The invention discloses a
halogen-free
flame-retardant high-adhesion
epoxy structural
adhesive film as well as a preparation method and application thereof. The preparation method comprises the following steps: reacting
phosphorus-containing
polyol with general-purpose diisocyanate to obtain an
isocyanate-terminated
polyurethane prepolymer, then adding liquid
epoxy resin, in the presence of a catalyst, initiating a ring-opening reaction between
isocyanate and an
epoxy group to generate an oxazolidinone heterocyclic ring, and then introducing
cardanol modified linear phenolic resin to react with the epoxy group to obtain the oxazolidinone modified phenolic resin. And finally, uniformly mixing the modified epoxy resin with a latent curing
system, and
coating a film, so as to prepare the
halogen-free
flame-retardant high-adhesion epoxy structural
adhesive film. The preparation process is reasonable, the
flame retardance and
heat resistance of the
adhesive film are improved through the synergistic flame retardant effect of
phosphorus-
nitrogen and the synergistic effect of phenolic resin while the excellent
processing property of the adhesive film is guaranteed, and the adhesive property of a resin
system is improved through the synergistic effect of a strong-polarity
carbamate structure and the modified linear phenolic resin.