The invention relates to a method and a device used for controlling and researching a bubble polymerization process. According to the method, bubbles are generated in a low-viscosity conductive electrolyte, and surfaces of the bubbles have charges; the bubbles with the charges having different polarities collide and polymerize in a non-conductive transparent liquid, and a collision and polymerization process of the bubbles is controlled through an external electric field. The device comprises an electrolyte storage tank, a dielectric separator plate, two metal electrode plates, a micropore pipe, electrodes and bubble observation analysis equipment, wherein the two electrodes have opposite polarities, height of the dielectric separator plate is greater than the electrolyte, and the non-conductive transparent liquid is injected above the electrolyte. The method is advantaged in that, the bubbles are generated through the micropore pipe, sizes of the bubbles are easy to control, and the bubbles are not easy to break; a motion speed and locus of the bubbles can be controlled through adjusting intensity of the electric field; shapes of the bubbles are good before polymerization, the bubble polymerization process is slow, duration time is long, and requirements for a camera is reduced.