The invention discloses a preparation method of a
lithium ion battery having high initial coulombic efficiency. The
lithium ion battery having high initial coulombic efficiency is prepared through the following working procedures: proportioning a positive pole active substance and a negative pole active substance,
coating, rolling, slitting, baking, die-
cutting, coiling, assembling and injecting, wherein the negative pole active substance is an artificial
graphite material; and the negative pole active substance is subjected to
lithium-doped modification treatment through the steps of solution preparation, active substance mixing, heating and
drying. According to the invention, the negative pole active substance is subjected to lithium-doped modification treatment, and the
lithium ion battery having high initial charge /
discharge efficiency is provided. The positive pole material is not definitely restricted in the invention, thereby widening the application range. The
lithium ion battery disclosed by the invention has the advantages of high capacity, stable cycle performance and high initial coulombic efficiency.