The invention discloses a preparation method of an esters retarding polycarbocylic acid
slump retaining agent. The method comprises the following steps that 1, unsaturated
carboxylic acid and / or anhydride, alkoxy poly alkylene glycol, hydroxy ethidene diphosphonic acid and / or 2-hydroxyphosphonoacetic acid and
polymerization inhibitor are mixed, under the protection of
nitrogen, the temperature is increased to range from 40 DEG C to 60 DEG C, a catalyst is added, the temperature is increased to 100-140 DEG C,
thermal reaction is conducted for 0.5-3 h, water is removed during the reaction, after reaction is finished, the temperature is cooled to
room temperature, and a first mixture is obtained; 2, the first mixture and unsaturated
carboxylic acid hydroxyl esters are mixed, and a
comonomer mixture solution is obtained; 3, the
comonomer mixture solution, an initiator
aqueous solution and a molecular weight
regulator aqueous solution are dropped in water to conduct reaction, and a
copolymer product is obtained; 4, pH of the
copolymer product is adjusted to 5-7 through alkali, and the esters retarding polycarbocylic acid
slump retaining agent is obtained. According to the preparation method of the esters retarding polycarbocylic acid
slump retaining agent, a structure of the hydroxy ethidene diphosphonic acid and / or the 2-hydroxyphosphonoacetic acid is introduced into the esters polycarbocylic acid slump retaining agent, and a finally obtained product has the effects of retardation and slump retaining.