The present invention relates to a synthetic method of borazine phenanthrene and its derivatives, and tested the photoelectric physical properties of these compounds, and further studied the potential application value of this type of organic material in organic electrochemistry. The structural formula of this compound is: wherein R 1 , R 2 , R 3 , R 4 They are independently substituted or unsubstituted groups, including alkyl, aryl (benzene ring, thiophene ring, furan ring, pyrrole, pyridine, benzothiophene, benzofuran, benzopyrrole, benzopyridine, naphthalene ring , anthracycline, phenacene, tetracene, pyrene, linear or angled pentacene, hexacene, indene, fluorene, etc.). where R 1 , R 2 It can also be a single substituted halogen atom X: F, Cl, Br, I.