The invention discloses silicon-free softening and dandruff removing shampoo. The silicon-free softening and dandruff removing shampoo is prepared from the following raw materials: ammonium dodecyl alcohol ether sulfate, sodium cocoyl glycinate, cocamidopropyl betaine, glycerol, jojoba oil, decyl glucoside, lead subcarbonate, a dandruff removing agent, a non-ionic surfactant, cocamide MEA (mono ethyl amine), a chamomile extract, guar hydroxypropyltrimonium chloride, p-hydroxyacetophenone, hexanediol, polyquaternium-10, polyquaternium-7, panthenol, a wheat gluten extract, a sesame seed extract,a chelating agent and deionized water. According to the silicon-free softening and dandruff removing shampoo disclosed by the invention, the ammonium dodecyl alcohol ether sulfate is used as a main surfactant and is matched with the sodium cocoyl glycinate as an auxiliary surfactant; then the ammonium dodecyl alcohol ether sulfate and the sodium cocoyl glycinate are matched with the cocamidopropyl betaine, the glycerol, the jojoba oil and the decyl glucoside as well as a lot of conditioners to prepare the shampoo with an excellent softening effect; and then the dandruff removing agent OCT isadded, and the cocamidopropyl betaine is combined to the dandruff removing agent OCT, so that the silicon-free softening and dandruff removing shampoo has a good dandruff removing effect.