The invention relates to a
system and a method for gasification treatment of waste
cathode carbon blocks of an
aluminum electrolysis cell in cooperation with
oxygen-enriched
combustion of
coal, and application of the
system. The method comprises the following steps: feeding part of high-temperature
flue gas generated by
oxygen-enriched
combustion of a pulverized
coal furnace into a circulating
fluidized bed gasification furnace, and performing a gasification reaction on waste
cathode carbon blocks of an
aluminum electrolysis cell and the high-temperature
flue gas in the gasification furnace togenerate gasified gas; adding a
calcium-based absorbent into the gasification furnace, wherein
hydrogen fluoride is removed,
calcium fluoride is generated, and primary
fluorine fixing is achieved; feeding the gasified gas containing a small amount of
hydrogen fluoride into a circulating
fluidized bed secondary
fluorine-fixing reactor, adding aluminum
oxide particles into the reactor to remove
hydrogen fluoride in the gasified gas so as to generate
aluminum fluoride, wherein secondary
fluorine fixing is achieved; and making the purified gasified gas enter the pulverized
coal furnace to be subjected to
oxygen-enriched
combustion together with pulverized coal to form
flue gas containing high-concentration CO2, so that the
flue gas can be sealed or recycled. According to the method, waste
cathode carbon blocks of an
aluminum electrolysis cell are converted into
combustible gas, CO2 capture and synergistic removal of various pollutants such as
hydrogen fluoride are achieved, coal consumption is reduced, and the method has good application prospects.