The invention provides a preparation method of spherical nano
cerium dioxide. The preparation method comprises the following steps: respectively dissolving
cerium salt and alkali in an
organic solvent, then mixing the two solutions, and carrying out
precipitation reaction; after the
precipitation reaction is completed, adding a high-molecular
polymer into a
reaction system, and stirring to obtain a reaction mixture; carrying out high-speed shearing dispersion on the obtained reaction mixture at the temperature of 40-220 DEG C for 30 min-48 h, and continuously blowing oxidizing gas into the
reaction system during the high-speed shearing dispersion; and centrifugally separating the obtained product to obtain a
solid, washing and
drying to obtain the spherical nano
cerium dioxide. According to the method disclosed by the invention, the monodisperse spherical nano CeO2 with the particle size of 40 nm-200 nm can be prepared; meanwhile, the method disclosed by the invention has the characteristics of high process stability, high yield, high
operability and the like, and is suitable for large-scale production.