The invention discloses a light-driven
nitrogen cycle
pyrolysis-gasification
biomass graded utilization
system and method, and relates to the technical field of
biomass graded utilization, the
system comprises a pretreatment unit, a light-driven
nitrogen-doped
pyrolysis reactor and a photocatalytic
nitrogen de-intercalation gasification reactor as core parts, an energy collection unit and a post-
treatment unit. The method comprises condensation
ammonia-doped
pyrolysis and condensation gasification: pretreated
biomass is subjected to condensation
ammonia-doped pyrolysis in a pyrolysis section to generate high-activity nitrogen-doped
coke and
hydrogen, then the nitrogen-doped
coke enters a gasification section to be subjected to condensation gasification, under the action of high-concentration
water vapor, nitrogen elements in the
coke are deintercalated, more active sites are released, NH3 is generated at the same time, and the nitrogen-doped coke enters the gasification section to be subjected to condensation gasification; the nitrogen can flow back to the pyrolysis zone for cyclic utilization, and a
nitrogen doping-de-intercalation
catalytic cycle process is formed. The light-driven
nitrogen cycle grading technology is adopted, efficient
doping of nitrogen elements at the high temperature is achieved, high-activity nitrogen-doped coke is generated, and production of high-quality synthesis gas and cyclic utilization of nitrogen are achieved.