The fluorescent material has the composition of (SraMbNcLd)SiOn, where, M is one or several selected from Mg, Ca, Ba, Zn, Li, Na and K; N is one or several selected from Li, Na and K; L is one or several selected from Mn, Cu, Sn, Sb, Bi, Pb and RE elements; a has the selection range of 2.5-3.5; b has the selection range of 0.001-0.5; c has the selection range of 0.001-0.5; d has the selection range of 0.001-0.5; and n has the selection range of 4.7-5.5. The present invention also provides the preparation process of the fluorescent material and the LED, planar display and other light emitting devices with the fluorescent material.