The invention relates to the field of temperature monitoring devices of mass concrete, and particularly relates to a mass concrete wireless automatic temperature measurement device with a temperatureself-compensating function and application thereof. The device comprises an NTC temperature sensor, a data acquisition module, a data storage module, a data processing module, a wireless data transmission module, and a display device, wherein the NTC temperature sensor is arranged on a temperature monitor point inside concrete, the data acquisition module is connected with the sensor through a three-core cable, the data storage module is connected with the data acquisition module, the data processing module is used for packaging and processing data, a signal input end of the data processing module is connected with both the data acquisition module and the data storage module, an output end of the data processing module is connected with the wireless data transmission module, the wireless data transmission module is used for sending information obtained from the data processing module to a control center, and the display device displays the information. According to the temperature measurement device, the NTC temperature sensor is used for wireless automatic monitoring of mass concrete temperature for the first time, and when temperature does not need compensating, mass concrete temperature is monitored remotely, accurately, efficiently and intelligently.