32results about How to "Increased permeability selectivity" patented technology

The invention discloses a preparation method of a polyamine nanoparticle self-assembled nanofiltration membrane. Polyamine monomer molecules are adopted as raw materials, polyamine is taken as a bionic adhesive, the polyamine nanoparticles are formed through auto-polymerization in an aqueous solution, and the polyamine nanocomposite nanofiltration membrane is prepared by in-situ self-assembly and interfacial cross-linking on the surface of a porous support membrane. By regulation of the surface self-assembly behavior and the interfacial crosslinking process of the polyamine nanoparticles, the thickness, the crosslinking degree and surface properties of a nano-separation layer can be optimized, and the nanofiltration membrane with high permeation selectivity and good stability can be obtained. The water flux of the nanofiltration membrane in operating pressure of 0.6MPa is 80-150 Lm<-2>.h<-1>, the organic matter molecular interception rate can be as high as 98%, and the inorganic salt ion interception rate is generally lower than 30%. Therefore, the prepared polyamine nano-composite nanofiltration membrane has high separation selectivity and water permeation flux; the preparation method of the membrane is simple, convenient, controllable and low in cost, thereby having good industrial application prospect.

The invention discloses an MOFs (metal-organic frameworks)-cross-linked polyethylene glycol diacrylate mixed substrate membrane, a preparation and an application. PEGDA (polyethylene glycol diacrylate) is selected as substrate membrane materials, MOFs are selected as fillers, and the MOFs-cross-linked polyethylene glycol diacrylate mixed substrate membrane is prepared by ultraviolet crosslinking and curing under induction of photo-initiators. The mixed substrate membrane has remarkable performances (PCO2>160Barrer, alpha CO2 / N2>70, alpha CO2 / CH4>40) for separating mixed gas of CO2 / N2 and CO2 / CH4. Compared with a pure cross-linked polyethylene glycol diacrylate membrane, the MOFs-cross-linked polyethylene glycol diacrylate mixed substrate membrane has higher CO2 gas permeability and separation selectivity, and can be applied to purification of flue gas and natural gas.

The invention relates to a uniwafer type bipolar ion exchange membrane and a method for preparing the same. An anion exchange layer and a cation exchange layer of a bipolar membrane are combined on two sides of the same carrier material respectively or the same side of a uniwafer type ion exchange membrane. The preparation method comprises the following steps that: a, according to certain proportion, an evocating agent, a functional monomer, a comonomer, a crosslinking agent and other additional compositions are prepared into a reaction solution of the corresponding ion exchange layer; and b, according to different carriers, the method carries out single side or double side coating treatment, that is the reaction solution is coated on the carrier material with certain thickness; the carrier material is positioned in an ultraviolet source and is radiated so that the carrier material is cured to obtain the ion exchange layer of one side; the other side of the ion exchange layer is coated with another reaction solution, positioned in the ultraviolet source and is radiated and cured, and according to requirements, cured membrane is positioned in a corresponding ionized treating solution and treated to obtain an ion exchange layer; and the bipolar membrane of the uniwafer type ion exchange layer is finally obtained. The voltage drop of two sides of the membrane is reduced; and the method has low cost and rapid reaction speed and is simple and feasible.

The invention discloses a preparation method of a glycine betaine colloid nano particle modified chitosan nanofiltration membrane which comprises a porous polysulfone support layer and a functional layer formed by glycine betaine colloid nano particle modified chitosan. The preparation method comprises the steps of: firstly, carrying out solution polymerization reaction to obtain a glycine betaine colloid nano particle; and then preparing the nano particle, chitosan and a cross-linking agent into a water solution with a certain concentration, dipping one layer of water solution on the surface of the porous polysulfone support layer, and then curing and crosslinking to obtain the nanofiltration membrane. According to the nanofiltration membrane, under the operation pressure of 0.6MPa, the water flux is 25-35L.m<-2>.h<-1>, the retention rate of divalent cations is generally higher than 97 percent, and the retention rate of monovalent salts is lower than 60 percent; meanwhile, the nanofiltration membrane shows good pollution resistance. Therefore, the prepared glycine betaine colloid nano particle modified chitosan nanofiltration membrane has high permeation selectivity and pollution resistance; the preparation method is simple and easy to operate and low in cost, and has a good industrialized application prospect.

The invention discloses a polyvinylamine film with a branched network structure as well as a preparation method and an application of the film. The film consists of a polyethyleneimine modified indianite tube composite and a polyvinylamine substrate in the mass ratio being (0.1-5.0):100. Firstly, polyethyleneimine with a branched network structure is supported on indianite nanotubes with an electrostatic self-assembling technology, then, the polyethyleneimine modified indianite nanotubes and polyvinylamine are blended, a membrane casting solution is obtained and applied to the surface of a microporous filter membrane, and the functional polyvinylamine film with the branched network structure is prepared and has the thickness of 1-100 mu m. By means of the polyethyleneimine modified indianite nanotubes, crystallization of polyvinylamine molecular chains can be reduced, the polyethyleneimine modified indianite nanotubes with the branched network structure are uniformly dispersed in the polyvinylamine film, and a rapid delivery channel is provided for CO2.

The invention discloses a high-permeability selective acid-resistant nanofiltration membrane material as well as a preparation method and application thereof. The nanofiltration membrane material comprises a dense separation layer which is formed by assembling an amine and a quaternary ammonium salt polycation electrolyte and a polyanion electrolyte material with sulfonic acid groups or sulfuric acid groups layer by layer; the concentration of the polycation is 0.1-20 g / L, and the polycation is dissolved in a salt solution of 0.05-5 mol / L; the used polyanion electrolyte polymer material is a polymer material with sulfonic acid groups or sulfuric acid groups, the concentration of polyanion is 0.1-20g / L, and the polyanion is dissolved in a 0.05-5mol / L salt solution; the dense separation layer of the nanofiltration membrane is formed by layer-by-layer assembly, and has better permeation selectivity and excellent acid-resistant stability than a commercial nanofiltration membrane. The retention rate of the membrane to multivalent cations is greater than 90%, the permeability of the membrane to phosphoric acid is greater than 80%, and the permeability of phosphoric acid is one order of magnitude layer than that of that of a commercial membrane. The high-permeability selective acid-resistant nanofiltration membrane material is used in phosphoric acid refining and recycling processes, inorganic compounds in phosphoric acid-containing feed liquid are removed through pretreatment, then substances such as large particles and colloids are removed through ultrafiltration, stable operation of a nanofiltration membrane process is achieved, high-purity phosphoric acid of different grades is obtained, and the high-permeability selective acid-resistant nanofiltration membrane material has wide application in the aspects of phosphoric acid refining and phosphoric acid recycling.

The invention discloses a preparation method of an ultra-low-pressure and high-flux metal-organic nano particle assembly nanofiltration membrane. Polyamine molecules and polyoxometalates serve as rawmaterials, dopamine serves as a biomimetic adhesive, and organic nano particle seeds loaded with metal ions are generated in a water solution through oxidation polymerization; the surface of a poroussupport membrane is coated with an aqueous dispersion of the nano particle seeds, and a membrane is formed through assembly; the membrane is soaked with an organic ligand solution, metal-organic nanoparticles are formed on the surface of the membrane, and finally, through interface crosslinking, the high-permselectivity and high-stability metal-organic nano particle assembly nanofiltration membrane is obtained. The metal-organic nano particle assembly nanofiltration membrane prepared by using the preparation method has the advantages that the structure and the characteristics of the membranecan be controlled, the operation pressure is low, the water flux is high, the separation selectivity is high, and the preparation method is simple and suitable for industrialized application.

The invention discloses a preparation method of a fluorinated organic nanoparticle-containing polyamide solvent-resistant nanofiltration membrane. Polyamine, dopamine and a fluoroalkyl mercaptan compound are used as reactive monomers, fluorinated organic nanoparticles are formed through Michael addition and Schiff base reaction, and then the fluorinated organic nanoparticles and polybasic acyl chloride form the polyamide membrane containing the fluorinated organic nanoparticles on the surface of the porous support membrane through interfacial polymerization reaction. The characteristic of lowsurface energy of the fluorinated organic nanoparticles is utilized, the interface polymerization process is regulated and controlled; the chemical composition, the microstructure and the hydrophilicity and the hydrophobicity of the polyamide separation layer are optimized, the polyamide solvent-resistant nanofiltration membrane having the unique pore channel structure is obtained, the prepared membrane has characteristics of high separation selectivity and high solvent permeation flux, the membrane preparation method is simple, easy to regulate and control, and the good industrial applicationprospect is provided.

The invention discloses a preparation method of a mixed matrix membrane material, and belongs to the technical field of membrane materials. Porous MIL-101 (Cr) particles with the particle size of 200-300 nm are prepared by adopting a solvothermal synthesis method, different amounts of MIL-101 are uniformly dispersed in an MOF dispersion liquid by adopting a stirring-ultrasonic treatment method, the formed solution is added into an ethanol / water solution of high polymer polyether block amide, a series of mixed matrix membranes with different composition proportions are obtained by adopting a natural tape casting method. The method comprises the following steps: preparing the MIL-101 (Cr), preparing the MIL-101-coated Pebax membrane and the like. A permeability comparison diagram shows that MIL-101-coated Pebax mixed matrix membranes with different composition proportions have certain permeability selectivity to ethylbenzene / N2, and along with the increase of the doping amount of MIL-101, the permeation rate of ethylbenzene is increased, and the permeability is improved. The method can be used for separating the VOCs-containing waste gas.

The invention discloses a preparation method of a hollow fiber membrane for removing carbon dioxide from natural gas, belonging to the technical field of gas separation membranes. The method comprisesthe following steps: dissolving MOF particles and a high polymer material in a polar organic solvent to prepare a uniformly mixed spinning solution; filtering the spinning solution, carrying out vacuum defoaming treatment, and performing standing at a spinning temperature; spinning the spinning solution by adopting a dry-wet phase inversion method to prepare a mixed matrix hollow fiber membrane;and drying the hollow fiber membrane by adopting a solvent replacement method, and coating the outer surface of the hollow fiber membrane with a silicone rubber layer. According to the invention, theMOF particles are added into the high polymer material; due to the fact that the MOF particles can provide a high specific surface area and a micropore structure, the gas permeability and separation selectivity of the hollow fiber membrane are improved and the permeation selectivity of the hollow fiber membrane is effectively improved through introduction of the MOF particles; and the preparationmethod is simple in process, easy to operate and good in industrial practicability.

The invention discloses a preparation method of an assembled membrane based on triazine porous organic nano particles. The preparation method comprises the following steps: taking a triazine derivative, a 1,2-dicarbonyl compound and an aldehyde compound as reaction monomers, preparing triazine porous organic nano particles in an acetic acid aqueous solution through a Debus-Radziszewski reaction; mixing the triazine porous organic nano particles with cationic polyelectrolyte to prepare dispersion liquid, and preparing the assembled membrane based on triazine porous organic nano particles on thesurface of a porous support membrane through a pressurized deposition filtration-chemical crosslinking method. The prepared assembled membrane has an efficient dye desalination performance and good stability, and can be applied to the application fields of dye purification, wastewater treatment and the like.

The invention belongs to the technical field of gas membrane separation, and provides a preparation method of an MOFs and polymer bicontinuous mixed matrix membrane. The preparation method comprises the following steps: adding inorganic metal salt particles into an electrospinning polymer for electrostatic spinning, then calcining and converting into metal oxide fibers, then taking oxide nanofibers as a self-sacrifice template, growing MOFs in situ through'coordination-replication ', maintaining the balance between template dissolution and MOFs nucleation, and converting the metal oxide nanofiber mat into the MOFs nanofiber mat. Functional small molecules with low molecular weight are polymerized into gaps of the MOFs nanofibers in situ, so that the compact MOFs / PDA mixed matrix gas separation membrane with high air permeability is constructed. The MOFs / PDA can provide a low-resistance rapid transfer path, selective screening of gas molecules is realized, and the prepared gas separation membrane has the characteristics of high permeability, high selectivity and high mechanical strength, so that the application prospect of the membrane is wider.

Disclosed herein is a gas separation membrane for a DEM production process, including: a porous support having a carbon dioxide permeability of more than 300 GPU (GPU=1*10-6 cm<3> / cm<2> sec cmHg) and an inner diameter of 100~1000 micrometers; and a composite membrane provided on an inner or outer surface of the porous support and coated with a separating material having a permeation selectivity of carbon dioxide / hydrogen of 4 or more. The gas separation membrane is advantageous in that it can improve efficiency of the separation process by selectively separating and removing carbon dioxide from a gas mixture of carbon dioxide and hydrogen produced during a process of producing DME which is a next-generation clean fuel.

The invention belongs to the technical field of blended matrix membrane separation, and particularly relates to a MoS2 / organic silicon blended matrix membrane, a preparation method and an application thereof, and the method comprises the following steps: preparing organic silicon sol from organic alkoxy silane through a hydrolytic polymerization method; uniformly mixing the MoS2 dispersion liquid with organic silicon sol to prepare MoS2 / organic silicon dispersion liquid; and coating the support body with the MoS2 / organic silicon dispersion liquid, and calcining to obtain the MoS2 / organic silicon blended matrix membrane. The MoS2 / organic silicon blended matrix membrane prepared by the method has good H2 permeability and selectivity, and can be applied to separation of hydrogen in mixed gas.

The invention discloses a charged composite nanofiltration membrane based on organic-inorganic nanoparticles and a preparation method of the charged composite nanofiltration membrane. The nanofiltration membrane is composed of a supporting layer and a nanofiltration functional layer, the nanofiltration functional layer is formed by cross-linking cross-linked ionic amphiphilic polymer nanoparticles and inorganic nanoparticles, the ionic amphiphilic polymer nanoparticles are mutually cross-linked, and the inorganic nanoparticles and the ionic amphiphilic polymer nanoparticles are mutually cross-linked; the supporting layer is crosslinked with the nanofiltration functional layer through reactive groups on the surface of the supporting layer; according to the preparation method of the nanofiltration membrane, the nanofiltration membrane in a flat, hollow fiber or tubular form can be prepared, the prepared nanofiltration membrane is high in flux, efficient separation of ions and charged small molecules of different valence states can be achieved through the charge characteristic of the nanofiltration membrane, and the nanofiltration membrane is excellent in pressure resistance and has the potential of treating high-concentration brine; the method has great application value in the fields of seawater desalination, ion separation, sewage treatment, hard water softening, biological medicine, food processing and the like.

The invention provides a preparation method for a high-performance polyimide hollow fiber membrane. The hollow fiber membrane is prepared by using a dry-wet spinning technology, and the mechanical strength and the solvent resistance of the polyimide hollow fiber membrane are improved by using a high-temperature annealing method. When the annealing temperature is close to the glass-transition temperature, the annealing process can improve the tensile strength of the polyimide hollow fiber membrane, and when the annealing temperature is higher than the glass-transition temperature, the tensile strength and the solvent resistance of the polyimide hollow fiber membrane can be obviously improved. The method is simple and effective, and has a good application prospect in the aspect of gas separation.

The invention provides a nitrogen-containing natural gas membrane separation process with low-temperature enhancement of permeation selectivity, and belongs to the field of petrochemical industry. Nitrogen-containing natural gas is subjected to pretreatment such as compression and dehydration, then high-efficiency and high-yield methane concentration is realized through a multi-stage low-temperature membrane process, and commercial natural gas with the nitrogen content being less than 4.0 vol% is produced. According to the separation process disclosed by the invention, the permeation selectivity is remarkably improved by reducing the operation temperature of a membrane, so that the separation efficiency and the methane recovery rate are improved; and through throttling refrigeration of membrane permeation, expansion refrigeration of high-pressure tail gas and compression refrigeration driven by a turbine, sufficient cooling capacity is provided for the low-temperature membrane process, and it is avoided that external energy is consumed to drive a refrigeration system. By adopting the membrane separation process provided by the invention, feed gas with the single power consumption of about 0.22 kWh / Nm<3> and the nitrogen content of about 30 vol% is produced, and the methane recovery rate exceeds 75.0%.

The invention provides a preparation method for a high-performance polyimide hollow fiber membrane. The hollow fiber membrane is prepared by using a dry-wet spinning technology, and the mechanical strength and the solvent resistance of the polyimide hollow fiber membrane are improved by using a high-temperature annealing method. When the annealing temperature is close to the glass-transition temperature, the annealing process can improve the tensile strength of the polyimide hollow fiber membrane, and when the annealing temperature is higher than the glass-transition temperature, the tensile strength and the solvent resistance of the polyimide hollow fiber membrane can be obviously improved. The method is simple and effective, and has a good application prospect in the aspect of gas separation.

The invention discloses a method for preparing a nanofiltration membrane assembled with ultra-low pressure and high flux metal-organic nanoparticles. Polyamine molecules and metal salts are used as raw materials, and dopamine is used as a bionic binder, and are oxidized and polymerized in an aqueous solution to form loaded metal ions. The above organic nanoparticle seeds are coated with the above nanoparticle seed aqueous dispersion on the surface of the porous support membrane and assembled into a membrane, and then impregnated with an organic ligand solution to form metal-organic nanoparticles on the membrane surface, and finally crosslinked through the interface , to obtain metal-organic nanoparticle-assembled nanofiltration membranes with high permeability selectivity and good stability. The prepared metal-organic nanoparticle-assembled nanofiltration membrane has the characteristics of controllable membrane structure and performance, low operating pressure, high water flux, good separation selectivity, simple preparation method, suitable for industrial application and the like.

The invention discloses a method for preparing a membrane based on triazine-based porous organic nanoparticle assembly, using triazine derivatives, 1,2-dicarbonyl compounds and aldehyde compounds as reaction monomers, and passing Debus- Radziszewski reaction to prepare triazine-based porous organic nanoparticles; then mix it with cationic polyelectrolyte to prepare a dispersion liquid, and prepare a membrane based on triazine-based porous organic nanoparticles on the surface of the porous support membrane by pressure deposition filtration-chemical cross-linking method . The triazine-based porous organic nanoparticle assembly membrane prepared by the invention has both high-efficiency dye desalination performance and good stability, and can be applied to application fields such as dye purification and wastewater treatment.

The invention discloses a preparation method of a polyamine nanoparticle self-assembled nanofiltration membrane. Polyamine monomer molecules are adopted as raw materials, polyamine is taken as a bionic adhesive, the polyamine nanoparticles are formed through auto-polymerization in an aqueous solution, and the polyamine nanocomposite nanofiltration membrane is prepared by in-situ self-assembly and interfacial cross-linking on the surface of a porous support membrane. By regulation of the surface self-assembly behavior and the interfacial crosslinking process of the polyamine nanoparticles, the thickness, the crosslinking degree and surface properties of a nano-separation layer can be optimized, and the nanofiltration membrane with high permeation selectivity and good stability can be obtained. The water flux of the nanofiltration membrane in operating pressure of 0.6MPa is 80-150 Lm<-2>.h<-1>, the organic matter molecular interception rate can be as high as 98%, and the inorganic salt ion interception rate is generally lower than 30%. Therefore, the prepared polyamine nano-composite nanofiltration membrane has high separation selectivity and water permeation flux; the preparation method of the membrane is simple, convenient, controllable and low in cost, thereby having good industrial application prospect.

The invention discloses an MOFs (metal-organic frameworks)-cross-linked polyethylene glycol diacrylate mixed substrate membrane, a preparation and an application. PEGDA (polyethylene glycol diacrylate) is selected as substrate membrane materials, MOFs are selected as fillers, and the MOFs-cross-linked polyethylene glycol diacrylate mixed substrate membrane is prepared by ultraviolet crosslinking and curing under induction of photo-initiators. The mixed substrate membrane has remarkable performances (PCO2>160Barrer, alpha CO2 / N2>70, alpha CO2 / CH4>40) for separating mixed gas of CO2 / N2 and CO2 / CH4. Compared with a pure cross-linked polyethylene glycol diacrylate membrane, the MOFs-cross-linked polyethylene glycol diacrylate mixed substrate membrane has higher CO2 gas permeability and separation selectivity, and can be applied to purification of flue gas and natural gas.

Epitaxial thin films for use as buffer layers for high temperature superconductors, electrolytes in solid oxide fuel cells (SOFC), gas separation membranes or dielectric material in electronic devices, are disclosed. By using CCVD, CACVD or any other suitable deposition process, epitaxial films having pore-free, ideal grain boundaries, and dense structure can be formed. Several different types of materials are disclosed for use as buffer layers in high temperature superconductors. In addition, the use of epitaxial thin films for electrolytes and electrode formation in SOFCs results in densification for pore-free and ideal grain boundary / interface microstructure. Gas separation membranes for the production of oxygen and hydrogen are also disclosed. These semipermeable membranes are formed by high-quality, dense, gas-tight, pinhole free sub-micro scale layers of mixed-conducting oxides on porous ceramic substrates. Epitaxial thin films as dielectric material in capacitors are also taught herein. Capacitors are utilized according to their capacitance values which are dependent on their physical structure and dielectric permittivity. The epitaxial thin films of the current invention form low-loss dielectric layers with extremely high permittivity. This high permittivity allows for the formation of capacitors that can have their capacitance adjusted by applying a DC bias between their electrodes.

The invention discloses a preparation method of a positively charged composite nanofiltration membrane. The preparation method specifically comprises the following steps: (1) preparing a water phase solution; (2) preparing an organic phase solution; and (3) preparing the positively charged composite nanofiltration membrane. Compared with a pure polyethyleneimine nanofiltration membrane, the positively charged composite nanofiltration membrane is higher in permeation selectivity and stronger in anti-pollution capacity.

The invention discloses a method for synchronously defluorinating and denitrifying by using a composite absorbent, which is characterized in that the composite absorbent consisting of a hydrophobic ionic liquid membrane and an alkaline aqueous solution is used for treating tail gas containing fluorine and nitrate to realize synchronous purification and selective separation of NO and HF; wherein the hydrophobic ionic liquid membrane is prepared by immersing a block-shaped dry membrane body into hydrophobic ionic liquid, standing, carrying out solid-liquid separation, drying and crushing; compared with the prior art, the composite absorbent provided by the invention has the advantages of simple synthesis, small solvent loss, large absorption capacity, good absorption effect and the like, the ionic liquid membrane has relatively strong permeation selectivity on NO, and water in the composite absorbent has a relatively high absorption effect on HF, so that NO and HF can be purified at the same time, and the two gases can be separated.

The invention provides a nitrogen-containing natural gas membrane separation process with enhanced permeation selectivity at low temperature, which belongs to the field of petrochemical industry. Nitrogen-containing natural gas undergoes pretreatment such as compression and dehydration, and then achieves high-efficiency and high-yield methane concentration through a multi-stage low-temperature membrane process to produce commercial natural gas with a nitrogen content of <4.0vol%. The separation process of the present invention significantly improves the permeation selectivity by reducing the operating temperature of the membrane, thereby improving the separation efficiency and methane recovery rate; throttling refrigeration through membrane permeation, expansion refrigeration of high-pressure tail gas, and compression refrigeration driven by turbines , to provide sufficient cooling capacity for the low-temperature membrane process, and avoid consuming external energy to drive the refrigeration system. Using the membrane separation process provided by the invention, the unit power consumption for production is about 0.22kWh / Nm 3 For feed gas with a nitrogen content of about 30 vol%, the methane recovery rate exceeds 75.0%.

The invention discloses a star carbon dioxide fixed carrier which is characterized in that the fixed carrier is a polymer taking CD as a core and PGED as an arm. The fixed carrier is established by an atom transfer radical polymerization method, the method has a smooth polymerization reaction and is easy to control, and the star CO2 fixed carrier with different arm numbers, different arm lengths, different molecular weights and narrow molecular weight distribution can be prepared according to the needs. The prepared CO2 fixed carrier has good storage stability, the amino on the arm is a CO2 promoting transfer carrier, and therefore, the fixed carrier can be used as a separating membrane material, and has CO2 selective permeability, high permeation selectivity on a CO2 / CH4 system, and has the application potential in a methane purification technology.