This utility model discloses a
system for removing impurities from carbon-containing chlorosilanes and recovering chlorosilanes, comprising: a first
distillation column for receiving and concentrating carbon-containing chlorosilanes; a first adsorption and reaction device connected to the first
distillation column, the first adsorption and reaction device being filled with a
metal adsorbent material and equipped with a
silicon tetrachloride feed pipeline; a second adsorption and reaction device connected to the first adsorption and reaction device, the second adsorption and reaction device being filled with a methyldichlorosilane adsorbent material; a second
distillation column connected to the second adsorption and reaction device; and a third distillation column connected to the second distillation column. This utility model can adsorb and concentrate
metal impurities in carbon-containing chlorosilanes as a catalyst for the carbon removal reaction, effectively avoiding deactivation and failure caused by
metal impurities encapsulating the resin catalyst, improving the conversion rate of methyldichlorosilane, and effectively avoiding the
disproportionation reaction of
silicon trichloride in the presence of the resin catalyst, thereby improving the carbon removal efficiency and
chlorosilane recovery efficiency.