The invention discloses a diglycol
amide compound with a tripod structure as well as a synthesis method and application thereof, and relates to the field of
amide compounds, and the chemical name of the diglycol
amide compound is 2, 2 ', 2' '-(((((
nitroso tris (
methylene))
tris (
benzene-2, 1-diyl))
tris (
nitrogen diyl)) tris (2-oxoethane-2, 1-diyl)) tris (oxy)) tris (N, N-dioctyl
acetamide). The compound is constructed by taking tris (2-aminobenzyl) amine as a core skeleton and
grafting three N, N, N ', N'-tetraoctyl diglycol amide chelating units. The Trapan-DGA compound disclosed by the invention shows excellent performance in the field of
nuclide separation: in a 5.0 M
nitric acid medium, the distribution ratio to Th (IV) reaches 12.4, and the
separation factor to Th (IV) / U (VI) reaches up to 34.4. The compound has excellent acid stability, the extraction performance is stable in the
nitric acid concentration range of 1.0-5.0 M, and the extraction
equilibrium time is only 5 minutes. Meanwhile, the compound has good
solubility in non-polar
diluent kerosene, and effective extraction can be realized without adding an
alcohol modifier.