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93results about How to "Reduce inactivation rate" patented technology

Paraffin dehydrogenation catalyst

One aspect of the invention relates to a dehydrogenation catalyst composite containing alumina, chromium oxide, lithium oxide, and sodium oxide. The invention also relates to methods of making the dehydrogenation catalyst composite. Another aspect of the invention relates to method of dehydrogenating a dehydrogenatable hydrocarbon involving contacting the dehydrogenatable hydrocarbon with a dehydrogenation catalyst composite containing alumina, chromium oxide, lithium oxide, and sodium oxide to provide a dehydrogenated hydrocarbon, such as an olefin.
Owner:TEXAS PETROCHEM +1

Zeolite y alkylation catalysts

The present invention is directed to a zeolite Y catalyst having a controlled macropore structure. The present invention is also directed to a zeolite Y catalyst composite and a process for preparing the catalyst composite. The catalyst composite exhibits reduced deactivation rates during the alkylation process, thereby increasing the life of the catalyst. The present invention is also directed to processes for the preparation of carbonated, overbased aromatic sulfonates, which processes comprise alkylation, carbonation of aromatic hydrocarbons with one or more olefins.
Owner:CHEVRON ORONITE CO LLC +1

Aramid fiber-reinforced rein-based composite material and preparation method thereof

InactiveCN102516570AReduce inactivation rateGood swelling effectFibre typesHot pressingPolyresin
The invention relates to an aramid fiber-reinforced rein-based composite material and a preparation method thereof. Aramid fibers coated with an acrylic ester derivative polymer are prepared with a biological enzyme treatment method. A composite material is molded according to different substrate resins by adopting the conventional molding processes of fiber-reinforced resin-based composite materials such as die pressing, laminating, a hot pressing tank and the like or liquid phase molding processes such as resin transfer molding (RTM), a resin film infiltration (RFI) process and the like, so that the aramid fiber-reinforced rein-based composite material is obtained. Compared with a composite material prepared with unmodified aramid fibers, the composite material provided by the invention has the advantage that: the interlaminal shear strength is raised by 10-25 percent. The technical scheme of the invention has the characteristics of small fiber damage, mild reaction conditions, simple and practicable process, environmental friendliness and high industrial production benefit.
Owner:SUZHOU UNIV +1

Highly stable heavy hydrocarbon hydrodesulfurization catalyst and methods of making and use thereof

Described is a catalyst useful in the hydroprocessing of a heavy hydrocarbon feedstock wherein the catalyst comprises a calcined mixture made by calcining a formed particle of a mixture comprising molybdenum trioxide, a nickel compound, and an inorganic oxide material. The catalyst may be made by mixing an inorganic oxide material, molybdenum trioxide, and a nickel compound to form a mixture that is formed into a particle and calcined to provide a calcined mixture. The process involves the hydrodesulfurization and hydroconversion of a heavy hydrocarbon feedstock which process may include the conversion of a portion of the pitch content of the heavy hydrocarbon feedstock and the yielding of a treated product having an enhanced stability as reflected by its P-value.
Owner:SHELL USA INC

Paraffin dehydrogenation catalyst

One aspect of the invention relates to a dehydrogenation catalyst composite containing alumina, chromium oxide, lithium oxide, and sodium oxide. The invention also relates to methods of making the dehydrogenation catalyst composite. Another aspect of the invention relates to method of dehydrogenating a dehydrogenatable hydrocarbon involving contacting the dehydrogenatable hydrocarbon with a dehydrogenation catalyst composite containing alumina, chromium oxide, lithium oxide, and sodium oxide to provide a dehydrogenated hydrocarbon, such as an olefin.
Owner:TEXAS PETROCHEM +1

Mutant of alpha-L-rhamnosidase from aspergillus terreus CCF 3059 and application thereof

ActiveCN106318957AReduce inactivation rateFavorable for biocatalytic conversionGenetic engineeringFermentationAgricultural scienceAlpha-L-rhamnosidase
The invention provides a mutant of alpha-L-rhamnosidase from aspergillus terreus CCF 3059 and application thereof. The mutant comprises a gene D594Q shown in SEQ ID NO:2, a gene D594R shown in SEQ ID NO:3, a gene D594C shown in SEQ ID NO:4, a gene G827K shown in SEQ ID NO:5, a gene G827M shown in SEQ ID NO:6 and a gene G828A shown in SEQ ID NO:7. The mutant has the beneficial effects that the optimum temperatures of a mutant enzyme MRha-D594Q and a proenzyme MRha are 65 DEG C, but compared with the proenzyme MRha, the mutant enzyme MRha-D594Q still maintains higher enzymatic activity at 70 DEG C and 75 DEG C; the heat stability of the mutant enzyme MRha-D594Q can be further improved by adding sorbitol and is improved by 7.8 times in the half-life period at 70 DEG C.
Owner:NANJING FORESTRY UNIV

Catalyst for hydrocarbon steam cracking, method of preparing the same and method of preparing olefin by using the same

The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5≦j≦120, 0≦k≦50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal / mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.
Owner:LG CHEM LTD

Catalyst for hydrocarbon steam cracking, method of preparing the same and method of preparing olefin by using the same

The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5≦j≦120, 0≦k≦50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal / mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.
Owner:LG CHEM LTD

Preparing phosphorus containing alumina support by sol-gel method for fischer-tropsch synthesis and catalyst preparation thereof

InactiveUS20100130349A1Increase heat and mass transferDecrease deactivation rateCatalyst activation/preparationLiquid hydrocarbon mixture productionSol-gelLiquid hydrocarbons
The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt / phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.
Owner:KOREA GAS CORPORATION +2

Alkylated aromatic compositions, zeolite catalyst compositions and processes for making the same

The present invention is directed to novel alkylated aromatic compositions, zeolite catalyst compositions and processes for making the same. The catalyst compositions comprise zeolite Y and mordenite zeolite having a controlled macropore structure. The present invention is also directed to the preparation of the catalyst compositions and their use in the preparation of novel alkylated aromatic compositions. The catalyst compositions of the present invention exhibit reduced deactivation rates during the alkylation process, thereby increasing the life of the catalysts.
Owner:CHEVRON ORONITE CO LLC +1

Method of controlling monoalkyl aromatic process

InactiveUS6872864B2Reduce formationDecrease catalyst deactivation rateMolecular sieve catalystCatalystsAlkyl transferAlkene
A process for the alkylation of aromatics with olefins using a solid catalyst is disclosed, wherein the olefin ratio and / or the maximum olefin concentration in the alkylation catalyst bed is maintained less than an upper limit. Such operation can decrease the catalyst deactivation rate and the formation of diphenylalkanes. This invention is applicable to processes for the production of a wide variety of commercially important alkylated aromatics, including ethylbenzene and cumene.
Owner:UOP LLC

Preparation method and application of catalyst applicable to methanation of slurry reactor

The invention discloses a preparation method of a catalyst applicable to methanation of a slurry reactor. The method comprises the following steps: pretreating nickel powder by using diluted acid, pretreating aluminum powder by using an organic solvent, uniformly mixing the nickel powder with the aluminum powder, melting in a high-temperature furnace provided with an external magnetic field, cooling to room temperature in the presence of inert gas, grinding into particles of which the size is 80-200 meshes, putting a NaOH solution into an ultrasonic constant-temperature water bath, stirring and adding nickel-aluminum alloy powder into the NaOH solution to react, removing alkaline liquid from the upper layer after the reaction ends, washing by using deionized water until the solution is neutral, and then washing by using absolute ethanol to obtain a Reyne nickel catalyst. The catalyst provided by the invention has the advantages of being high in strength, high in activity and applicable to the methanation of the slurry reactor.
Owner:SEDIN ENG

Copper catalyst for dehydrogenation application

Disclosed are catalytic compositions having from about 35% to about 75% of Cu by weight, from about 15% to about 35% of Al by weight, and about 5% to about 20% of Mn by weight. The catalytic compositions are bulk homogeneous compositions formed from extruding and calcinating a powder formed from a precipitation reaction of Cu(NO3)2, Mn(NO3)2, Na2Al2O3. The catalytic compositions have one or more crystalline phases of one or more of CuO and CuxMn(3-x)O4, where x is from about 1 to about 1.5, or both. The catalytic compositions are useful for the conversion of 1,4-butane-di-ol to γ-butyrolactone by a dehydrogenation reaction.
Owner:BASF CORP

Optimized method for recycling bio-oils into hydrocarbon fuels

A process for the production of hydrocarbon products from a feed comprising at least one non-pre-treated bio-oil, comprising a first step for hydroreforming in the presence of hydrogen and a hydroreforming catalyst, used alone or as a mixture, to obtain at least one liquid effluent comprising at least one aqueous phase and at least one organic phase, a second step in which at least a portion of the organic phase of the effluent obtained from the first hydroreforming step is recycled to the first hydroreforming step with a recycle ratio equal to the ratio of the mass flow rate of said organic phase to the mass flow rate of the non-pre-treated bio-oil in the range 0.05 to 2 and in which the hydrocarbon effluent obtained from the hydrotreatment and / or hydrocracking step is not recycled to said first hydroreforming step.
Owner:INST FR DU PETROLE

A process for the preparation of a mixture of alkyl phoenols

The present invention relates to a process for the preparation of mixture of alkyl phenols preferably of 2, 6 xylenol and o-cresol using an ortho selective catalyst comprises contacting a catalyst with a feed consisting of an alcohol and a phenolic compound at a temperature ranging between 250 to 400 ° C., at a pressure in the range of ambient to 150 psi and collecting the products at a temperature ranging between -5 to +5° C.
Owner:COUNCIL OF SCI & IND RES

Method for degrading corn straws

A method for degrading corn straws is characterized by comprising the following steps: specifically mechanically crushing, sieving and drying the corn straws, then degrading lignin in the corn strawsby using immobilized laccase taking Cu2+ modified Fe3O4-NH2-PEI magnetic nanoparticles as carriers, recovering the immobilized laccase, boiling the degraded corn straws, then adding NaOH for washing,and adding cellulase for further degrading the cellulose. According to the method, the affinity between the immobilized laccase and a substrate is enhanced, the stability and the activity of the laccase in an application process are improved, thus, the degradation efficiency is improved, and the degradation rate of the lignin reaches 40.76% or above. Inhibition of the immobilized laccase and degradation products such as phenolic substances generated by degradation on the cellulase activity is eliminated, so that the cellulase activity is guaranteed, and the conversion rate of the cellulose isimproved, and reaches 46.85%.
Owner:JILIN AGRICULTURAL UNIV

Fischer-Tropsch synthesis oil hydrofining method

The invention provides a Fischer-Tropsch synthesis oil hydrofining method which comprises the following steps: S1, mixing Fischer-Tropsch synthesis oil with hydrogen, carrying out a low-temperature pre-hydrogenation reaction, and converting unsaturated olefins in the Fischer-Tropsch synthesis oil into corresponding saturated hydrocarbons to obtain a pre-hydrogenation product; S2, performing a deephydrodeoxygenation reaction on the pre-hydrogenation product to obtain a hydrofining product; and S3, circulating a part of the hydrofining product, conducting mixing with Fischer-Tropsch synthesis oil, and then carrying out a low-temperature pre-hydrogenation reaction. Through circulation of a part of the hydrofining product, reaction temperature rise can be reduced, coking carbon deposition andinactivation of a catalyst are prevented, stable operation of the reaction is easy to maintain, and a high olefin conversion rate and a high oxygen-containing compound conversion rate are maintainedfor a long time.
Owner:BEIJING SJ ENVIRONMENTAL PROTECTION & NEW MATERIAL CO LTD

Catalyst, a process for preparation of the catalyst and application thereof

The present disclosure relates to a composition, wherein the composition is a catalyst comprising support matrix, active metal, promoter metal and halide, wherein the support matrix is additionally subjected to a modifier to obtain a modified support matrix. The catalyst in the reaction reduces the percentage coke formation and provides for an enhanced reformate yield having an increase total aromatic yield and C8 aromatic yield when compared to the known / commercially available catalyst for naphtha reforming process, and also improves the quality of reformate obtained at end of the reaction. The disclosure further relates to process of preparation of the catalyst, the catalyst of the present disclosure derived from the process described, displays lower deactivation during the reaction demonstrating increased stability and reduction in the regeneration frequency and thereby making the catalyst economically feasible.
Owner:RELIANCE INDUSTRIES LIMITED

Organic triplet photosensitive agent with host-guest recognition group and preparation method of organic triplet photosensitive agent

The invention discloses an organic triplet photosensitive agent with a host-guest recognition group and a preparation method of the organic triplet photosensitive agent, which belong to the technicalfield of the synthesis of photosensitive agents. Hexanediamine is introduced on a meso-position benzene ring position of Bodipy in a C60-Bodipy binary compound organic triplet photosensitive agent tobe used as a supermolecule combination site, the triplet photosensitive agent with a hyperon combination site and a supermolecule main body with a triplet receptor are self-assembled in a solution, and a space distance between the triplet photosensitive agent and the triplet receptor is shortened to a molecular dimensional range, so that the triplet photosensitive agent can transfer the energy without being dispersed in an effective service life range, the non-radiation deactivation probability of a triplet exciton can be reduced, the energy transfer efficiency between the photosensitive agentand the receptor can be increased, and the upconversion efficiency can be increased.
Owner:SICHUAN UNIV

Catalyst and Process for Olefin Metathesis Reaction

The present invention relates to the use of magnesium oxide (MgO) as catalyst for isomerisation of olefins with defined physical properties, a catalyst for olefin metathesis comprising said MgO and a process for olefin metathesis using said catalyst.
Owner:BOREALIS AG

Premixed flour for buckwheat steamed buns and production process thereof

The invention discloses premixed flour for buckwheat steamed buns and a production process thereof and belongs to the technical field of foods. The premixed flour for buckwheat steamed buns comprises,by weight, 60-80 parts of wheat flour, 5-25 parts of buckwheat flour, 5-25 parts of puffed buckwheat flour, 0.7-1.2 parts of microcapsule-embedded high-activity dry yeast, 0.05-0.2 part of sodium stearoyl lactylate, 0.05-0.2 part of calcium stearoyl lactylate, 0.01-0.02 part of vitamin C and 0.005-0.02 part of an enzyme preparation, wherein the mass ratio of the buckwheat flour to the puffed buckwheat flour is 1: 5 to 5: 1; the microcapsule embedded high-activity dry yeast is an industrial instant dry yeast of lesaffre; the moisture content of the premixed flour for buckwheat steamed buns is10% or below. By adopting the buckwheat steamed bun premixed flour, the quality of the buckwheat steamed bun is improved, the increase of a fatty acid value can be effectively delayed, the rancidity is prevented, the inactivation of the yeast and enzyme preparation is delayed, the quality guarantee period of the premixed flour for buckwheat steamed buns is prolonged, and the industrial productionof the premixed flour for the buckwheat steamed buns is achieved.
Owner:JIANGNAN UNIV +1

Active layer used for ternary blending solar cell and application of active layer

The invention belongs to the technical field of organic photovoltaic devices or organic semiconductor film solar cells, and particularly relates to an active layer used for a ternary blending solar cell and application of the active layer. In the active layer, high-crystallinity P3HT serves as a donor, micromolecular DPP4T-Cz serves as a second donor, and a fullerene derivate PC61BM serves as an acceptor. Under the condition that the active layer is relatively thick, a good carrier transport capacity of the cell is ensured, the carrier recombination efficiency is reduced, a good exciton dissociation efficiency is obtained, and the optical absorption range is enpanded.
Owner:CHANGZHOU UNIV
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