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55results about How to "Reduced polarization loss" patented technology

Single-crystal lithium nickel manganese cobalt positive electrode material, preparation method thereof and lithium ion battery

The invention provides a single-crystal lithium nickel manganese cobalt positive electrode material. The single-crystal lithium nickel manganese cobalt positive electrode material comprises a substrate, wherein the substrate is a compound shown as a formula I of LiNi<x>Co<y>Mn<1-x-y>M<z>O<2>, x is more than or equal to 0.3 but less than or equal to 0.75, y is more than or equal to 0.2 but less than or equal to 0.3, z is more than or equal to 0 but less than or equal to 0.1, and a coating layer is coated on a surface of the substrate and is one or more of Li2ZrO3, Li2SnO3, LiNbO3, Li4Ti5O12 and LiAlO2. Compared with the prior art, a fast ion conductor is coated on the surface, thus, the rate performance of a single-crystal material is improved, the gram capacity of the single-crystal material is improved, the cycle performance of the material is further improved, the internal resistance can also be reduced, the polarization loss is reduced, and the cycle lifetime of a battery is prolonged; and meanwhile, the advantage of large compaction of a single-crystal ternary material is maintained, a particle broken phenomenon caused by rolling particles similar to secondary particles during battery fabrication can be prevented due to relatively high compaction, and the cycle performance is improved.
Owner:NINGBO RONBAY LITHIUM BATTERY MATERIAL CO LTD

High-voltage and single-crystal ternary positive electrode material and preparation method thereof

The invention discloses a high-voltage and single-crystal ternary positive electrode material and preparation method thereof. The general formula of the material can be expressed with Li<x>Ni<1-m-n>Co<m>Mn<n>O2, wherein x is more than 0.96 but less than 1.12, m is more than 0 but less than 1, n is more than 0 but less than 1, and (m+n) is less than 1. The preparation method comprises the steps of preparing a precursor by taking a nickel salt, a cobalt salt and a manganese salt as raw materials and by employing a co-precipitation method or a chemical synthesis method, mixing the precursor with a lithium source, adding a modifying agent into the mixture after pre-processing, and performing sintering, smashing and sieving after uniform mixing to obtain the high-voltage and single-crystal ternary positive electrode material. The grain size of the prepared high-voltage and single-crystal ternary positive electrode material is 2-15 micrometers, and the compaction density reaches 3.8-3.9g / cm<3>; meanwhile, the surface of the ternary positive electrode material is modified by a wet process to package Al, the material structure is stabilized, and side reaction of the material and an electrolyte is prevented; and according to actual detection, the cycle property, the high-temperature storage performance and the safety performance of the lithium ion battery under high voltages of 4.4V and 4.5V are effectively improved.
Owner:HENAN KELONG NEW ENERGY CO LTD

Satellite-borne K-band phased array antenna circularly-polarized waveguide radiation array

The invention relates to a satellite-borne K-band phased array antenna circularly-polarized waveguide radiation array, which can radiate microwave signals to the space, and can receive microwave signals from the space. The satellite-borne K-band phased array antenna circularly-polarized waveguide radiation array is composed of a plurality of antenna units, wherein each antenna unit comprises a matching diaphragm, an SMP coaxial feed socket, a square waveguide radiator, a waveguide-to-coaxial adapter, an SMP feed socket feed end, an impedance matching device and a circular polarizer, and adopts an integral design; and the matching diaphragms are adopted among the antenna units for deploying coupling characteristics among radiating units, so as to achieve more ideal standing wave performance and radiation characteristics. The satellite-borne K-band phased array antenna circularly-polarized waveguide radiation array is simple and reliable in structure, has the advantages of two-directional plus/minus 40-degree wide angle scanning, low sweep gain drop and excellent circular polarization characteristics, and satisfies the requirements for an phased-array antenna of satellite-borne intersatellite and satellite-to-ground communication. The antenna adopts an aluminum structure, and performances of the antenna are not affected by factors such as elemental oxygen corrosion and ultraviolet radiation of the on-orbit space environment.
Owner:BEIJING INST OF SPACECRAFT SYST ENG

High-capacity porous spherical graphitized carbon negative electrode material and preparation method thereof

ActiveCN106025279APacked tightlyReduce electrode surface side reactionsCell electrodesSecondary cellsEvaporationSilicon dioxide
The invention belongs to the technical field of lithium ion battery negative electrode materials, and in particular relates to a preparation method for a high-capacity porous spherical graphitized carbon negative electrode material. The preparation method comprises the following steps: injecting a precursor dispersion liquid into nano pores of a silicon dioxide colloidal crystal spherical template; carrying out ultrasonic immersing, high-temperature calcinations, template removal, filtering and drying to obtain the high-capacity porous spherical graphitized carbon negative electrode material; and further emulsifying a colloidal silicon dioxide aqueous solution to obtain nano silicon dioxide mixed emulsion; and carrying out constant-temperature condensation, water evaporation, self-assembly, washing and calcinations on the nano silicon dioxide mixed emulsion to obtain the silicon dioxide colloidal crystal spherical template. The invention further discloses the high-capacity porous spherical graphitized carbon negative electrode material prepared by the method. The high-capacity porous spherical graphitized carbon negative electrode material is suitable for manufacturing an electrode material, an electrode plate and the like, can increase charging and discharging capacity of a battery, and is suitable for large-current charging and discharging; and compaction density of the electrode plate is increased, rebound of the electrode plate is reduced, and service life of the battery is prolonged.
Owner:内蒙古凯金新能源科技有限公司

Preparation method of ordered solid oxide membrane electrode

The invention belongs to the technical field of an electrode preparation method, and in particular relates to a preparation method of an ordered solid oxide membrane electrode. In the method, a supporter array solid oxide bar of a catalyst can be prepared by a template method, and can be roasted and integrally fused with a compact solid oxide electrolyte membrane. The highly ordered array solid oxide bar defines the electrode void ratio and the catalyst surface size in the ordered solid oxide membrane electrode, so as to realize the controllable preparation of the ordered electrode. An anode catalyst and a cathode catalyst are prepared respectively on the array solid oxide bar, the catalysts are combined on the surface of the solid oxide bar in a nano- or micro-particle state to form a catalysis layer, the catalyst particles are communicated with each other and are connected to a collector, and the catalyst particles are dispersed highly and have higher specific surface area and catalysis activity, therefore, the three-phase reaction interface of an SOFC (solid oxide fuel cell) and an SOEC (solid oxide electrolysis cells) is increased greatly, the polarization resistance of the electrode is reduced, and consequently, the reaction rate of the fuel and the raw material gas reducing transforming rate are improved.
Owner:TSINGHUA UNIV

Nonvolatile SRAM unit based on hafnium-based ferroelectric capacitor

The nonvolatile SRAM unit comprises a 6T SRAM and a nonvolatile storage module, the nonvolatile storage module comprises a fifth NMOS (N-channel metal oxide semiconductor) tube, a sixth NMOS tube, a seventh NMOS tube, an eighth NMOS tube, a first hafnium-based ferroelectric capacitor and a second hafnium-based ferroelectric capacitor and is of a 4T2C structure, and in the nonvolatile storage module, the first hafnium-based ferroelectric capacitor is connected with the second hafnium-based ferroelectric capacitor. A pair of hafnium-based ferroelectric capacitors, namely a first hafnium-based ferroelectric capacitor and a second hafnium-based ferroelectric capacitor, is adopted as nonvolatile memory devices to form a complementary bilateral structure, data in a 6T SRAM (Static Random Access Memory) is stored in the first hafnium-based ferroelectric capacitor and the second hafnium-based ferroelectric capacitor before power failure, and then the circuit is completely turned off, so that the standby power consumption is saved, and the power consumption is reduced. A complementary bilateral structure formed by the first hafnium-based ferroelectric capacitor and the second hafnium-based ferroelectric capacitor can improve the data recovery rate and the reliability of resisting process change; the method has the advantages of being high in data recovery rate and good in reliability of resisting process changes.
Owner:NINGBO UNIV

Single crystal nickel cobalt lithium manganate cathode material and preparation method thereof and lithium ion battery

The invention provides a single-crystal lithium nickel manganese cobalt positive electrode material. The single-crystal lithium nickel manganese cobalt positive electrode material comprises a substrate, wherein the substrate is a compound shown as a formula I of LiNi<x>Co<y>Mn<1-x-y>M<z>O<2>, x is more than or equal to 0.3 but less than or equal to 0.75, y is more than or equal to 0.2 but less than or equal to 0.3, z is more than or equal to 0 but less than or equal to 0.1, and a coating layer is coated on a surface of the substrate and is one or more of Li2ZrO3, Li2SnO3, LiNbO3, Li4Ti5O12 and LiAlO2. Compared with the prior art, a fast ion conductor is coated on the surface, thus, the rate performance of a single-crystal material is improved, the gram capacity of the single-crystal material is improved, the cycle performance of the material is further improved, the internal resistance can also be reduced, the polarization loss is reduced, and the cycle lifetime of a battery is prolonged; and meanwhile, the advantage of large compaction of a single-crystal ternary material is maintained, a particle broken phenomenon caused by rolling particles similar to secondary particles during battery fabrication can be prevented due to relatively high compaction, and the cycle performance is improved.
Owner:NINGBO RONBAY LITHIUM BATTERY MATERIAL CO LTD

Preparation method of functional porous graphene integrated electrode material and application of functional porous graphene integrated electrode material in vanadium battery

The invention relates to a preparation method of a functional porous graphene integrated electrode material and application of the functional porous graphene integrated electrode material in a vanadium battery. The method comprises the following steps: taking a bipolar plate as a working electrode, adopting a three-electrode system, taking an aqueous solution containing graphene oxide and lithiumperchlorate as a supporting electrolyte, carrying out electrochemical deposition for the first time to obtain a porous graphene/bipolar plate integrated electrode material, and carrying out immersioncleaning with deionized water; and taking the immersed porous graphene/bipolar plate integrated electrode material as a working electrode, adopting a three-electrode system, taking a solution containing functional components as a secondary electro-deposition electrolyte solution, carrying out secondary electrochemical deposition, and introducing the functional components into the surface of the porous graphene to obtain the functional porous graphene integrated electrode material. When the electrode material is applied to a vanadium battery electrode, the polarization loss of a vanadium battery in the operation process can be effectively reduced, the battery storage capacity is increased, and the battery performance is improved. The method is easy and convenient to operate, flexible in design, high in controllability, environmentally friendly, free of pollution and good in application prospect.
Owner:LIAONING UNIVERSITY

A high-power annular energy storage battery

A high-power ring-shaped energy storage battery, including several layers of ring-shaped walls made of solid electrolyte coaxially set together, the two ends of the ring-shaped wall are respectively fixed on the insulating circular base and the circular upper cover, all the ring-shaped walls Together with the circular base and the circular upper cover, several layers of airtight chambers are enclosed together. The adjacent airtight chambers are filled with positive electrode materials or negative electrode materials at intervals. When the battery is running, the positive and negative electrode materials are both in liquid state; The bottom of the body draws out the positive and negative current lead-out poles respectively and gathers them to form the positive and negative poles of the battery. The battery provided by the invention has a large electrochemical reaction area and a current flow area, has excellent electronic conductivity, can reach a sufficiently large current density, and ensures a sufficiently high charge and discharge rate and power, and has a simple structure and low cost. It is cheap, can determine size parameters according to different capacity requirements, is easy to expand in scale, and can meet different capacity and space requirements.
Owner:XI AN JIAOTONG UNIV
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