A molten aluminum alloy refining slag removal agent is characterized by being composed of, by weight, 25%-30% of silicon dioxide, 10%-15% of sodium chloride, 10%-15% of potassium oxide, 5%-10% of sodium oxide, 5%-10% of sodium sulfate, 1%-5% of sodium fluoroaluminate, 5%-10% of sodium fluorosilicate, 1%-5% of titanium dioxide, 5%-10% of calcium fluoride, 2%-4% of potassium fluoride, 2%-4% of hydrogen fluoride and 2%-4% of silicic acid. The molten aluminum alloy refining slag removal agent has the advantages that by the adoption of the sodium chloride and the potassium fluoride, the infiltration effect of molten aluminum is guaranteed, separation of hydrogen in the molten aluminum is guaranteed by the adoption of the potassium fluoride, the molten aluminum alloy refining slag removal agentis high in reliability, high in separation capacity, convenient to prepare, easy to use, low in cost and the like, and meanwhile the molten aluminum alloy refining slag removal agent can be widely applied to the molten aluminum refining aspect.