The invention discloses a process for extracting white carbon black in alkaline-leaching and vanadium extraction of stone coal, which aims at solving the problem that no mature process for extracting white carbon black from filter residues of the stone coal, which are subjected to sodium-free blank roasting, alkaline leaching and vanadium extraction, exists at present. The process comprises the following steps of: carrying out sodium-free blank roasting on the stone coal, adding 3-7% of industrial alkali, soaking for 3-5 hours at 65-95 DEG C, putting the obtained lixivium to a white carbon black reaction kettle, heating to 75-85 DEG C, simultaneously adding concentrated sulfuric acid to adjust the pH to 5-6, stirring and maintaining for 0.5-1.5 hours, carrying out conventional pressure filtration, simultaneously introducing hot water of 65-75 DEG C, conventionally pulping the obtained filter cake, carrying out spray drying to obtain the white carbon black, and carrying out vanadium extraction on the obtained filtrate and water washing liquid. The invention is used for extracting the white carbon black from the filter residues of the stone coal, which are subjected to sodium-free blank roasting, alkaline leaching and vanadium extraction, has the advantages of simple and convenient process, high extraction yield, good benefit and no environmental pollutant emission, and realizes the comprehensive development and cyclic utilization of the stone coal.