The invention provides a triarylamine organic compound and an organic light-emitting device thereof, and relates to the technical field of organic photoelectric materials. According to the invention, triarylamine is taken as a center and connected with a benzo alicyclic group, so that the electron donating ability of the compound is further enhanced, and the compound has the advantages of excellent hole transport performance, high luminous efficiency and low driving voltage, and is a good hole transport material. The triarylamine organic compound provided by the invention is applied to the organic light-emitting device as a covering layer material, and the light extraction efficiency can be improved, so that the light-emitting efficiency of the organic light-emitting device is improved. The triarylamine organic compound disclosed by the invention is good in film-forming property, high in glass transition temperature (Tg), relatively good in stability, simple in synthesis and easy to operate, and can be widely applied to the fields of panel display, lighting sources, organic solar cells, organic photoreceptors or organic thin film transistors and the like.