The invention relates to a special metal roofing organo-silicone rubber waterproof paint and a preparation method thereof. The paint is prepared from water, organo-silicone rubber emulsion, sodium lauryl benzenesulfate emulsion, phthalic acid, emulsifier, dispersant, sodium chloride, vinyl acetate, isooctyl alcohol, bentonite, heavy calcium carbonate, aedelforsite, ferric oxide, nano silicon dioxide, pigment and defoamer. The paint is nontoxic and tasteless and is ultraviolet radiation resistant, ageing resistant, waterproof, anticorrosion, thermally insulated, environment-friendly and energy-saving; therefore, the paint is suitable for metal roofing of workshops and factories, and the paint has special waterproofing effect as for important waterproofing complicated roofs.