The invention discloses high-gloss anti-warping toughened nylon PA66/PC alloy and a preparation method thereof. The alloy comprises the following components in parts by weight: 60-80 parts of polyamide resin (PA66), 20-40 parts of polycarbonate (PC), 5-15 parts of a compatilizer, 0.02-0.05 part of an antioxidant 1098, 0.02-0.05 part of an antioxidant 626 and 0.5-2 parts of a lubricant. The alloy has the characteristics of high gloss, smooth surface, toughening, warping prevention, dimensional stability and the like, is used for engineering plastics of structures and appearance parts of electronics, electric appliances, automobiles and the like, is prepared from safe and environment-friendly raw materials, and is widely applied to structural parts, appearance parts and other products with high gloss, good toughness and dimensional stability requirements in the fields of household appliances, machinery, automobiles and the like.