The invention discloses a high-performance composite adsorbing material and a preparing method and application thereof. The composite material is prepared from powdery zeolite, powdery active carbon,wood pulp fibers, special fibers, an insoluble fire retardant and an adhesive. Multiple components of the special fibers, the active carbon, the zeolite and the insoluble fire retardant are added intothe composite adsorbing material prepared with the method, and the composite adsorbing material has the advantages of being high in fire resistance, good in hydrophobicity, heat stability and chemical stability, developed in pore structure, large in specific area, high in mechanical strength, not prone to pulverization, controllable in gas channel, wide in application range and the like, and is particularly suitable for adsorption purification of all kinds of VOCs waste gas. According to the high-performance composite adsorbing material and the preparing method and application thereof, a source of raw materials is wide, the technology process is simple, fiber products (felt, bands, cloth and the like) with different forms can be freely processed, and the composite adsorbing material has the advantages of being high in adsorption capacity, capable of achieving in-situ regeneration and recycling, high in adsorption/desorption rate, small in pressure drop and the like in application of fixed bed adsorption and rotating wheel adsorption.