The invention provides a visual array chip for gas analysis and application thereof. According to the visual array chip, functional modules from No.1 to No.36 are arranged on a substrate according to an array distribution mode, and the functional modules are prepared by coating the substrate with porphyrin and dye modified by gold nano-particles, porous organic silicate, plasticizer and materials having specific response to aldehyde volatile organic compounds. The visual array chip can be used for detecting and analyzing at least one volatile gas in benzene, methylbenzene, p-xylene, trimethylbenzene, trichlorofluoromethane, propyl aldehyde, hexanal, acetaldehyde, heptanal, acetone, 2-pentanone, tetrahydrofuran, heptane, decane, undecane, 1-hexene, isoprene, styrene, acetic acid, propionic acid, ethylenediamine, tetramethylethylenediamine, acetonitrile, propyl alcohol, thiol and butyl acetate compounds. The chip can be used for detecting multiple gas ingredients, has high sensitivity for detected objects with low detection limit, and can reach the ppbv detection level.