The invention discloses a method for manufacturing a solar double-glass assembly. The method includes the following steps that (1) a PVB adhesive film, a solar battery string, a PVB adhesive film and surface layer tempered glass are sequentially laid on bottom layer tempered glass, so that the solar double-glass assembly is formed; (2) whether hidden cracking pieces exist in solar battery pieces of the double-glass assembly in the first step is checked, and the hidden cracking pieces are removed; (3) the double-glass assembly is placed in a laminating machine under the -1 barometric pressure, the process is kept for 30-40 minutes, then an upper chamber of the laminating machine is placed at the pressure of -0.5 MPA, a lower chamber is placed at the pressure of -1 MPA, the process is kept for 20-30 minutes, afterwards, the temperature rises to be 140+/-5 DEG C, and at the pressure of -0.5 MPA to -0.6 MPA, the process is kept for 20-30 minutes; (4) whether hidden cracking pieces exist in the solar battery pieces of the laminated double-glass assembly is checked, and the hidden cracking pieces are removed; (5) the double-glass assembly is fixed, the double-glass assembly is placed in an autoclave, and after a dehumidifier is used for dehumidifying, under the conditions of 20-150 DEG C and 0-1.3 MPA, the process is kept for 2-4 hours.