.