The invention discloses a Fe, Ni and N three-
doped carbon nanotube coated type FeNi@NCNT catalyst as well as a preparation method and application thereof, and belongs to the fields of energy materialsand
electrochemistry. The catalyst is prepared by using dicyandiamide as a C source and N source and
ammonium ferric citrate and NiCl2.6H2O as
metal sources, adopting one pot method and performing
pyrolysis in two steps; and a plurality of Fe and Ni
metal particles in the catalyst are uniformly wrapped in walls of ''bamboo-like'' N-
doped carbon nanotubes, and a small number of the particles are distributed at the tip ends of the carbon nanotubes. Compared with a common
metal alloy oxygen reduction reaction and
oxygen evolution reaction
bifunctional catalyst, the catalyst disclosed by the invention exhibits good
oxygen evolution reaction activity and stability under alkaline conditions; the preparation method is simple, and raw materials used in the method have low costs and wide sources;and the catalyst can be widely used in the fields of
proton exchange membrane
fuel cells, electrolyzed water, metal-air batteries and the like, and has higher practical value.