The invention discloses an extended-range electric vehicle power coupling thermal control system and a control method thereof, and the system comprises four cooling liquid loops which are an engine heating loop, an engine heat dissipation loop, a power battery heating loop and a power battery heat dissipation loop in sequence. The engine heating loop comprises an engine, a first electronic thermostat, a first electric water pump and a first temperature sensor which are sequentially connected in series; the engine heat dissipation loop comprises an engine, a first electronic thermostat, a heat exchanger, a first radiator, a first electric water pump and a first temperature sensor which are sequentially connected in series. The power battery heating loop comprises a power battery, a second electronic thermostat, a heat exchanger and a second electric water pump which are sequentially connected in series; the power battery heat dissipation loop comprises a power battery, a second electronic thermostat, a second radiator, a second electric water pump and a second temperature sensor. According to the system, rapid preheating and accurate temperature control of the power battery and the engine are realized, and the energy utilization rate of the whole vehicle is effectively improved.