The invention discloses a color film substrate, an array substrate, a display panel and a display device. The color brightness ratio of the display device can be improved, and the white balance effect is improved, so that the display quality of the display device is improved. The color film substrate comprises a plurality of first pixel units arranged and distributed in an array shape, the first pixel units comprise red sub-pixels, green sub-pixels and blue sub-pixels, the sub-pixels comprise colorful photoresistance of the corresponding colors and white photoresistance, a white chromaticity coordinate formed after color mixture of the red sub-pixels, the green sub-pixels and the blue sub-pixels equals a white chromaticity coordinate formed after color mixture of the red sub-pixels, the green sub-pixels and the blue sub-pixels with the area ratio of 1:1:1. Compensation can be carried out on the brightness difference caused by difference of light filtration effects of the colorful photoresistance by designing the white photoresistance of the corresponding area, and therefore the color brightness ratio of the display device can be improved, the white balance effect is improved, and the display quality of the display device is improved.