The invention belongs to the technical field of powder paint, particularly relates to a compound curing agent used for polyester-type powder paint, and further discloses a production method and application of the compound curing agent used for the polyester-type powder paint. The compound curing agent used for the polyester-type powder paint is mainly produced by using trimesic acid,tris(2,3-epoxypropy)ester and diglycidyl terephthalate as main raw materials and selectively adding 1,2,4-benzenetricarboxylic acid,tris(2,3-epoxypropy)ester, hydroxy polyester resin, bicyclopentadiene dioxide and/or crystalline epoxy resin for mixing reaction. The compound curing agent used for the polyester-type powder paint has a good curing effect, the mechanical performance of a produced coating is stable,and meanwhile, the coating has good boiling-resistant performance; and when the compound curing agent used for the polyester-type powder paint and polyester resin are cured, the performance of a product of the compound curing agent used for the polyester-type powder paint and the polyester resin totally reaches curing effects of current TGIC and HAA curing agents, and the compound curing agent used for the polyester-type powder paint and an existing TGIC or HAA product can be mixed for use, so that the comprehensive performance is more excellent.