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60results about How to "Reduce desulfurization operating costs" patented technology

System device and method for recycling sulfur dioxide from fume to prepare sulfur

The invention discloses a system device and a method for recycling sulfur dioxide from fume to prepare sulfur. The device comprises three units of an absorption and pyrolysis unit, a reduction unit and a krauss unit, wherein the absorption and pyrolysis unit mainly consists of a cooling tower, an absorbing tower, a purifier, a circulation pump, a regeneration pyrolysis tank and a rich and lean liquid heat exchanger; the reduction unit mainly consists of a mixed gas generation system, a reduction reactor and a sulfur condenser; the krauss unit mainly consists of a krauss reactor and a sulfur condenser. The method comprises the steps that the absorption and pyrolysis unit absorbs and pyrolyzes the fume so as to obtain a pure sulfur dioxide gas, and the reduction unit converts the sulfur dioxide into elementary sulfur through catalysis reaction, wherein the conversion per pass is not less than 95%, and the total conversion is greater than 99.5%. The sulfur dioxide content that the fume is completely discharged is not greater than 50 milligrams per normal cubic meter. The sulfur dioxide is converted into national best grade sulfur products which are stable in property and convenient to store and transport, with high efficiency and low cost, the desulfuration operation cost is lower than the value of a recycled product, and the products can be widely applied to chemistry and thermal power industry.
Owner:陕西华锐迪橡胶科技有限公司

Activated carbon diatomite particles with well-developed pores and low cost and method for preparing activated carbon diatomite particles with well-developed pores and low cost.

The invention discloses activated carbon diatomite particles with well-developed pores and low cost. The activated carbon diatomite particles are characterized by being prepared from the following raw materials in parts by weight: 95-105 parts of fruit shell activated carbon, 30-35 parts of diatomite, 18-22 parts of traditional Chinese medicine residues, 22-26 parts of tung seed shells, 6-9 parts of kaoline, 1-2 parts of a silane coupling agent kh560, 3-4 parts of sodium sulfate, 4-6 parts of limestone powder, 2.5-3.5 parts of vitrified microspheres, 3.5-5 parts of silicon micro-powder, 3-5 parts of clay, 3-5 parts of active aluminum oxide, 4-6 parts of an absorbent additive and an appropriate amount of water. According to the method for preparing the activated carbon diatomite particles with the well-developed pores and the low cost, the materials such as the traditional Chinese medicine residues, and the tung seed shells are reused, dried, crushed and then added into the activated carbon and the diatomite, and the particles have sufficient sources of raw materials, the well-developed pores, the high absorption ability and the excellent property; the absorbent additive gives the special porosity of the particles and increases the contact time between gas and each particle; the particles prepared according to the method have the good desulfurization dedusting effect and the high porosity, and is low in cost and simple in production process, and therefore, the operation cost of dry desulfurization is greatly reduced.
Owner:广州大津健康建筑技术有限公司

Liquid-phase oxidation catalyst for fire coal flue gas desulfurization

The invention discloses a liquid phase oxidation catalyst which is used to desulphurize fire coal flue gas. The invention comprises a surface active agent, M2+1, M3+2 and industrial-grade urea, wherein the mass ratio between the surface active agent and the industrial grade urea is 1:40-1:60, the solution mass concentration ratio between the M2+1and the M3+2 is 10:1-30:1, the mass ratio between the surface active agent and the M2+1 is 1:80-1:90, and M is Mn or Fe or Mg. The oxidative catalyst of the invention is very easy to be dissolved in water, and water solution is weakly-acidic. Density range is 2.75-2.93*103kg.m-3, and physiochemical stability is comparatively good. The invention only has catalytic oxidative effect in the process of flue gas desulphurization and no consumption theoretically, and can be used in circulation. The oxidative catalyst of the invention is adopted to desulphurize the fire coal flue gas, desulphurizing efficiency can be increased, simultaneously a desulphurizing process can be simplified (without an oxidation draught fan process), the operational cost of the flue gas desulphurization can be lowered greatly, and the invention has great practical applicable value and wide applicable foreground.
Owner:ZHEJIANG GONGSHANG UNIVERSITY

Desulphurizing tower for desulphurizing with seawater soda-residue emulsion

InactiveCN101444698AVersatileSimplified desulfurization processDispersed particle separationSeawaterOperating cost
The invention discloses a desulphurizing tower for desulphurizing with seawater soda-residue emulsion. A defogging section, a seawater absorption section, a seawater soda-residue emulsion absorption section, an oxidation section and a clarification section are sequentially arranged inside the tower from top to bottom. A flue gas inlet is arranged on the side of the tower positioned between the seawater soda-residue emulsion absorption section and the oxidation section, a flue gas outlet is arranged at the top of the tower, a sediment outlet is arranged at the bottom of the tower, and a clarified liquid outlet is arranged on the side of the tower positioned on the upper part of the clarification section. The desulphurizing tower has multiple functions including absorption, oxidation, clarification and fog removal, so as to simplify desulphurizing process; and the flue gas exhaust and water drainage both achieve National Standard. The desulphurizing tower also has the advantages of low equipment investment, small floor area, low operating cost, convenient operation, and high flue gas desulphurizing efficiency (up to 95%); realizes simultaneous treatment of soda-residue and sulfur dioxide in flue gas; and is suitable for flue gas desulphurization in boilers of large-sized, middle-sized and small-sized thermal power stations of ammonia-soda process soda ash production plants in a coastal area, as well as industrial boilers and kilns in industrial and mining establishments.
Owner:QINGDAO SODA ASH IND DEV CO LTD +1

Method of desulfuration using powder dust and flue gas from calcium carbide stove

The invention provides a method for utilizing calcium carbide furnace dust and flue gas for desulfurization,and belongs to a coal fired boiler desulfurization method. Furnace gases containing dust and flue gases, which are generated during the production of the calcium carbide furnace, are transferred to a furnace hearth above a grate of the coal fired boiler, calcium oxide in the dust makes the over reaction with sulfur dioxide generated when coal burns, and the generated calcium sulfate is discharged along with slag; and, calcium steam in the flue gas enters a boiler flue and undergoes over reaction with sulfur dioxide in the flue, and the generated crystal is removed from the flue gas by an electric dust removing device in the flue. The desulfurization method not only eliminates the pollution of the dust and flue gas generated in the process of producing calcium carbide, but also uses the dust and flue gas to desulfurize the coal fired boiler, so that the method has the advantages of realizing the combat-pollutant-with-pollutant, having good desulfurization effect, and having low desulfurization operation cost, and the desulfurization efficiency is more than 90 percent; moreover, because the dust and flue gas are high in temperature and contain a large amount of coke powder and carbon monoxide, and the dust and flue gas are cofired with coal, the coal is saved.
Owner:WUDI XINXING THERMOELECTRICITY

System device and method for recycling sulfur dioxide from fume to prepare sulfur

The invention discloses a system device and a method for recycling sulfur dioxide from fume to prepare sulfur. The device comprises three units of an absorption and pyrolysis unit, a reduction unit and a krauss unit, wherein the absorption and pyrolysis unit mainly consists of a cooling tower, an absorbing tower, a purifier, a circulation pump, a regeneration pyrolysis tank and a rich and lean liquid heat exchanger; the reduction unit mainly consists of a mixed gas generation system, a reduction reactor and a sulfur condenser; the krauss unit mainly consists of a krauss reactor and a sulfur condenser. The method comprises the steps that the absorption and pyrolysis unit absorbs and pyrolyzes the fume so as to obtain a pure sulfur dioxide gas, and the reduction unit converts the sulfur dioxide into elementary sulfur through catalysis reaction, wherein the conversion per pass is not less than 95%, and the total conversion is greater than 99.5%. The sulfur dioxide content that the fume is completely discharged is not greater than 50 milligrams per normal cubic meter. The sulfur dioxide is converted into national best grade sulfur products which are stable in property and convenient to store and transport, with high efficiency and low cost, the desulfuration operation cost is lower than the value of a recycled product, and the products can be widely applied to chemistry and thermal power industry.
Owner:陕西华锐迪橡胶科技有限公司

Low-cost activated carbon kieselguhr particles with developed pores, and preparation method of kieselguhr particles

The invention discloses low-cost activated carbon kieselguhr particles with developed pores. The activated carbon kieselguhr particles are characterized by being prepared from the following raw materials in parts by weight: 95-105 parts of nut shell activated carbon, 30-35 parts of kieselguhr, 18-22 parts of Chinese medicine residue, 22-26 parts of tung shell, 6-9 parts of kaolin, 1-2 parts of a silane coupling agent kh560, 3-4 parts of sodium sulfate, 4-6 parts of limestone powder, 2.5-3.5 parts of glass beads, 3.5-5 parts of silica powder, 3-5 parts of clay, 3-5 parts of activated aluminum oxide, 4-6 parts of an absorption auxiliary agent and a proper amount of water. According to the activated carbon kieselguhr particles, the resources such as Chinese medicine residue, tung shell are reused and are fed into the activated carbon and the kieselguhr after being dried and ground; the activated carbon kieselguhr particles are sufficient in raw materials, developed in pores, high in absorption and excellent in performances; the absorption auxiliary agent is fed into the activated carbon kieselguhr particles, so that the activated carbon kieselguhr particles have special porosity, and the contact time of the activated carbon kieselguhr particles with air can be prolonged; the activated carbon kieselguhr particles have good desulfurization and dust-removal effects, are high in porosity, low in cost and simple in production technology, and are capable of greatly lowering the operating cost of dry desulfurization.
Owner:ANHUI PHOENIX INT CO LTD

Coal slime fluidized bed boiler desulfurization collaborative optimization operation method

The invention relates to the field of SO<2> pollutant treatment of coal-fired power plants. The invention aims to solve the problem of high SO<2> emission after desulfurization in the prior art. The invention discloses a coal slime fluidized bed boiler desulfurization collaborative optimization operation method. A desulfurization collaborative optimization operation system comprises the followingmodules: a DCS data acquisition module, an A/D and D/A conversion module, a central processing system module, a prediction control module, a man-machine interaction module and an optimization calculation module. The invention provides the coal slime fluidized bed boiler desulfurization collaborative optimization operation method. According to the method, modeling and optimization calculation are carried out on the process of the whole desulfurization system, and the SO<2> concentration value after optimization calculation is subjected to predictive control, so that the operation cost of the whole desulfurization system is minimized, and the result after optimization solution is subjected to predictive control to obtain the lowest operation cost, thereby realizing the economic and stable operation of SO<2> removal and improving the economic benefits of enterprises.
Owner:HANGZHOU DIANZI UNIV

Horizontal spraying and desulfurizing device and method for aluminum electrolysis fume

ActiveCN104226102AEfficient desulfurization and dust removalLow investment costDispersed particle separationCycloneElectrolysis
The invention discloses a horizontal spraying and desulfurizing device and method for aluminum electrolysis fume. The horizontal spraying and desulfurizing device comprises a limestone silo, a wet ball mill, a limestone slurry coarse material barrel, an oxidation fan, a circulation slurry pump, a limestone slurry fine material barrel, a limestone vortex pump, a limestone slurry pump, a limestone slurry cyclone, a horizontal absorption tower, a heat exchanger, a gypsum slurry pump, a filtered water pump, a vacuum device, a vacuum belt dewaterer, a water distribution vortex slurry pump, a waste water cyclone, a gypsum cyclone, a booster fan, a bypass baffle door and a chimney. Dehydrate gypsum is generated in the horizontal absorption tower, and SO2 is removed. Gypsum slurry expelled by the absorption tower is dewatered by the dewaterer to be recycled, and the desulfurized fume is exhausted. The r aluminum electrolysis fume has low-concentration SO2, efficient, economic and safety-management new process and new method and matched equipment are obtained, and the purposes of efficiently desulfurizing and removing dust, reducing investment cost, reducing desulfurization operation cost and improving the safety performance of aluminum electrolysis fume purification equipment and operation sites are achieved.
Owner:YUNNAN RUNXIN ALUMINUM

Apparatus and method for preparing high-activity calcium hydroxide by using carbide slag alkali residue

The invention discloses an apparatus used for preparing high-activity calcium hydroxide by using carbide slag alkali residue. The apparatus comprises a sodium bicarbonate metrical adding apparatus, a carbide slag adding apparatus, and sequentially connected components of a mixing tank, a carbide slag delivering screw conveyor, a drier, a crusher, an air separator, a deduster, and a collection chamber. The sodium bicarbonate metrical adding apparatus and the carbide slag adding apparatus are both connected with the mixing tank. The invention also relates to a method used for preparing high-activity calcium hydroxide by using the carbide slag alkali residue. According to the invention, sodium bicarbonate and the carbide slag are stirred in the mixing tank; the mixture is processed by using the drier, the crusher, and the air separator; and a calcium hydroxide finished product can be collected by using the deduster. The apparatus and the method provided by the invention are advantaged inthat: an advanced micro-porous structure is formed in the calcium hydroxide particles, such that the specific surface area of calcium hydroxide is increased, and the reaction activity is improved. When calcium hydroxide is applied as a desulphurization absorbent, the desulphurization efficiency can be improved by 5-10%, such that the consumption amount of absorbent can be reduced, and the cost ofdesulphurization operation can be reduced.
Owner:浙江菲达脱硫工程有限公司 +1

Regeneration method and regeneration equipment for waste salt produced in flue gas desulfurization

The invention relates to treatment of waste salt produced in flue gas desulfurization and discloses a regeneration method and regeneration equipment for waste salt produced in flue gas desulfurization, belonging to the technical field of treatment of coke oven flue gas. The regeneration method for waste salt produced in flue gas desulfurization in the invention comprises the following steps: (1) dissolving waste salt produced in flue gas desulfurization, carrying out flocculation for impurity removal, preparing a sodium sulfate saturated solution from the waste salt produced in flue gas desulfurization, an ammonium bicarbonate solution and a sodium sulfate solid, maintaining a temperature at 36-42 DEG C, and conducting centrifuging to obtain sodium bicarbonate and a mother solution I; (2)decomposing ammonium bicarbonate in the mother solution I through an ammonium bicarbonate tower to obtain ammonia gas, carbon dioxide and sodium sulfate, feeding the ammonia gas and the carbon dioxideinto an ammonium bicarbonate recovery device for generating an ammonium bicarbonate solution, and conducting centrifuging to obtain a sodium sulfate solid and a mother solution II; and (3) producingan ammonium sulfate fertilizer from the mother solution II by using an ammonium sulfate generation system. The regeneration method and the regeneration equipment in the invention can greatly reduce the operation cost of dry desulfurization of flue gas, improve the desulfurization efficiency and increase the utilization rate of sodium bicarbonate, and has important and positive practical significance for optimizing environmental conditions.
Owner:山西长林能源科技有限公司

Cement performance adjusting method for power plant gypsum production

The invention relates to the technical field of power plant gypsum, and discloses a cement performance adjusting method for power plant gypsum production. The method comprises the following steps: proper amounts of lime milk, soda ash, PFS and PAM are sequentially added to reclaimed water of an urban sewage treatment plant according to the quality of water coming from the urban sewage treatment plant in order to deeply treat the reclaimed water, the dosages of above reagents are correspondingly adjusted according to the quality of water coming from the urban sewage treatment plant and water treatment requirements, a mud-water mixture is subjected to mud-water separation through a variable-pore V-shaped filter tank, and clear water is conveyed to a clear water tank. The clinker components,admixture varieties, admixture use amounts, seasons and air temperatures during cement production, mill grinding working conditions and the like in the cement production process affect the quality andhe performances of produced cement, and adjustment of the ratio of the power plant gypsum, comprising an optimized formula of the gypsum and other raw materials, is carried out to timely correspondingly adjusting the formula in order to produce the stable high-strength and high-performance cement, so the method achieves an excellent effect.
Owner:SICHUAN XINGCHUANCHENG CEMENT CO LTD

Desulphurizing tower for desulphurizing with seawater soda-residue emulsion

InactiveCN101444698BVersatileSimplified desulfurization processDispersed particle separationSeawaterOperating cost
The invention discloses a desulphurizing tower for desulphurizing with seawater soda-residue emulsion. A defogging section, a seawater absorption section, a seawater soda-residue emulsion absorption section, an oxidation section and a clarification section are sequentially arranged inside the tower from top to bottom. A flue gas inlet is arranged on the side of the tower positioned between the seawater soda-residue emulsion absorption section and the oxidation section, a flue gas outlet is arranged at the top of the tower, a sediment outlet is arranged at the bottom of the tower, and a clarified liquid outlet is arranged on the side of the tower positioned on the upper part of the clarification section. The desulphurizing tower has multiple functions including absorption, oxidation, clarification and fog removal, so as to simplify desulphurizing process; and the flue gas exhaust and water drainage both achieve National Standard. The desulphurizing tower also has the advantages of low equipment investment, small floor area, low operating cost, convenient operation, and high flue gas desulphurizing efficiency (up to 95%); realizes simultaneous treatment of soda-residue and sulfur dioxide in flue gas; and is suitable for flue gas desulphurization in boilers of large-sized, middle-sized and small-sized thermal power stations of ammonia-soda process soda ash production plants in a coastal area, as well as industrial boilers and kilns in industrial and mining establishments.
Owner:QINGDAO SODA ASH IND DEV CO LTD +1
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