32 results about "Potassium peroxymonosulfate" patented technology

The invention discloses a method for degrading antibiotics in wastewater based on chitosan aerogel. The method comprises the following steps: adding chitosan aerogel Co-PBA / CS and potassium hydrogen peroxymonosulfate into the antibiotic-containing wastewater, and degrading under stirring. The method provided by the invention has a ciprofloxacin degradation capability of 94.7%. In addition, the material also has excellent self-cleaning and photo-thermal conversion performance, and can realize surface cleaning. The multifunctional aerogel provides a new strategy for removing pollutants such as ciprofloxacin in a complex and severe water environment.

The invention discloses a tetracycline hydrochloride-containing wastewater treatment method in the field of wastewater treatment, which comprises the following steps: introducing tetracycline hydrochloride-containing wastewater into a reactor, adding a multilevel structure iron and iron sulfide composite carbon material, and adjusting the system to a nearly neutral condition; then adding potassium peroxymonosulfate composite salt, starting a direct current system, and carrying out catalytic degradation reaction under specific current density; and finally recovering the catalyst through magnetic field separation. The preparation method comprises the following steps: grinding pyrite and hematite, ball-milling and mixing the ground pyrite and hematite with orange peel powder and sodium hydroxide, and carrying out microwave pyrolysis, acid washing and drying, hydrogen peroxide surface treatment and the like to obtain a final product. According to the method, efficient degradation of tetracycline hydrochloride under the neutral condition is achieved, the catalyst can be magnetically recycled, secondary pollution is avoided, and the method has the advantages of being low in cost, easy and convenient to operate, environmentally friendly and the like.

The invention discloses an HPCACM-coated Co3O4 composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing rice straw source cellulose; preparing rice straw source cellulose acetate (CA); preparing a hollow porous cellulose acetate fiber membrane (HPCAFM); preparing a hollow porous cellulose acetate derived carbon fiber membrane (HPCACM); and preparing the HPCACM-coated Co3O4 composite material. The prepared HPCACM-coated Co3O4 composite material is prepared based on straw, has a high specific surface area and a unique micro-mesoporous hierarchical structure, provides a rich active interface for a catalytic reaction, is beneficial to promoting mass transfer of reactants and products, efficiently activates potassium hydrogen persulfate, realizes high-value utilization of agricultural wastes, and improves the water pollution treatment efficiency.

The invention relates to the technical field of cleaning tablets, and provides a multi-effect cleaning tablet for a kitchen waste processor and a preparation method of the multi-effect cleaning tablet. The multi-effect cleaning tablet comprises a foaming cleaning layer, an oxidation sterilization layer and a deep decomposition layer, the foaming cleaning layer is arranged on one side of the oxidation sterilization layer, the deep decomposition layer is arranged on the opposite side of the oxidation sterilization layer, and the foaming cleaning layer comprises sodium bicarbonate, gluconic acid-delta-lactone, alkyl glycoside, limonene and a chelating agent; the oxidation sterilization layer comprises sodium percarbonate, potassium hydrogen peroxysulfate, potassium carbonate, sodium citrate and a stabilizer; the deep decomposition layer comprises biological enzyme. Gluconic acid-delta-lactone is adopted in the foaming cleaning layer of the multi-effect cleaning tablet to generate gluconic acid, so that the system is prevented from instantly and violently turning over, a middle-layer peroxidation system is favorably released at a proper time, invalid decomposition is reduced, strong acid or violent pH fluctuation is prevented from permeating into an inner layer, the enzyme inactivation risk is reduced, the foaming process is mild, and the foaming effect is good. And the integral integrity of the tablet can be maintained.

The invention relates to the technical field of production devices, and discloses a potassium monopersulfate-based composite disinfectant production device, which comprises a support frame, the inner wall of the support frame is fixedly connected with a mixing barrel, the inner wall of the mixing barrel is rotatably connected with a reciprocating screw rod, and the circumferential surface of the reciprocating screw rod is fixedly connected with a triangular plate. A rotating rod is rotatably connected to the inner wall of the triangular plate, a stirring plate is fixedly connected to the circumferential surface of the rotating rod, a rubber wheel is fixedly connected to the circumferential surface of the stirring plate, an ultraviolet lamp is arranged at the bottom of the triangular plate, a raw material frame is fixedly connected to the inner wall of the mixing barrel, and a fan-shaped plate is slidably connected to the inner wall of the raw material frame. In the mixing process, quantitative intermittent feeding can be achieved, the amount of medicine powder fed every time is accurately controlled, the requirement of a production formula is met, and local concentration unbalance caused by excessive feeding at a time is avoided.

The invention provides a method and a system for removing multiple pollutants in flue gas by using double-cavitation modified fire coal fly ash. The method comprises the following steps: co-activating a modified solution composed of potassium hydrogen peroxymonosulfate, hydrogen peroxide and ammonium chloride by using a synergistic effect between nano bubble cavitation and ultrasonic cavitation; active functional groups containing oxygen, nitrogen, sulfur and chlorine are induced to be grafted to the surface of the coal-fired fly ash, the coal-fired fly ash is modified, and then pollutants such as SO2, Hg < 0 >, methylbenzene and As < 3 + > in flue gas are adsorbed and removed at the same time in a boiler flue by utilizing the modified coal-fired fly ash. The double-cavitation modification method and system developed by the invention have the comprehensive advantages of simple process device, energy conservation, low carbon, high mixing and mass transfer diffusion efficiency, high simultaneous removal efficiency of multiple pollutants, clean and environment-friendly modification process and the like, and have good development prospects and industrial application values.

The invention discloses a preparation method of pesticide line thiophene, which comprises the following steps: under protective gas, dissolving benzaldoxime and 2-cyano thiophene in an organic solvent, slowly adding an oxidizing agent at the temperature of 20-30 DEG C, and after the reaction is completed, washing with water, extracting, concentrating and recrystallizing to obtain line thiophene, the oxidizing agent is selected from one or more of diacetoxy iodobenzene, [bis (trifluoroacetoxy) iodine] benzene and potassium peroxymonosulfonate. According to the preparation method of the pesticide line thiophene, the line thiophene is directly and efficiently synthesized through one-step reaction, and the yield is good. Compared with the existing synthesis route, the route is short, the solvent can be recycled and reused, the requirement on equipment is simple and corrosion-free, and a foundation is laid for further pilot scale production.

The invention relates to the technical field of environmental catalysis and advanced oxidation, in particular to a composite catalyst based on abnormal adsorbate type strong metal-carrier interaction (AA-SMSI), a preparation method of the composite catalyst and activation application of the composite catalyst to potassium peroxymonosulfate (PMS). The composite catalyst comprises a nanoscale carrier CeO2 and cobalt nanoparticles which are loaded on the carrier and have a core-shell structure. The unique core-shell structure of the composite catalyst effectively inhibits leaching of cobalt ions and aggregation of nano particles through physical packaging, the stability is greatly improved, the under-coordination shell layer of the composite catalyst also serves as a high-activity site, the PMS activation capacity is remarkably enhanced, and therefore ultrahigh activity and stability are achieved at the same time. The preparation process of the composite catalyst is mild, controllable and environment-friendly, a new thought is provided for breaking through the bottleneck that activity and stability in a traditional catalytic system are difficult to consider at the same time, and the composite catalyst has wide application prospects in the fields of advanced oxidation, industrial wastewater treatment and environmental catalysis.

The application discloses a kind of biochar catalyst and its preparation method and application in catalyzing 5-hydroxymethylfurfural oxidation preparation 2,5-furan dicarboxylic acid.The preparation method comprises the following steps: after mixing trehalose with zinc chloride and potassium chloride, carbonization is pyrolyzed under inert atmosphere to obtain biochar catalyst.The application utilizes efficient, low-cost, renewable catalyst to efficiently catalyze HMF to selectively generate DFF in the presence of potassium hydrogen peroxymonosulfate composite salt, and has the advantages of low catalyst cost, high product yield, high product selectivity, mild reaction conditions, low production cost, no security risks and environmental friendliness.

The invention discloses a method for degrading vomitoxin by potassium hydrogen peroxymonosulfate, which comprises the following steps: treating a mixture to obtain a bimetallic modified graphite phase carbon nitride catalyst; the mixture is prepared from urea, CuCl2 (copper chloride) and CoCl2. 6H2O (cobalt chloride); potassium hydrogen peroxymonosulfate is treated with the bimetallic modified graphite phase carbon nitride catalyst, and activated potassium hydrogen peroxymonosulfate is obtained; and degrading vomitoxin in the water body by using the activated potassium hydrogen peroxymonosulfate to obtain a water body degradation result. According to the method disclosed by the invention, the degradation efficiency of DON within 30 minutes can reach 100% under an electro-catalysis coupled PMS system, and the method has wide pH and complex matrix adaptability, is wide in application range, and can be stably and circularly used.

Various formulations of a disinfectant are disclosed. The disinfectant includes an amount of potassium peroxymonosulfate, at least one organic acid, and at least one surfactant. The disclosed disinfectant can exist in both powder form and liquid form, and can also be in kit form having a variety of form factors. These disinfectant formulations offer higher efficacy and lower toxicity when compared with disinfectants known in the art, and when compared with potassium peroxymonosulfate alone.

The invention relates to the technical field of chemical methods, in particular to preparation of a Cu and Ni doped modified MIL-88A material and application of the Cu and Ni doped modified MIL-88A material in activating potassium hydrogen persulfate to degrade PFBS. The preparation method comprises the following steps: performing ultrasonic dispersion and dissolution on fumaric acid, CuCl2. 2H2O, FeCl3. 6H2O and Ni (NO3.) 2.6 H2O, mixing, reacting at specific temperature and rotating speed, and washing and drying to obtain a product; the application comprises the following steps: preparing PMS and PFBS solutions, adding the modified material, and reacting under specific conditions. The problems that existing MIL-88A catalytic active sites are limited, and Fe < 3 + > / Fe < 2 + > valence state circulation conversion is slow are solved.

The invention relates to the technical field of disinfectant preparation, in particular to a disinfectant containing a potassium peroxymonosulfate compound and a preparation method of the disinfectant. The compound disinfectant is prepared from the following components in parts by mass: 60 to 80 parts of potassium peroxymonosulfate, 20 to 30 parts of a modified photoaccelerator, 10 to 15 parts of sulfamic acid, 5 to 10 parts of sodium hexametaphosphate, 1 to 3 parts of sodium dodecyl benzene sulfonate, 3 to 4 parts of sodium chloride, 1 to 2 parts of lemon essence, 0.3 to 1.5 parts of amaranth red pigment, 10 to 20 parts of trisodium citrate and 1 to 3 parts of an anti-caking agent, the composite disinfectant prepared by the invention has excellent microorganism killing performance, and can efficiently kill various microorganisms such as bacteria, fungi, viruses and the like; meanwhile, the disinfectant is safe and harmless to human bodies, does not cause potential health problems, does not generate adverse effects on the environment in the use process, is environmentally friendly and safe, and is an efficient, reliable, durable and safe disinfectant.

The application provides a high-potential potassium hydrogen persulfate bottom modification sheet and a preparation method thereof, relates to the field of bottom modification sheets, and comprises the following components in parts by weight: 10-30 parts of potassium hydrogen persulfate composite salt, 2-3 parts of potassium bisulfate, 2-5 parts of potassium sulfate, 1-3 parts of sodium chloride, 1-3 parts of polyethylene glycol 6000, 1-3 parts of polyvinylpyrrolidone, 1-3 parts of magnesium sulfate, 3-5 parts of sodium dodecyl sulfate, 4-10 parts of sodium metaphosphate and 30-60 parts of sodium sulfate. The application also provides a method for preparing the high-potential potassium hydrogen persulfate bottom modification sheet. The application realizes slow dissolution of the drug in water through inclusion technology, continuously releases active peroxide ions, ensures long-acting oxidation and decomposition of the organic matter in the bottom mud, and meets the sustainability requirement of the water product breeding environment for the bottom improvement.

The application discloses a preparation method of o-carboxybenzaldehyde, which comprises the following steps: S1, reacting a phthalide with a potassium hydrogen peroxysulfate complex salt and an alkali in a polar protic solvent to prepare an intermediate; S2, hydrolyzing the intermediate obtained in the step S1 by using a strong protic acid aqueous solution to obtain a product o-carboxybenzaldehyde; and S3, adjusting the pH of the product obtained in the step S2 to 3-4 by using a sodium hydroxide aqueous solution, quenching excessive potassium hydrogen peroxysulfate complex salt by using a saturated sodium sulfite solution, cooling, recrystallizing, filtering and vacuum drying to obtain a final product o-carboxybenzaldehyde. The preparation method of the o-carboxybenzaldehyde can effectively reduce the synthesis cost, avoids the use of dangerous and toxic reagents, effectively reduces the generation of industrial three wastes, and is simple in process, convenient in operation, low in raw material cost, high in yield and beneficial to large-scale industrial production.

The invention relates to the technical field of electroplating waste liquid treatment, in particular to a resourceful treatment method for electroplating waste liquid. The trace metal impurities in the waste liquid are adsorbed in situ by the phosphonic acid chelating resin in a strong acid system and are converted into the heterogeneous catalyst, and the continuous / pulse combined feeding strategy of potassium hydrogen peroxymonosulfate is matched, so that deep mineralization of stubborn organic matters and accurate separation of impurities such as iron and nickel are realized; and high-purity copper sulfate pentahydrate crystals are prepared through copper type resin buffering and a specific crystallization process on the premise of not introducing exogenous impurities. The method is free of secondary pollution, realizes high-valued total recovery of ultra-pure resources in the electroplating waste liquid, has remarkable economic and environmental benefits, and is suitable for resource treatment of the PCB and semiconductor electroplating waste liquid.

The present application relates to the technical field of disinfectant preparation, and particularly relates to a disinfectant containing potassium peroxymonosulfate compound and a preparation method thereof, the compound disinfectant comprises the following components in parts by mass: 60-80 parts of potassium peroxymonosulfate, 20-30 parts of modified photomodulator, 10-15 parts of sulfamic acid, 5-10 parts of sodium hexametaphosphate, 1-3 parts of sodium dodecyl benzene sulfonate, 3-4 parts of sodium chloride, 1-2 parts of lemon essence, 0.3-1.5 parts of amaranth red pigment, 10-20 parts of trisodium citrate, and 1-3 parts of anti-blocking agent; the compound disinfectant prepared by the present application has excellent microorganism killing performance, and can efficiently kill various microorganisms such as bacteria, fungi and viruses; meanwhile, the disinfectant is safe to human body, cannot cause potential health problems, and cannot cause adverse effects on the environment in the use process, is environment-friendly and safe, and is an efficient, reliable, persistent and safe disinfectant.

The invention relates to a functional composition for reducing the total sugar content of tobacco leaves and increasing the potassium content of the tobacco leaves and application of the functional composition. The functional composition comprises a first component, a second component and a third component, the first component comprises potassium hydrogen persulfate; the second component comprises trisodium phosphate; and the third component comprises glucose oxidase. The raw materials including the potassium hydrogen persulfate, the trisodium phosphate and the glucose oxidase are combined for use and are matched with one another, the effects of reducing the total sugar content in the tobacco leaves and increasing the potassium content in the tobacco leaves can be achieved after the composition is applied in the tobacco growth period, then the sugar-alkali ratio and the sugar-nitrogen ratio of the tobacco leaves are balanced, the sweet sense and the aroma amount of the tobacco leaves are increased, and the tobacco quality is improved. The comfort of the sensory smoking quality of the tobacco leaves is improved.

This invention provides a method for preparing high bulk density potassium peroxymonosulfate composite salt. Through multi-dimensional process optimization including multi-point feeding and neutralization, ultrasonic action, crystal guiding agent, heating-heating-heating-cooling, and drying-mixing-sieving, the bulk density of PMS is synergistically improved, and the overall performance of the final product is superior to that of the prior art.

The present application relates to a kind of ammonia content detection method in sulfurous acid-containing solution, belong to material detection technical field.The ammonia content detection method in sulfurous acid-containing solution of the present application, comprising the following steps: (1) adding potassium hydrogen persulfate to be measured sulfurous acid-containing ammonia solution and reacting with sulfurous acid, obtain the test solution;(2) using indigo phenol blue spectrophotometry to determine the ammonia content in the test solution obtained in step (1), i.e.the ammonia content in sulfurous acid-containing solution is obtained.The present application first adds oxidizing agent potassium hydrogen persulfate solution as pretreatment reagent, and reacts with sulfurous acid, eliminates sulfurous acid, while it will not produce interference factors affecting ammonia content determination.The ammonia concentration standard curve obtained by the test method of the present application, the R 2 of fitting curve has reached 0.999, which indicates that ammonia signal intensity and the concentration of standard solution have good linear relationship, further indicating that the ammonia content detection method of the present application has good detection reliability and accuracy.

Described herein are oral care compositions comprising: an oxidizing agent comprising potassium peroxymonosulfonate, a carrier comprising a polymer fluid, an adhesive, and a flavouring agent; wherein the oxidizing agent is substantially free of a peroxide source, optionally free of a peroxide source.

This invention discloses a multifunctional potassium peroxymonosulfate composite effervescent tablet and its preparation method, belonging to the field of water treatment and disinfection formulation technology. The effervescent tablet is composed of potassium peroxymonosulfate composite salt, microencapsulated citric acid, a sodium bicarbonate / sodium carbonate mixture, sodium chloride, natural saponin extract, magnesium silicate-loaded hydrogen peroxide powder, polyvinyl alcohol-sodium alginate composite binder, magnesium stearate, and anhydrous sodium sulfate. By introducing pH-responsive microencapsulation technology to achieve gradient release of active ingredients, utilizing magnesium silicate-loaded hydrogen peroxide powder to achieve bottom flocculation and continuous oxygenation, and employing natural saponins to enhance biofilm penetration. This invention effectively solves the problems of excessively rapid release, high pH sensitivity, and lack of targeting in existing potassium peroxymonosulfate effervescent tablets, significantly extending the effective action time and improving the sterilization, algae removal, and water quality improvement effects. It is suitable for various scenarios such as aquaculture water bodies, landscape lakes, and emergency disinfection.

The invention relates to the technical field of wastewater treatment, in particular to a treatment process of naphthalene-polluted wastewater. The treatment process comprises the following steps: measuring the initial concentration of naphthalene in the wastewater; adding a modified manganese-based complex and potassium peroxymonosulfate composite salt into the wastewater to form a mixed system; heating the mixed system to 60-80 DEG C, stirring and reacting for 90-150 minutes, sampling according to a preset interval, measuring the absorbance by an ultraviolet and visible spectrophotometer, and calculating the degradation rate by combining a naphthalene standard curve. The core of the process lies in that the modified manganese-based complex can controllably release Mn < 2 + > and activate persulfate in cooperation with heat to generate active oxygen species with < 1 > O2 as a main component and <. > SO4 <-> and <. > OH as auxiliary components, and a conjugated aromatic ring structure of naphthalene is efficiently destroyed to realize deep degradation. The process does not need complex equipment, gives consideration to both degradation efficiency and energy consumption control, is suitable for large-scale treatment of industrial naphthalene polluted wastewater, and has good practicability and environmental benefits.

The utility model relates to a live pig isolation quarantine fence with disinfection channel belongs to live pig isolation quarantine fence technical field. The live pig isolation quarantine fence with disinfection channel, include: quarantine fence main part, one end fixedly connected with connecting plate of quarantine fence main part, disinfection mechanism can carry out effective disinfection to live pig isolation quarantine fence and set up in the top of connecting plate, the connecting plate of quarantine fence main part and intercepting rod cooperation constitute live pig disinfection channel, the conveying pipe on intercepting rod can convey potassium peroxymonosulfate disinfectant to water mist spray head, and the water mist is sprayed through water mist spray head and is sterilized to live pig and disinfection channel, and the bacteria are killed, and the first ultraviolet disinfection lamp and second ultraviolet disinfection lamp on the intercepting rod and quarantine fence main part emit ultraviolet light in advance and disinfect the intercepting rod and connecting plate and quarantine fence main part, can carry out effective disinfection sterilization to live pig isolation quarantine fence, prevent live pig cross infection.

This invention relates to the field of chemical method technology, specifically to the preparation of Cu and Ni-doped modified MIL-88A material and its application in the degradation of PFBS by activated potassium persulfate. The preparation involves ultrasonically dispersing and dissolving fumaric acid with CuCl2·2H2O, FeCl3·6H2O, and Ni(NO3·)2·6H2O, then mixing the mixture and reacting it at a specific temperature and rotation speed. The product is obtained after washing and drying. The application involves preparing PMS and PFBS solutions, adding the modified material, and reacting under specific conditions. This invention overcomes the limitations of existing MIL-88A catalytic active sites and the Fe... 3+ / Fe 2+ The problem of slow valence state cycle transitions.

The invention discloses a method for promoting sludge dewatering. According to the method, low-temperature heating and iron-rich sludge biochar (Fe (at) SBC) are cooperated to activate potassium peroxymonosulfate composite salt (PMS) to promote sludge dewatering. According to the invention, low-temperature heating is cooperated with Fe-coated SBC to activate PMS so as to form a composite conditioning agent, so that deeper dehydration of activated sludge is realized; the sludge does not need to be subjected to original acid regulation treatment; the activated sludge is used as a raw material for preparing the biochar, so that the treatment cost and waste utilization are saved; compared with high-temperature heating, low-temperature heating can reduce more cost. The method disclosed by the invention can be widely applied to treatment and disposal of residual activated sludge in a sewage treatment plant, and has obvious social and environmental benefits.

The present disclosure provides tooth whitening oral care compositions comprising potassium peroxymonosulfate having improved stability, and methods of using the same.

The invention relates to the technical field of pharmaceutical wastewater treatment, in particular to a method for treating chloroquine phosphate wastewater by activating PMS with a platinum nano-catalyst, which comprises the following steps: S1, preparing the platinum nano-catalyst: dropwise adding an ethylene glycol solution of H2PtCl6 into an ethylene glycol solution of NaOH heated in an oil bath, stirring and cooling to room temperature to obtain the brownish black platinum nano-catalyst, the average particle size of platinum nanoparticles in the platinum nano-catalyst is less than or equal to 3 nm; and S2, activating PMS by the platinum nano-catalyst to carry out chloroquine phosphate degradation reaction, namely adding the platinum nano-catalyst and potassium peroxymonosulfate composite salt into chloroquine phosphate wastewater, and carrying out degradation reaction under irradiation of 222 nm ultraviolet light. In order to improve the reaction activity of peroxymonosulfate and further improve the degradation efficiency of chloroquine phosphate in a water body, a UV / PMS system is optimized by adopting a platinum nano-catalyst, and help can be provided for treating wastewater containing chloroquine phosphate.

The present application relates to the technical field of pyrophosphate heavy metal treatment, and discloses a treatment method for pyrophosphate heavy metal wastewater and application thereof, the treatment method for pyrophosphate heavy metal wastewater comprises the following steps: adding waste manganese slag into the pyrophosphate heavy metal wastewater, adding a hydrolysis agent, fully reacting, and obtaining a mixed solution; the hydrolysis agent comprises at least one of potassium peroxymonosulfate, potassium persulfate, potassium sulfite, hydrogen peroxide and peroxyacetic acid. Wherein, the waste manganese slag serves as a reaction carrier, provides a catalytic surface and an adsorption site for degradation of pyrophosphate heavy metal complexes; the hydrolysis agent is activated under the catalysis of the manganese slag, attacks the pyrophosphate P-O-P bond to hydrolyze into orthophosphate, simultaneously destroys the metal complex structure, releases metal ions, and subsequently adds iron salt for co-precipitation, thereby breaking through the problems of slow treatment and low efficiency of traditional treatment methods for stable complexes.

The invention discloses an oral cavity whitening composition, whitening toothpaste and a tooth whitening method. The oral cavity whitening composition contains 0.1-5% by mass of whitening functional components, wherein the whitening functional components at least comprise potassium hydrogen peroxymonosulfate and / or potassium peroxydisulfate; and 0.1-2% by mass of a catalyst, wherein the catalyst is at least one of a chloride ion supply source, titanium dioxide and percarbonate; the chloride ion supply source is at least one of sodium chloride, zinc chloride and potassium chloride; the percarbonate is sodium percarbonate. According to the oral cavity whitening composition, the screened catalyst is combined with potassium peroxymonosulfate and / or potassium peroxydisulfate in a specified dosage range, so that stable storage of whitening functional components can be realized, an efficient whitening effect can be achieved during use, and efficient and stable application of the whitening functional components in daily care products is realized; the oral cavity whitening composition disclosed by the invention has the effects of low irritation and strong whitening property, and is high in whitening speed and good in effect.