The invention relates to a process for preparing uropium-doped
yttrium oxide @
silicon dioxide bean-shaped nano-cables, which belongs to the technical field of nano-material preparation. The process includes three steps: (1) preparing
spinning liquor; (2) preparing (PVP + rare-earth
nitrate) @ (PVP + tetraethoxysilane) recombination nano-cables; (3) preparing Y2O3 @ SiO2 or Y2O3: Eu3 + @SiO2 bean-shaped nano-cables. The first step includes: adding a certain amount of mixed liquor(volume ratio is 5:1) including polyvinyl-pyrrolidone (PVP), N,N-
dimethylformamide (DMF) and
glycerol into the rare-earth
nitrate; stirring the mixed liquor for 4-6 hours with a magnetic force under
room temperature; standing the mixed liquor for 2-3 hours to obtain core layer
spinning liquor, wherein
mass percentage includes that the PVP is 9%, the rare-earth
nitrate is 8%, the DMF is 65% and the
glycerol is 18%; mixing a certain amount of mixed liquor ( volume ratio is 4:1) including the PVP, absolute ethyl
alcohol and the tetraethoxysilane, stirring the mixed liquor with the magnetic force for 3-6 hours, and standing the mixed liquor to obtain shell layer
spinning liquor, wherein the
mass percentage includes that the PVP is 12%, the tetraethoxysilane is 20% and the ethyl
alcohol is 68%. The second step includes that coaxial electrostatic spinning technology is adopted, and parameters include: coaxial nozzles are formed by adopting a 10# stainless steel injection needle after being
cut flat (outer
diameter=1.0
millimeter, inner
diameter=0.7
millimeter) as an inner
nozzle needle and adopting a 12# stainless steel needle head (outer
diameter=1.4 millimeters, inner diameter=1.2 millimeters) as an outer
nozzle needle. Further, the two
nozzle needles are sleeved and fixed, the prepared shell layer spinning liquor is placed in an outer
pipe of a coaxial spinning device, the core layer spinning liquor is added in an inner
pipe.